US4963304A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Process for preparing microporous membranes
Assignee: Dow Chemical Co
•
Filing: 1988-09-26
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Granted: 1990-10-16
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Expires: 2008-09-26
Abstract
Abstract A process for preparing microporous membranes by coextruding a melt of a plurality of interdigitated layers of at least two polymers, one having preferential solubility over the other, dividing and reorienting the layers of said melt into discrete domains of random orientation, forming a thin membrane or like article and leaching the preferentially soluble polymer out of the resulting article.
Inventors
- 👤 Jang-hi Im
- 👤 C. C. Chau
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 04:27
CPC Classifications
B; B29; B29C; B29C67/00; B29C67/20; B29C67/202; C; C08; C08J; C08J9/00; C08J9/26; B29C48/00; B29C48/03; B29C48/07; B29C48/08; B29C48/09; B29C48/10; B29C48/16; B29C48/18; B29C48/21; B29C48/22; B29C48/25; B29C48/30; B29C48/32; B29C48/335; B29C48/36; B29C48/362; B29C48/50; B29C48/695; B29C48/70; B29C48/71; B29K; B29K2105/00; B29K2105/0088
Claims Analysis
Total Claims: 30
Claim 1
Independent Claim
162 words
A process for preparing a microporous membrane having a narrow pore size distribution and sharp size cutoff comprising: forming a lamellar polymeric composition by dividing and reorienting a plurality of adjacent layers of polymeric materials, each layer comprising at least two different polymeric materials and having a thickness of from 0.03 to 5 microns to form discrete domains of said polymeric materials of random orientation, at least one of said different polymeric materials having a preferential solubility in a selected solvent with respect to at least one other of said different polymeric materials; forming a melt composition of said lamellar polymeric composition into a thin solid structure; contacting said solid unitary structure with an extraction medium which has a preferential solubility for at least one of said at least two different polymeric materials, whereby said preferentially soluble polymeric material is removed from said solid unitary structure to form a porous unitary structure; and separating said extraction medium from said porous unitary structure.
Claim 2
Dependent Claim
162 words
A process for preparing a microporous membrane having a narrow pore size distribution and sharp size cutoff comprising: forming a lamellar polymeric composition by dividing and reorienting a plurality of adjacent layers of polymeric materials, each layer comprising at least two different polymeric materials and having a thickness of from 0.03 to 5 microns to form discrete domains of said polymeric materials of random orientation, at least one of said different polymeric materials having a preferential solubility in a selected solvent with respect to at least one other of said different polymeric materials; forming a melt composition of said lamellar polymeric composition into a thin solid structure; contacting said solid unitary structure with an extraction medium which has a preferential solubility for at least one of said at least two different polymeric materials, whereby said preferentially soluble polymeric material is removed from said solid unitary structure to form a porous unitary structure; and separating said extraction medium from said porous unitary structure.
Claim 3
Dependent Claim
24 words
A process according to claim 1 which includes forming each of said layers from a mixture of said at least two different polymeric materials.
Claim 4
Dependent Claim
44 words
A process according to claim 2 which includes forming each of said layers from another melt of at least one lamellar composition comprising a plurality of thin layers of a first polymeric material interdigitated with thin layers of a second and different polymeric material.
Claim 5
Dependent Claim
29 words
A process according to claim 3 which includes providing a compatibilizing polymeric material interdigitated between each layer of said first and second polymeric materials of said one lamellar composition.
Claim 6
Dependent Claim
15 words
A process according to claim 4 wherein said compatibilizing polymeric material comprises styrene-butadiene-styrene triblock copolymer.
Claim 7
Dependent Claim
20 words
A process according to claim 5 wherein said first polymeric material comprises polyethylene and said second polymeric material comprises polystyrene.
Claim 8
Dependent Claim
22 words
A process according to claim 2 wherein said mixture of at least two polymeric materials comprises a mixture of polyethylene and polystyrene.
Claim 9
Dependent Claim
36 words
A process according to claim 1 wherein the amount of said preferentially soluble polymeric material is in the range from 10 to 90 volume percent, based on the total volume of said differentially soluble polymeric materials.
Claim 10
Dependent Claim
25 words
A process according to claim 8 wherein the amount of said preferentially soluble polymeric material is in the range from 30 to 85 volume percent.
Claim 11
Dependent Claim
25 words
A process according to claim 8 wherein the amount of said preferentially soluble polymeric material is in the range from 50 to 80 volume percent.
Claim 12
Dependent Claim
24 words
A process according to claim 8 which includes forming each of said layers from a mixture of said at least two different polymeric materials.
Claim 13
Dependent Claim
44 words
A process according to claim 11 which includes forming each of said layers from another melt of at least one lamellar composition comprising a plurality of thin layers of a first polymeric material interdigitated with thin layers of a second and different polymeric material.
