Orthopaedic structures from polymeric materials

Claim 1

A method of producing an orthopaedic structure which is substantially transparent, formable and reformable at temperatures of from about 45° to about 65° C., essentially rigid at ambient temperatures of below about 30° C. and which has a desirable balance of strength properties, which method comprises: (a) providing a sheet of polymeric material, (b) heating said sheet to a temperature of from about 45° to about 65° C., (c) shaping said heated sheet to form the orthopaedic structure about the desired part of the body, and (d) allowing the so-shaped orthopaedic structure to cool to below about 30° C., wherein said polymeric material comprises as the essential components, all parts being parts by weight, (A) from about 55 to 70 parts of styrene, (B) from 0 to about 10 parts of methyl methacrylate, (C) from about 15 to about 40 parts of a C 2 -C 8 alkyl acrylate and (D) from about 2 to about 15 parts of one or more block copolymer selected from the group consisting of styrene-butadiene, styrene-butadiene-styrene and styrene-isoprene block copolymers having a weight average molecular weight of not less than about 75,000 and a styrene content of about 20 to about 50 weight per cent, for a total of 100 parts, said polymeric material being produced by the polymerization of A, B and C in the presence of D to produce a polymeric material containing said block copolymer having grafted thereto at least a portion of A,B, and C.

Claim 2

A method of producing an orthopaedic structure which is substantially transparent, formable and reformable at temperatures of from about 45° to about 65° C., essentially rigid at ambient temperatures of below about 30° C. and which has a desirable balance of strength properties, which method comprises: (a) providing a sheet of polymeric material, (b) heating said sheet to a temperature of from about 45° to about 65° C., (c) shaping said heated sheet to form the orthopaedic structure about the desired part of the body, and (d) allowing the so-shaped orthopaedic structure to cool to below about 30° C., wherein said polymeric material comprises as the essential components, all parts being parts by weight, (A) from about 55 to 70 parts of styrene, (B) from 0 to about 10 parts of methyl methacrylate, (C) from about 15 to about 40 parts of a C 2 -C 8 alkyl acrylate and (D) from about 2 to about 15 parts of one or more block copolymer selected from the group consisting of styrene-butadiene, styrene-butadiene-styrene and styrene-isoprene block copolymers having a weight average molecular weight of not less than about 75,000 and a styrene content of about 20 to about 50 weight per cent, for a total of 100 parts, said polymeric material being produced by the polymerization of A, B and C in the presence of D to produce a polymeric material containing said block copolymer having grafted thereto at least a portion of A,B, and C.

Claim 3

A method of producing an orthopaedic structure which is substantially transparent, formable and reformable at temperatures of from about 45° to about 65° C., essentially rigid at ambient temperatures of below about 30° C. and which has a desirable balance of strength properties, which method comprises: (a) providing a polymeric material in the shape of an orthopaedic pre-form of standard shape and size, (b) heating said pre-form to a temperature of from about 45° to about 65° C., (c) fitting said heated pre-form about the desired part of the body, (d) adjusting said heated pre-form to the desired shape about the desired part of the body, (e) optionally removing surplus polymeric material from said shaped pre-form, and (f) allowing the shaped pre-form to cool to below about 30° C., wherein said polymeric material comprises as the essential components, all parts being parts by weight, (A) from about 55 to about 70 parts of styrene, (B) from 0 to about 10 parts of methyl methacrylate, (C) from about 15 to about 40 parts of C 2 -C 8 alkyl acrylate and (D) from about 2 to about 15 parts of one or more block copolymer selected from the group consisting of styrene-butadiene, styrene-butadiene-styrene and styrene-isoprene block copolymers having a weight average molecular weight of not less than about 75,000 and a styrene content of about 20 to about 50 weight per cent, for a total of 100 parts, said polymeric material being produced by the polymerization of A, B and C in the presence of D to produce a polymeric material containing said block copolymer having grafted thereto at least a portion of A, B, and C.

Claim 4

A method of producing an orthopaedic structure which is substantially transparent, formable and reformable at temperatures of from about 45° to about 65° C., essentially rigid at ambient temperatures of below about 30° C. and which has a desirable balance of strength properties, which method comprises: (a) providing a polymeric material in the shape of an orthopaedic pre-form of standard shape and size, (b) heating said pre-form to a temperature of from about 45° to about 65° C., (c) fitting said heated pre-form about the desired part of the body, (d) adjusting said heated pre-form to the desired shape about the desired part of the body, (e) optionally removing surplus polymeric material from said shaped pre-form, and (f) allowing the shaped pre-form to cool to below about 30° C., wherein said polymeric material comprises as the essential components, all parts being parts by weight, (A) from about 55 to about 70 parts of styrene, (B) from 0 to about 10 parts of methyl methacrylate, (C) from about 15 to about 40 parts of C 2 -C 8 alkyl acrylate and (D) from about 2 to about 15 parts of one or more block copolymer selected from the group consisting of styrene-butadiene, styrene-butadiene-styrene and styrene-isoprene block copolymers having a weight average molecular weight of not less than about 75,000 and a styrene content of about 20 to about 50 weight per cent, for a total of 100 parts, said polymeric material being produced by the polymerization of A, B and C in the presence of D to produce a polymeric material containing said block copolymer having grafted thereto at least a portion of A, B, and C.