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US4960551A
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Method of producing modified lead barium titanate ceramic useful as PTC thermistor
Assignee: Central Glass Co Ltd
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Filing: 1988-11-21
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Granted: 1990-10-02
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Expires: 2008-11-21
Abstract
Abstract A modified lead barium titanate ceramic which has a fundamental composition of (Ba 1-x-y Sb y Pb x )TiO 3 , where x is not greater than 0.9 and usually not smaller than 0.6 and y is from 0.001 to 0.1, and has a high positive temperature coefficient of resistivity (PTCR) over a range of temperature higher than about 350° C. at the lower boundary, is produced by using a metal salt of an organic acid such as lead titanate salt of oxalic acid as the source of Pb and by adding at least one of BaCO 3 , SiO 2 , BN and TiO 2 to the raw materials of the above fundamental composition. After thermally decomposing the organic acid metal salt the mixture of the raw materials including the additive(s) is compacted and sintered. By this method the sintering is achieved with good reproducibility and with little dissipation of lead, and the obtained titanate ceramic is good and durable in the PTCR characteristics and hence is useful as the material of a PTC thermistor functioning at medium-to-high temperatures.
Inventors
- 👤 Takamitsu Eonomoto
- 👤 Hiroshi Ueda
- 👤 Midori Kawahara
- 👤 Naoki Okada
- 👤 Noboru Murata
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 08:37
CPC Classifications
C; C04; C04B; C04B35/00; C04B35/01; C04B35/46; C04B35/462; C04B35/465; C04B35/468; C04B35/4682; C04B35/4684; C04B35/472; H; H01; H01C; H01C7/00; H01C7/02
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
222 words
A method of producing a modified lead barium titanate ceramic which has a fundamental composition represented by the general formula (Ba 1-x-y Sb y Pb x )TiO 3 , where x is not greater than 0.9 and y is from 0.001 to 0.1, and has a positive temperature coefficient of resistivity over a range of temperature higher than about 350° C. at the lower boundary, the method comprising the steps of: preparing a mixure of metal-oxygen compounds, which are sufficient as the sources of Ba, Pb, SSb and Ti in said titanate ceramic and include as the source of Pb in said titanate ceramic a lead-containing compound obtained by thermal decomposition of a metal salts of an organic acid, and a combination of additives, said combination comprising BN amounting to 0.01-4.0 atom% of said fundamental composition and at least one other additive selected from the group consisting of BaCO 3 , SiO 2 and TiO 2 , the amount of said BaCO 3 being not more than 1.0 atom% of said fundamental composition, the amount of said SiO 2 being not more than 2.0 atom% of said fundamental composition, the amount of said TiO 2 being not more than 1.0 atom% of said fundamental composition; compacting the prepared mixture into a desired shape; and sintering the compacted mixture in an oxidizing atmosphere.
Claim 2
Independent Claim
222 words
A method of producing a modified lead barium titanate ceramic which has a fundamental composition represented by the general formula (Ba 1-x-y Sb y Pb x )TiO 3 , where x is not greater than 0.9 and y is from 0.001 to 0.1, and has a positive temperature coefficient of resistivity over a range of temperature higher than about 350° C. at the lower boundary, the method comprising the steps of: preparing a mixure of metal-oxygen compounds, which are sufficient as the sources of Ba, Pb, SSb and Ti in said titanate ceramic and include as the source of Pb in said titanate ceramic a lead-containing compound obtained by thermal decomposition of a metal salts of an organic acid, and a combination of additives, said combination comprising BN amounting to 0.01-4.0 atom% of said fundamental composition and at least one other additive selected from the group consisting of BaCO 3 , SiO 2 and TiO 2 , the amount of said BaCO 3 being not more than 1.0 atom% of said fundamental composition, the amount of said SiO 2 being not more than 2.0 atom% of said fundamental composition, the amount of said TiO 2 being not more than 1.0 atom% of said fundamental composition; compacting the prepared mixture into a desired shape; and sintering the compacted mixture in an oxidizing atmosphere.
Claim 3
Dependent Claim
17 words
A method according to claim 1, wherein x in the general formula is not smaller than 0.6.
Claim 4
Dependent Claim
24 words
A method according to claim 1, wherein said metal salt of an organic acid is PbTiO(C 2 O 4 ) 2 or its tetrahydrate.
Claim 5
Dependent Claim
66 words
A method according to claim 3, wherein the step of preparing said mixture comprises the sub-steps of preparing a preliminary mixture of PbTiO(C 2 O 4 ) 2 .4H 2 O, BaTiO(C 2 O 4 ) 2 .4H 2 O, Sb 2 O 3 and said at least one additive, and calcining said perliminary mixture at a temperature in the range from 500° to 900° C.
Claim 6
Dependent Claim
23 words
A method according to claim 1, wherein said compacted mixture is sintered at a temperature in the range from 1000° to 1200° C.
Claim 7
Dependent Claim
23 words
A method according to claim 1, wherein said combination of additives consists of BN, BaCO 3 , SiO 2 and TiO 2 .
References Cited (Backward Citations)
JPS5033490A
Cited
JPS60258901A
Cited
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