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US4956230A Expired / Lapsed US ⏱️ 0.0 years remaining

Ink receptive transparency sheet

Assignee: 3M Co
•
Filing: 1988-02-02
•
Granted: 1990-09-11
•
Expires: 2008-02-02
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Abstract

Abstract Transparent sheet for use with ink jet printers and pen plotters which utilize hydrophilic solvent-based inks. The sheet comprises a transparent backing bearing on at least one major surface thereof a transparent coating formed of a blend of at least one hydrophilic polymer containing a carbonylamido functional group and at least one hydrophobic polymer substantially free of acidic functional groups, hydroxyl groups, >NH groups and --NH 2 groups.

Inventors

  • 👤 Donald W. Edwards
  • 👤 Armin J. Paff
  • 👤 Daniel C. Duan

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-10 02:06
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/50; B41M5/52; B41M5/502; B41M5/508; B41M5/5236; B41M5/5254; B41M5/5263; B41M5/5272; B41M5/529; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507; Y10T428/31533; Y10T428/31725; Y10T428/31855

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 139 words
Transparent sheet consisting of a polymeric backing bearing on at least one major surface thereof an ink receptive layer comprising a blend of at least one hydrophobic polymer substantially free of acidic functional groups, hydroxyl groups, >NH groups, and --NH 2 groups and at least one hydrophilic polymer containing carbonylamido groups, said carbonylamido groups selected from the group consisting of ##STR2## where R 1 and R 2 independently represent alkyl groups, or R 1 and R 2 together can be represented by (--CH 2 --) x where x is an integer from two to five, or R 2 can be hydrogen provided that it is bonded to a carbon atom, R 3 represents hydrogen or alkyl group having from one to six carbon atoms, and R 4 represents hydrogen or alkyl group, said layer capable of receiving aqueous-based inks.
Claim 2
Dependent Claim 139 words
Transparent sheet consisting of a polymeric backing bearing on at least one major surface thereof an ink receptive layer comprising a blend of at least one hydrophobic polymer substantially free of acidic functional groups, hydroxyl groups, >NH groups, and --NH 2 groups and at least one hydrophilic polymer containing carbonylamido groups, said carbonylamido groups selected from the group consisting of ##STR2## where R 1 and R 2 independently represent alkyl groups, or R 1 and R 2 together can be represented by (--CH 2 --) x where x is an integer from two to five, or R 2 can be hydrogen provided that it is bonded to a carbon atom, R 3 represents hydrogen or alkyl group having from one to six carbon atoms, and R 4 represents hydrogen or alkyl group, said layer capable of receiving aqueous-based inks.
Claim 3
Dependent Claim 13 words
The sheet of claim 1 wherein said backing is transmissive to visible light.
Claim 4
Dependent Claim 15 words
The sheet of claim 1 wherein R 1 contains from 1 to 8 carbon atoms.
Claim 5
Dependent Claim 18 words
The sheet of claim 3 wherein R 1 represents an alkyl group having 1 to 3 carbon atoms.
Claim 6
Dependent Claim 15 words
The sheet of claim 1 wherein R 2 contains from 1 to 8 carbon atoms.
Claim 7
Dependent Claim 18 words
The sheet of claim 5 wherein R 2 represents an alkyl group having 1 to 3 carbon atoms.
Claim 8
Dependent Claim 15 words
The sheet of claim 1 wherein R 4 contains from 1 to 8 carbon atoms.
Claim 9
Dependent Claim 18 words
The sheet of claim 7 wherein R 4 represents an alkyl group having 1 to 3 carbon atoms.
Claim 10
Dependent Claim 39 words
The sheet of claim 1 wherein said hydrophobic polymer is selected from the group consisting of polyesters, homopolymers and copolymers of vinyl chloride, polysulfone resins, polyacrylonitrile and copolymers thereof, poly(benzyl methacrylate), poly(phenyl methacrylate), poly(vinyl cinnamate), poly(vinylidene fluoride), and polycarbonate.
Claim 11
Dependent Claim 12 words
The sheet of claim 9 wherein said hydrophobic polymer is a polyester.
Claim 12
Dependent Claim 12 words
The sheet of claim 9 wherein said hydrophobic polymer is a polysulfone.
Claim 13
Dependent Claim 13 words
The sheet of claim 9 wherein said hydrophobic polymer is a poly(vinyl chloride).
Claim 14
Dependent Claim 30 words
The sheet of claim 1 wherein said hydrophilic polymer is selected from the group consisting of poly(N-vinyl pyrrolidone), poly(N,N-dimethyl acrylamide), poly(methyloxazoline), poly(ethyloxazoline), poly(N-vinyl valerolactam), poly(N-vinyl caprolactam), and poly(N-vinyl N-methyl acetamide).
Claim 15
Dependent Claim 12 words
The sheet of claim 13 wherein said hydrophilic polymer is poly(N-vinyl pyrrolidone).
Claim 16
Dependent Claim 39 words
The sheet of claim 1 wherein said hydrophilic polymer comprises from about 5 to about 99 parts by weight of the blend and said hydrophobic polymer comprises from about 95 to about 1 part by weight of the blend.
Claim 17
Dependent Claim 39 words
The sheet of claim 1 wherein said hydrophilic polymer comprises from about 40 to about 95 parts by weight of the blend and said hydrophobic polymer comprises from about 60 to about 5 parts by weight of the blend.
Claim 18
Dependent Claim 23 words
The sheet of claim 1 wherein said carbonylamido functional group comprises from about 20% to about 60% by weight of the hydrophilic polymer.
Claim 19
Dependent Claim 22 words
The sheet of claim 1 wherein said ink-receptive layer has a coating weight of no less than 0.2 grams per square foot.
Claim 20
Dependent Claim 23 words
The sheet of claim 1 wherein said ink-receptive layer has a coating weight less than or equal to 2.0 grams per square foot.

References Cited (Backward Citations)

US4301195A Cited
GB2050866A Cited
US4371582A Cited
US4460637A Cited
US4481244A Cited
EP0125113A2 Cited
GB2155815A Cited
US4636805A Cited
US4642247A Cited
US4547405A Cited
US4868118A Cited
US4781978A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-09-10 1994-03-12 1994-09-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-09-10 1998-03-12 1998-09-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-09-10 2002-03-12 2002-09-11 $7700.00 Window Closed / Lapsed

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