US4964875A
Expired / Lapsed
US
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Process for after-treatment of dyed polyamide textile materials with polyurethane containing quaternary ammonium groups
Assignee: Bayer AG
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Filing: 1989-05-09
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Granted: 1990-10-23
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Expires: 2009-05-09
Abstract
Abstract The invention relates to a process for after-treatment of anionically dyed natural and synthetic polyamide textile materials by means of polyurethanes containing quaternary ammonium groups.
Inventors
- 👤 Udo W. Hendricks
- 👤 Josef Sanders
- 👤 Ergun Tamer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 14:31
CPC Classifications
D; D06; D06P; D06P1/00; D06P1/44; D06P1/52; D06P1/5264; D06P1/5285; D06P5/00; D06P5/02; D06P5/04; D06P5/08; Y; Y10; Y10S; Y10S8/00; Y10S8/916; Y10S8/917; Y10S8/92; Y10S8/924
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
174 words
A process for the after-treatment of anionically dyed polyamide textile materials comprising contacting said materials with polyurethanes containing quaternary ammonium groups, wherein the polyurethanes are obtainable by reaction of (A) compounds containing tertiary amino groups and at least two hydroxyl groups comprising hydroxyalkylamines of the general formulae ##STR6## in which Q 1 and Q 2 , independently of one another, denote a radical of the general formula ##STR7## X denotes C 1 -C 18 -alkyl, C 5 -C 8 -cycloalkyl, C 7 -C 9 aralkyl or a radical of the formula ##STR8## R 1 , R 2 and R 4 , independently of one another, denote C 2 -C 6 -alkylene, C 5 -C 8 -cycloalkylene or C 7 -C 9 -aralkylene, R 3 denotes hydrogen or methyl, R 5 denotes C 1 -C 18 -alkyl, C 5 -C 8 -cycloalkyl, C 7 -C 9 -aralkyl or a radical of the formula HO--Q.sup.1 --R.sup.1 -- and m, n and r denote a number from 0 to 30 with (B) polyisocyanates and (C) quaternizing agents.
Claim 2
Dependent Claim
174 words
A process for the after-treatment of anionically dyed polyamide textile materials comprising contacting said materials with polyurethanes containing quaternary ammonium groups, wherein the polyurethanes are obtainable by reaction of (A) compounds containing tertiary amino groups and at least two hydroxyl groups comprising hydroxyalkylamines of the general formulae ##STR6## in which Q 1 and Q 2 , independently of one another, denote a radical of the general formula ##STR7## X denotes C 1 -C 18 -alkyl, C 5 -C 8 -cycloalkyl, C 7 -C 9 aralkyl or a radical of the formula ##STR8## R 1 , R 2 and R 4 , independently of one another, denote C 2 -C 6 -alkylene, C 5 -C 8 -cycloalkylene or C 7 -C 9 -aralkylene, R 3 denotes hydrogen or methyl, R 5 denotes C 1 -C 18 -alkyl, C 5 -C 8 -cycloalkyl, C 7 -C 9 -aralkyl or a radical of the formula HO--Q.sup.1 --R.sup.1 -- and m, n and r denote a number from 0 to 30 with (B) polyisocyanates and (C) quaternizing agents.
Claim 3
Dependent Claim
24 words
A process according to claim 1, wherein the component (B) used in the preparation of the polyurethanes comprises aliphatic, cycloaliphatic, araliphatic or aromatic polyisocyanates.
Claim 4
Dependent Claim
14 words
A process according to claim 2, wherein the component (B) is an aliphatic diisocyanate.
Claim 5
Dependent Claim
54 words
A process according to claim 1, wherein component (A) is used in a mixture with other compounds (D) which are customary in polyurethane chemistry and contain at least two Zerewitinoff-active hydrogen atoms, said compounds (D) selected from the group consisting of polyesters, polyethers, polythioethers, polyacetals, polycarbonates and polyesteramides containing 2 to 4 hydroxyl groups.
Claim 6
Dependent Claim
20 words
A process according to claim 1, wherein (A) and (B) are reacted in the process of chain terminating agents (E).
Claim 7
Dependent Claim
42 words
A process according to claim 5, wherein (A) and (B) and, if present, (D) and/or (E) are reacted, while maintaining a ratio of isocyanate groups to groups which are reactive towards isocyanate groups of 0.8:1 to 1:1 at 20° to 150° C.
Claim 8
Dependent Claim
40 words
A process according to claim 1, wherein in the quaternization 0.7 to 1.0 equivalent of quaternizing agent is used per tertiary amino group of the resultant addition product and any remaining tertiary amino groups are protonated by treatment with acids.
Claim 9
Dependent Claim
14 words
A process according to claim 1, wherein the polyamide which is after-treated is wool.
Claim 10
Dependent Claim
18 words
A process according to claim 1, wherein the polyamide which is after-treated is wool with a non-felting finish.
Claim 11
Dependent Claim
24 words
A process according to claim 5, wherein the terminating agent is a monoalcohol, a monoamine, acetic hydrazide, stearyl hydrazide, aniline or a thiol compound.
Claim 12
Dependent Claim
18 words
A process according to claim 10, wherein the monoalcohol is methanol, N-octanol, isopropanol, isooctyl alcohol or stearyl alcohol.
Claim 13
Dependent Claim
16 words
A process according to claim 10, wherein the monoamine is ethylamine, di-n-butylamine, di-isopropylamine, stearylamine or 4-amino-2,2,6,6-tetramethylpiperidine.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1993-10-22 | 1994-04-23 | 1994-10-23 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-10-22 | 1998-04-23 | 1998-10-23 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-10-22 | 2002-04-23 | 2002-10-23 | $7700.00 | Window Closed / Lapsed |