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US4956447A Expired / Lapsed US ⏱️ 0.0 years remaining

Rinse-added fabric conditioning compositions containing fabric sofening agents and cationic polyester soil release polymers and preferred cationic soil release polymers therefor

Assignee: Procter and Gamble Co
•
Filing: 1989-05-19
•
Granted: 1990-09-11
•
Expires: 2009-05-19
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Abstract

Abstract Rinse-added fabric conditioning compositions containing cationic soil release polymers are much more effective than similar compositions containing nonionic soil release polymers for soil release. Most of the cationic soil release polymers are new compounds comprising a hydrophobic alkylene oxide/terephthalate portion which has a low molecular weight and at least a single cationic charge under use conditions.

Inventors

  • 👤 Eugene P. Gosselink
  • 👤 Frederick E. Hardy
  • 👤 Toan Trinh

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 20:34
CPC Classifications
C; C11; C11D; C11D3/00; C11D3/16; C11D3/37; C11D3/3703; C11D3/3715; C08; C08G; C08G63/00; C08G63/68; C08G63/685; C11D3/0005; C11D3/001; C11D3/0036

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 384 words
Compound useful as cationic polymeric soil release agent having the generic empirical formula: (AO).sub.x (T).sub.y (CAT).sub.z (En).sub.q (L).sub.r (FCG).sub.s wherein: (I) Each (AO) represents an oxyalkyleneoxy group, excluding oxyalkyleneoxy groups of (E n ), containing from 2 to about 6 carbon atoms, and each "x" is from about 1 to about 80. (II) Each (T) represents a terephthaloyl group and each "y" is from about 1 to about 80; (III) Each (CAT) represents a cationic group comprising at least one moiety selected from the group consisting of: (R) m N (-) 3-m wherein each "m" is from 0 to 2; ##STR42## wherein each R group is selected from the group consisting of C 1-4 alkyl groups, C 1-4 hydroxyalkyl groups, C 2-4 alkylene groups, C 2-4 oxyalkylene groups, phenyl, phenyl C 1-4 alkyl groups, hydrogen, wherein two R groups can be joined to form cyclic structures, and wherein each A.sup.⊖ is any compatible anion, and each "z" is selected from 1 to about 100 to provide the cationic charge to the polymer; (IV) Each (E n ) represents a poly(oxyethylene)oxy group --(OCH 2 CH 2 ) n O-- wherein each "n" is from 2 to about 200, and each q is less than about 25; (V) Each (L), when present, represents a linking group comprising at least one hydrocarbylene group having from 2 to about 4 covalent bonds and containing from one to about 10 carbon atoms and 0 to 4 groups selected from the group consisting of: ##STR43## and mixtures thereof and each "r" is a number from 0 to about 40; and (VI) Each Formula Completing Group (FCG), when present, is selected from the group consisting of: (a) H--; (b) --OH; (c) C 1-18 alkyl, alkoxy, or hydroxy alkyl groups, except that when the molecular weight of the compound is above about 10,000, the maximum number of carbon atoms that is in each FCG is about 4; (d) --C(O)OH, and (e) anionic groups neutralized with a compatible cation, and each "s" is a number from to a number sufficient to complete the formula; and wherein the molecular weight of the compound is less than about 50,000, the net cationic charge of the compound is at least about one per 15,000 molecular weight units and the compound is essentially free of hydrazide groups.
Claim 2
Dependent Claim 384 words
Compound useful as cationic polymeric soil release agent having the generic empirical formula: (AO).sub.x (T).sub.y (CAT).sub.z (En).sub.q (L).sub.r (FCG).sub.s wherein: (I) Each (AO) represents an oxyalkyleneoxy group, excluding oxyalkyleneoxy groups of (E n ), containing from 2 to about 6 carbon atoms, and each "x" is from about 1 to about 80. (II) Each (T) represents a terephthaloyl group and each "y" is from about 1 to about 80; (III) Each (CAT) represents a cationic group comprising at least one moiety selected from the group consisting of: (R) m N (-) 3-m wherein each "m" is from 0 to 2; ##STR42## wherein each R group is selected from the group consisting of C 1-4 alkyl groups, C 1-4 hydroxyalkyl groups, C 2-4 alkylene groups, C 2-4 oxyalkylene groups, phenyl, phenyl C 1-4 alkyl groups, hydrogen, wherein two R groups can be joined to form cyclic structures, and wherein each A.sup.⊖ is any compatible anion, and each "z" is selected from 1 to about 100 to provide the cationic charge to the polymer; (IV) Each (E n ) represents a poly(oxyethylene)oxy group --(OCH 2 CH 2 ) n O-- wherein each "n" is from 2 to about 200, and each q is less than about 25; (V) Each (L), when present, represents a linking group comprising at least one hydrocarbylene group having from 2 to about 4 covalent bonds and containing from one to about 10 carbon atoms and 0 to 4 groups selected from the group consisting of: ##STR43## and mixtures thereof and each "r" is a number from 0 to about 40; and (VI) Each Formula Completing Group (FCG), when present, is selected from the group consisting of: (a) H--; (b) --OH; (c) C 1-18 alkyl, alkoxy, or hydroxy alkyl groups, except that when the molecular weight of the compound is above about 10,000, the maximum number of carbon atoms that is in each FCG is about 4; (d) --C(O)OH, and (e) anionic groups neutralized with a compatible cation, and each "s" is a number from to a number sufficient to complete the formula; and wherein the molecular weight of the compound is less than about 50,000, the net cationic charge of the compound is at least about one per 15,000 molecular weight units and the compound is essentially free of hydrazide groups.
