US4966803A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polymer films partially provided with stiffened segments, process for the production thereof, and the use thereof
Assignee: DSM BV
•
Filing: 1988-07-25
•
Granted: 1990-10-30
•
Expires: 2008-07-25
Abstract
Abstract The invention relates to films of polymers of high molecular weight, which have been obtained by casting polymers dissolved or swollen in solvents and partially contain stiffened segments, which films serve either for decorative, handling or fixing purposes or allow, especially when formed on the film edges, a particularly ultrahigh stretching of the films without excessive formation of lips.
Inventors
- 👤 Pieter B. Pluyter
- 👤 Hendrikus J. J. Rutten
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 04:29
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/18; B; B29; B29C; B29C55/00; B29C55/005; B29K; B29K2105/00; B29K2105/06; B29K2105/20; C08J2323/00; C08J2323/02; Y; Y10; Y10S; Y10S428/00; Y10S428/91; Y10T; Y10T428/00; Y10T428/24; Y10T428/24777; Y10T428/31504; Y10T428/31507; Y10T428/31533; Y10T428/3154; Y10T428/31544; Y10T428/31721; Y10T428/31786; Y10T428/31797; Y10T428/31855; Y10T428/31935
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
42 words
A film comprising copolymers of high molecular weight, obtained by casting polymers, dissolved or swollen in solvents, wherein said film contains stiffened segments having a width of at least 0.5 mm, and said polymers have molecular weights greater than 1×10 4 g/mol.
Claim 2
Dependent Claim
42 words
A film comprising copolymers of high molecular weight, obtained by casting polymers, dissolved or swollen in solvents, wherein said film contains stiffened segments having a width of at least 0.5 mm, and said polymers have molecular weights greater than 1×10 4 g/mol.
Claim 3
Dependent Claim
25 words
The film according to claim 1, wherein said film consists of polyolefins having a molecular weight (weight average molecular weight) of more than 100,000 g/mol.
Claim 4
Dependent Claim
25 words
The film according to claim 1 wherein said film consists of polyethylenes having a molecular weight (weight average molecular weight) from 400,000 to 6,000,000 g/mol.
Claim 5
Dependent Claim
15 words
The film according to claim 1, wherein said film is pre-stretched in the longitudinal direction.
Claim 6
Dependent Claim
15 words
The film according to claim 1, wherein said film is pre-stretched in the transverse direction.
Claim 7
Dependent Claim
18 words
The film according to claim 1, wherein said film is pre-stretched in both the longitudinal and transverse directions.
Claim 8
Dependent Claim
145 words
A process for producing the film according to claim 1 comprising: dissolving or swelling a polymer of high molecular weight in a solvent, shaping the polymer solution or the swollen polymer to obtain a film, cooling the thus obtained film to a temperature below the gelling temperature, partially or completely removing the solvent, and stiffening segments of said film by heating (i) wherein, in the case that the solvent has been partially removed, the resulting film in the segments that are to be stiffened, is heated to a temperature which is between 10° C. below the crystalline melting point and the decomposition temperature of the polymer, or (ii) wherein, in the case that solvent has been completely removed, the resulting film, in the segments that are to be stiffened, is heated to a temperature which is above the dissolution temperature and below the decomposition temperature.
Claim 9
Dependent Claim
33 words
Process according to claim 7, wherein said heating is conducted for a period of time which is sufficient to permit re-entangling of the polymer molecules to occur in accordance with the equation: ##EQU2##
Claim 10
Dependent Claim
162 words
A process for producing the film according to claim 1 comprising: dissolving or swelling a polymer of high molecular weight in a solvent, shaping the polymer solution of the swollen polymer to obtain a film, cooling the thus obtained film to a temperature below the gelling temperature, partially or completely removing the solvent pre-stretching the film in the longitudinal, the transverse or in both the longitudinal and transverse directions, and stiffening segments of said film by heating (i) wherein, in the case that the solvent has been partially removed, the resulting film in the segments that are to be stiffened, is heated to a temperature which is between 10° C. below the crystalline melting point and the decomposition temperature of the polymer, or (ii) wherein, in the case that the solvent has been completely removed, the resulting film, in the segments that are to be stiffened, is heated to a temperature which is above the dissolution temperature and below the decomposition temperature.
Claim 11
Dependent Claim
33 words
Process according to claim 9, wherein said heating is conducted for a period of time which is sufficient to permit re-entangling of the polymer molecules to occur in accordance with the equation: ##EQU3##
Claim 12
Dependent Claim
99 words
A process for producing high molecular weight film comprising: dissolving or swelling a polymer of high molecular weight in a solvent, shaping the polymer solution or the swollen polymer to obtain a film, cooling the thus obtained film to a temperature below the gelling temperature, partially or completely removing the solvent, and pre-stretching the film in the longitudinal direction, or in the transverse direction, or in both the longitudinal and transverse directions, and stiffening segments of said film by laminating the film in the segments to be stiffened with a polymer film on one side or on both sides.
Claim 13
Dependent Claim
99 words
A process for producing high molecular weight film comprising: dissolving or swelling a polymer of high molecular weight in a solvent, shaping the polymer solution or the swollen polymer to obtain a film, cooling the thus obtained film to a temperature below the gelling temperature, partially or completely removing the solvent, and pre-stretching the film in the longitudinal direction, or in the transverse direction, or in both the longitudinal and transverse directions, and stiffening segments of said film by laminating the film in the segments to be stiffened with a polymer film on one side or on both sides.
Claim 14
Dependent Claim
78 words
A process for producing high molecular weight film comprising: dissolving or swelling a polymer of high molecular weight in a solvent, shaping the polymer solution or the swollen polymer to obtain a film, cooling the thus obtained film to a temperature below the gelling temperature, partially or completely removing the solvent, and stiffening segments of said film by laminating the film in the segments to be stiffened with a polymer film on one side or on both sides.
Claim 15
Dependent Claim
78 words
A process for producing high molecular weight film comprising: dissolving or swelling a polymer of high molecular weight in a solvent, shaping the polymer solution or the swollen polymer to obtain a film, cooling the thus obtained film to a temperature below the gelling temperature, partially or completely removing the solvent, and stiffening segments of said film by laminating the film in the segments to be stiffened with a polymer film on one side or on both sides.
Claim 16
Dependent Claim
17 words
Process according to claim 1 wherein said polymer film used for lamination consists of low density polyethylene.
Claim 17
Dependent Claim
17 words
Process according to claim 12 wherein said polymer film used for lamination consists of low density polyethylene.
References Cited (Backward Citations)
US3634182A
Cited
US3562383A
Cited
US4090008A
Cited
US4551296A
Cited
US4664859A
Cited
US4600633A
Cited
US4726977A
Cited
GB2164898A
Cited
GB2164897A
Cited
US4663101A
Cited
JPS6461821A
Cited
JPS6466624A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-10-29 | 1994-04-30 | 1994-10-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-10-29 | 1998-04-30 | 1998-10-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-10-29 | 2002-04-30 | 2002-10-30 | $7700.00 | Window Closed / Lapsed |