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US4960833A Expired / Lapsed US ⏱️ 0.0 years remaining

Rubber composition with nitrogen and phosphorous compound

Assignee: Sumitomo Chemical Co Ltd
•
Filing: 1988-11-14
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Granted: 1990-10-02
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Expires: 2008-11-14
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Abstract

Abstract A rubber composition containing (A) a bismaleimide compound represented by the general formula (I) ##STR1## wherein R is a divalent acyclic aliphatic group, cyclic aliphatic group, aromatic group, or alkylaromatic group, these groups optionally containing a hetero atom selected from O, N and S in their chain or side substituent, (B) a sulfenamide compound represented by the general formula (II) ##STR2## wherein R 1 and R 2 denote independently from each other a hydrogen atom, an acyclic aliphatic group, or cyclic aliphatic group, or R 1 and R 2 together denote a chain aliphatic group which optionally contains an oxygen atom, provided that R 1 and R 2 cannot simultaneously denote a hydrogen atom, (C) a dithiophosphoric acid compound represented by the general formula (III) ##STR3## wherein R 3 and R 4 denote each an aliphatic group, and (D) sulfur; or (A) a bismaleimide compound represented by the general formula (I) defined above, (E) an aromatic carboxylic acid anhydride, (F) sulfur and/or a sulfur donor, and (G) vulcanization accelerators.

Inventors

  • 👤 Hideo Nagasaki
  • 👤 Yasuzi Takemoto

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 23:27
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/16; C08K5/34; C08K5/3412; C08K5/3415; C08F; C08F291/00; C08F291/02; C08K5/49; C08K5/5398

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 221 words
A rubber composition containing (A) a bismaleimide compound represented by the general formula (I) ##STR7## wherein R is a divalent acyclic aliphatic group, cyclic aliphatic group, aromatic group, or alkylaromatic group, and wherein these groups may contain a hetero atom selected from O, N and S, (B) a sulfenamide compound represented by the general formula (II) ##STR8## wherein R 1 and R 2 denote independently from each other a hydrogen atom, an acyclic aliphatic group, or cyclic aliphatic group, or R 1 and R 2 together denote a chain aliphatic group which may contain an oxygen atom, provided that R 1 and R 2 cannot simultaneously denote a hydrogen atom, (C) a dithiophosphoric acid compound represented by the general formula (III) ##STR9## wherein R 3 and R 4 denote each an aliphatic group, and (D) sulfur, wherein the rubber is at least one member selected from the group consisting of styrene-butadiene rubber, butadiene rubber, isoprene rubber, acrylonitrile-butadiene rubber, chloroprene rubber, ethylene-propylene-diene terpolymer, and isopreneisobutylene rubber, and which composition contains 0.1 to 8 parts by weight of the bismaleimide compound (I), 0.1 to 8 parts by weight of the sulfenamide compound (II), 0.3 to 6 parts by weight of the dithiophosphoric acid compound (III), and 0.1 to 14 parts by weight of sulfur, each based on 100 parts by weight of rubber.
Claim 2
Dependent Claim 221 words
A rubber composition containing (A) a bismaleimide compound represented by the general formula (I) ##STR7## wherein R is a divalent acyclic aliphatic group, cyclic aliphatic group, aromatic group, or alkylaromatic group, and wherein these groups may contain a hetero atom selected from O, N and S, (B) a sulfenamide compound represented by the general formula (II) ##STR8## wherein R 1 and R 2 denote independently from each other a hydrogen atom, an acyclic aliphatic group, or cyclic aliphatic group, or R 1 and R 2 together denote a chain aliphatic group which may contain an oxygen atom, provided that R 1 and R 2 cannot simultaneously denote a hydrogen atom, (C) a dithiophosphoric acid compound represented by the general formula (III) ##STR9## wherein R 3 and R 4 denote each an aliphatic group, and (D) sulfur, wherein the rubber is at least one member selected from the group consisting of styrene-butadiene rubber, butadiene rubber, isoprene rubber, acrylonitrile-butadiene rubber, chloroprene rubber, ethylene-propylene-diene terpolymer, and isopreneisobutylene rubber, and which composition contains 0.1 to 8 parts by weight of the bismaleimide compound (I), 0.1 to 8 parts by weight of the sulfenamide compound (II), 0.3 to 6 parts by weight of the dithiophosphoric acid compound (III), and 0.1 to 14 parts by weight of sulfur, each based on 100 parts by weight of rubber.
Claim 3
Dependent Claim 26 words
A rubber composition according to claim 1, wherein the bismaleimide compound represented by the general formula (I) is N,N'-ethylenebismaleimide, N,N'-hexamethylenebismaleimide, N,N'-(m-phenylene)bismaleimide, N,N'-(p-phenylene)bismaleimide, N,N'-(p-tolylene)bismaleimide, N,N'-(methylenedi-p-phenylene)bismaleimide, or N,N'-(oxydi-p-phenylene)bismaleimide.
Claim 4
Dependent Claim 23 words
A rubber composition according to claim 1, wherein the sulfenamide compound represented by the general formula (II) is N-cyclohexyl-2-benzothiazylsulfenamide, N-oxydiethylene-2-benzothiazylsulfenamide, N-t-butyl-2-benzothiazylsulfenamide, or N,N-dicyclohexyl-2-benzothiazylsulfenamide.
Claim 5
Dependent Claim 41 words
A rubber composition according to claim 1, wherein the dithiophosphoric acid compound represented by the general formula (III) is diethyldithiophosphoric acid disulfide, diisopropyldithiophosphoric acid disulfide, di-n-propyldithiophosphoric acid disulfide, dibutyldithiophosphoric acid disulfide, dihexyldithiophosphoric acid disulfide, dicyclohexyldithiophosphoric acid disulfide, or dioctyldithiophosphoric acid disulfide.
Claim 6
Dependent Claim 18 words
A rubber composition according to claim 1, wherein the sulfur is powdered sulfur, precipitated sulfur, or insoluble sulfur.

References Cited (Backward Citations)

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US3419521A Cited
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