Claim 3
Dependent Claim 21 words
The compound of claim 1 wherein said (AO) group is selected from the group consisting of: oxyethyleneoxy, oxy-1,2-propyleneoxy, and mixtures thereof.
Claim 4
Dependent Claim 75 words
The compound of claim 2 wherein x is from about 1 to about 25, y is from 1 to about 25, n is from about 6 to about 100, q is less than about 10, (L) contains from about to about 4 carbon atoms, r is from about 2 to about 20, the net cationic charge is at least about 1 per 10,000 molecular weight units and the molecular weight is less than about 20,000.
Claim 5
Dependent Claim 14 words
The compound of claim 3 wherein the molecular weight is less than about 10,000.
Claim 6
Dependent Claim 19 words
The compound of claim 4 wherein the cationic charge is at least about 1 per 5,000 molecular weight units.
Claim 7
Dependent Claim 25 words
The compound of claim 2 wherein the cationic charge is from about 1 per 150 molecular weight units to about per 3,000 molecular weight units.
Claim 8
Dependent Claim 16 words
The compound of claim 6 wherein the molecular weight is from about 800 lo about 10,000.
Claim 9
Dependent Claim 51 words
The compound of claim 2 wherein each x and y is from about 1.25 to about 15, n is from about 10 to about 80, q is from about 1 to about 5, (L) contains from 1 to about 2 carbon atoms, and the molecular weight is less than about 20,000.
Claim 10
Dependent Claim 14 words
The compound of claim 8 wherein the molecular weight is less than about 10,000.
Claim 11
Dependent Claim 19 words
The compound of claim 9 wherein the cationic charge is at least about 1 per 5,000 molecular weight units.
Claim 12
Dependent Claim 25 words
The compound of claim 8 wherein the cationic charge is from about 1 per 150 molecular weight units to about per 3,000 molecular weight units.
Claim 13
Dependent Claim 16 words
The compound of claim 5 wherein the molecular weight is from about 800 to about 10,000.
Claim 14
Dependent Claim 13 words
The compound of claim 3 wherein (CAT) is (R) m N(-) 3-m .
Claim 15
Dependent Claim 44 words
The compound of claim 13 wherein x is from about 1.25 to about 15, y is from about 1.25 to about 15, n is from 10 to about 80, q is less than about 5, and r is from about 2 to about 10.
Claim 16
Dependent Claim 24 words
The compound of claim 14 wherein (AO) is oxyethyleneoxy and the net cationic charge is at least about 1 per 5,000 molecular weight units.
Claim 17
Dependent Claim 14 words
The compound of claim 14 wherein (AO) is a mixture of oxyethyleneoxy and oxypropyleneoxy.
Claim 18
Dependent Claim 27 words
The compound of claim 16 wherein the net cationic charge is from about 1 per 150 molecular weight units to about 1 per 3,000 molecular weight units.
Claim 19
Dependent Claim 16 words
The compound of claim 17 wherein the molecular weight is from about 800 to about 10,000.
Claim 20
Dependent Claim 14 words
The compound of claim 3 wherein (CAT) is (R) m N.sup.⊕ (-) 4-m A.sup.⊖.
Claim 21
Dependent Claim 44 words
The compound of claim 19 wherein x is from about 1.25 to about 15, y is from about 1.25 to about 15, n is from 10 to about 80, q is less than about 5, and r is from about 2 to about 10.
Claim 22
Dependent Claim 24 words
The compound of claim 20 wherein (AO) is oxyethyleneoxy and the net cationic charge is at least about 1 per 5,000 molecular weight units.
Claim 23
Dependent Claim 14 words
The compound of claim 20 wherein (AO) is a mixture of oxyethyleneoxy and oxypropyleneoxy.
Claim 24
Dependent Claim 27 words
The compound of claim 22 wherein the net cationic charge is from about 1 per 150 molecular weight units to about 1 per 3,000 molecular weight units.
Claim 25
Dependent Claim 16 words
The compound of claim 23 wherein the molecular weight is from about 800 to about 10,000.
Claim 26
Dependent Claim 9 words
The compound of claim 20 where (AO) is oxypropyleneoxy.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-09-10 1994-03-12 1994-09-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-09-10 1998-03-12 1998-09-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-09-10 2002-03-12 2002-09-11 $7700.00 Window Closed / Lapsed

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