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US4948529A Expired / Lapsed US ⏱️ 0.0 years remaining

Stable high resistance transparent coating

Assignee: Andus Corp
•
Filing: 1988-06-28
•
Granted: 1990-08-14
•
Expires: 2008-06-28
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Abstract

Abstract A stable high resistant transparent coating is formed by choosing an undoped wide band gap semiconducting oxide, and by forming a film from elements constituting the undoped oxide and from a dopant which is chosen so as to form a doped wide band gap semiconducting oxide, the doped oxide having an electrical resistance greater than the undoped oxide, the electrical resistance of the doped oxide being such that it equals an optimum value when the coating composition is inherently stable.

Inventors

  • 👤 Ian T. Ritchie
  • 👤 Wilfred C. Kittler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 07:07
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/0202; G03G5/04; G03G5/08; G03G5/082

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 109 words
A method of forming a partially transparent conductive coating, comprising the steps of: choosing an undoped wide band gap semiconducting oxide; forming a film from elements constituting the undoped oxide and from a dopant so as to form a doped wide band gap semiconducting oxide, the doped oxide having an electrical resistance greater than the undoped oxide, the doped oxide being one whose electrical resistance first reaches an interim maximum and then reaches an interim minimum as an oxygen concentration thereof is varied and increased, the oxygen concentration of the doped oxide being within ±5% of an oxygen concentration yielding the interim minimum electrical resistance of the doped oxide.
Claim 2
Independent Claim 109 words
A method of forming a partially transparent conductive coating, comprising the steps of: choosing an undoped wide band gap semiconducting oxide; forming a film from elements constituting the undoped oxide and from a dopant so as to form a doped wide band gap semiconducting oxide, the doped oxide having an electrical resistance greater than the undoped oxide, the doped oxide being one whose electrical resistance first reaches an interim maximum and then reaches an interim minimum as an oxygen concentration thereof is varied and increased, the oxygen concentration of the doped oxide being within ±5% of an oxygen concentration yielding the interim minimum electrical resistance of the doped oxide.
Claim 3
Dependent Claim 15 words
The method of claim 1, the film consisting essentially of the elements and the dopant.
Claim 4
Dependent Claim 23 words
The method of claim 1, the doped oxide having an electrical resistance more than an order of magnitude greater than the undoped oxide.
Claim 5
Dependent Claim 23 words
The method of claim 1, the doped oxide having an electrical resistance more than two orders of magnitude greater than the undoped oxide.
Claim 6
Dependent Claim 23 words
The method of claim 1, the doped oxide having an electrical resistance more than three orders of magnitude greater than the undoped oxide.
Claim 7
Dependent Claim 38 words
The method of claim 1, the wide band gap semiconducting oxide including a first metal, a dopant used for doping comprising a second metal, the second metal having an odd number of electrons different than the first metal.
Claim 8
Dependent Claim 23 words
The method of claim 1, the doped oxide oxygen concentration being within ±2% of the oxygen concentration yielding the interim minimum electrical resistance.
Claim 9
Dependent Claim 25 words
The method of claim 1, the doped oxide being produced by sputtering a two metal composite or alloy target in a partial atmosphere of oxygen.
Claim 10
Dependent Claim 21 words
The method of claim 6, the first metal being selected from the group consisting of tin, indium, zinc, lead, and cadmium.
Claim 11
Dependent Claim 11 words
The method of claim 9, the first metal consisting of tin.
Claim 12
Dependent Claim 12 words
The method of claim 9, the second metal being copper or aluminum.
Claim 13
Dependent Claim 12 words
The method of claim 10, the second metal being copper or aluminum.
Claim 14
Dependent Claim 31 words
The method of claim 9, the second metal being selected from the group consisting of copper, aluminum, indium, gallium, boron, thallium, silver, gold, nickel, palladium, platinum, zinc, cadmium, mercury, and vanadium.
Claim 15
Dependent Claim 101 words
A high resistance partially transparent conductive coating, comprising: a wide band gap semiconducting oxide, an undoped composition thereof having a first electrical resistance, the oxide being doped so as to form a doped wide band gap semiconducting oxide whose electrical resistance is increased by an amount greater than an order of magnitude over the undoped composition, the doped oxide being one whose electrical resistance first reaches an interim maximum and then reaches an interim minimum as its oxygen concentration is increased, an oxygen concentration of the doped oxide being within ±5% of an oxygen concentration yielding the interim minimum electrical resistance.
Claim 16
Dependent Claim 101 words
A high resistance partially transparent conductive coating, comprising: a wide band gap semiconducting oxide, an undoped composition thereof having a first electrical resistance, the oxide being doped so as to form a doped wide band gap semiconducting oxide whose electrical resistance is increased by an amount greater than an order of magnitude over the undoped composition, the doped oxide being one whose electrical resistance first reaches an interim maximum and then reaches an interim minimum as its oxygen concentration is increased, an oxygen concentration of the doped oxide being within ±5% of an oxygen concentration yielding the interim minimum electrical resistance.
Claim 17
Dependent Claim 16 words
The coating of claim 14, the doped oxide being at least 70% transparent to visible light.
Claim 18
Dependent Claim 59 words
The coating of claim 14, a metal forming the oxide being chosen from the group consisting of tin, indium, zinc, cadmium and lead, a dopant used for doping the wide band gap semiconducting oxide being a metal chosen from the group consisting of copper, aluminum, indium, gallium, boron, thallium, silver, gold, nickel, palladium, platinum, zinc, cadmium, mercury, and vanadium.

References Cited (Backward Citations)

US4194994A Cited
FR2430629A1 Cited
US4250228A Cited
GB2025915A Cited
US4409134A Cited
DE3639508A1 Cited
US4816183A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-08-13 1994-02-12 1994-08-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-08-13 1998-02-12 1998-08-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-08-13 2002-02-12 2002-08-14 $7700.00 Window Closed / Lapsed

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