Claim 14
Dependent Claim
29 words
A process according to claim 12 which includes providing a compatibilizing polymeric material interdigitated between each layer of said first and second polymeric materials of said one lamellar composition.
Claim 15
Dependent Claim
15 words
A process according to claim 13 wherein said compatibilizing polymeric material comprises styrene-butadiene-styrene triblock copolymer.
Claim 16
Dependent Claim
20 words
A process according to claim 14 wherein said first polymeric material comprises polyethylene and said second polymeric material comprises polystyrene.
Claim 17
Dependent Claim
22 words
A process according to claim 11 wherein said mixture of at least two polymeric materials comprises a mixture of polyethylene and polystyrene
Claim 18
Dependent Claim
165 words
A process for preparing a microporous membrane comprising: forming a melt blend comprising an admixture of at least two different polymeric materials, at least one of said different polymeric materials having a differential solubility in a selected solvent with respect to at least one other of said different polymeric materials; forming said melt blend into a melt stream comprising a layered stream of a plurality of thin, substantially parallel layers, each layer comprising a blend of said different polymeric material and being from about 0.03 to about 5 microns in thickness; passing said melt stream through a mixing means; forming said mixed melt stream into a solid unitary structure; contacting said solid unitary structure with an extraction medium which has a differential solubility for at least one of said at least two different polymeric materials whereby said preferentially soluble polymeric material is removed from said solid uniform structure to form a solid unitary microporous structure; and separating said extraction medium from said unitary porous structure.
Claim 19
Dependent Claim
165 words
A process for preparing a microporous membrane comprising: forming a melt blend comprising an admixture of at least two different polymeric materials, at least one of said different polymeric materials having a differential solubility in a selected solvent with respect to at least one other of said different polymeric materials; forming said melt blend into a melt stream comprising a layered stream of a plurality of thin, substantially parallel layers, each layer comprising a blend of said different polymeric material and being from about 0.03 to about 5 microns in thickness; passing said melt stream through a mixing means; forming said mixed melt stream into a solid unitary structure; contacting said solid unitary structure with an extraction medium which has a differential solubility for at least one of said at least two different polymeric materials whereby said preferentially soluble polymeric material is removed from said solid uniform structure to form a solid unitary microporous structure; and separating said extraction medium from said unitary porous structure.
Claim 20
Dependent Claim
15 words
A process in accordance with claim 17 wherein said mixing means comprises a motionless mixer.
Claim 21
Dependent Claim
18 words
A process in accordance with claim 17 wherein said polymeric material comprises a mixture of polyethylene and polystyrene.
Claim 22
Dependent Claim
53 words
A process according to claim 17 wherein said melt blend comprising a admixture of at least two different polymeric materials is formed from a melt of at least one lamellar composition comprising a plurality of thin layers of a first polymeric material interdigitated with thin layers of a second and different polymeric material.
Claim 23
Dependent Claim
29 words
A process according to claim 20 which includes providing a compatibilizing polymeric material interdigitated between each layer of said first and second polymeric materials of said one lamellar composition.
Claim 24
Dependent Claim
15 words
A process according to claim 21 wherein said compatibilizing polymeric material comprises styrene-butadiene-styrene triblock copolymer.
Claim 25
Dependent Claim
36 words
A process according to claim 22 wherein the amount of said preferentially soluble polymeric material is in the range from 10 to 90 volume percent, based on the total volume of said differentially soluble polymeric materials.
Claim 26
Dependent Claim
36 words
A process according to claim 17 wherein the amount of said preferentially soluble polymeric material is in the range from 10 to 90 volume percent, based on the total volume of said differentially soluble polymeric materials.
Claim 27
Dependent Claim
25 words
A process according to claim 24 wherein the amount of said preferentially soluble polymeric material is in the range from 30 to 85 volume percent.
Claim 28
Dependent Claim
25 words
A process according to claim 25 wherein the amount of said preferentially soluble polymeric material is in the range from 50 to 80 volume percent.
Claim 29
Dependent Claim
56 words
The process of claim 17 wherein said melt blend is formed from another melt of at least one lamellar composition comprising a plurality of thin layers of a first polymeric material interdigitated with thin layers of a second and different polymeric material, where said another melt has been passed through said motionless mixer prior to recoextruding.
Claim 30
Dependent Claim
29 words
A process according to claim 27 which includes providing a compatibilizing polymeric material interdigitated between each layer of said first and second polymeric materials of said one lamellar composition.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-10-15 | 1994-04-16 | 1994-10-16 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-10-15 | 1998-04-16 | 1998-10-16 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-10-15 | 2002-04-16 | 2002-10-16 | $7700.00 | Window Closed / Lapsed |