← Back to Patent Explorer
US4945036A Expired / Lapsed US ⏱️ 0.0 years remaining

Silver halide photosensitive material

Assignee: Fujifilm Holdings Corp
•
Filing: 1989-05-31
•
Granted: 1990-07-31
•
Expires: 2009-05-31
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A silver halide photosensitive material is described, comprising two or more monodisperse silver halide emulsions of different average grain size on a support, wherein at least one of the said monodisperse silver halide emulsions has an average grain size of at least 0.7 mu m, and at least one of the silver halide emulsions has a smaller average grain size than the other, the average grain size of the silver halide emulsion as a whole being within the range of from 0.33 to 0.54 mu m, with a coated silver weight of from 2.3 to 3.8 g/m2, and which contains a sensitizing dye represented by formula (I) <IMAGE> (I) wherein Z and Z1 each represents a group of non-metallic atoms forming a thiazole nucleus, a benzothiazole nucleus, or a benzoxazole nucleus; R0 represents an alkyl group having from 1 to 6 carbon atoms, an allyl group, or an aralkyl group; R and R1 each represents an alkyl group or an aryl group; L, L1, and L2 each represents a methine group; X represents an anion; and m represents 0 or 1, and an internal salt is formed when m is 0.

Inventors

  • 👤 Naoki Arai
  • 👤 Kazuo Kagawa

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 18:35
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/10; G03C1/12; G03C1/26; G03C1/0051; G03C1/14; G03C1/18; G03C1/035; G03C2001/03564; G03C2001/0357; G03C2001/03594; G03C7/00; G03C7/30; G03C7/3022; G03C2007/3025; Y; Y10; Y10S; Y10S430/00; Y10S430/167

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 193 words
A silver halide photosensitive material comprising two or more monodisperse silver halide emulsions of different average grain size on a support, wherein at least one of said monodisperse silver halide emulsions has an average grain size of at least 0.7 μm, and at least one of the silver halide emulsions has a smaller average grain size than the other, the average grain size of the silver halide emulsion as a whole being within the range of from 0.33 to 0.54 μm, with a coated silver weight of from 2.3 to 3.8 g/m 2 , and which contains a sensitizing dye represented by formula (I) ##STR9## wherein Z and Z 1 each represents a group of non-metallic atoms forming a thiazole nucleus, a benzothiazole nucleus, or a benzoxazole nucleus; R 0 represents an alkyl group having from 1 to 6 carbon atoms, an allyl group, or an aralkyl group; R and R 1 each represents an alkyl group or an aryl group; L, L 1 , and L 2 each represents a methine group; X represents an anion; and m represents 0 or 1, and an internal salt is formed when m is 0.
Claim 2
Dependent Claim 193 words
A silver halide photosensitive material comprising two or more monodisperse silver halide emulsions of different average grain size on a support, wherein at least one of said monodisperse silver halide emulsions has an average grain size of at least 0.7 μm, and at least one of the silver halide emulsions has a smaller average grain size than the other, the average grain size of the silver halide emulsion as a whole being within the range of from 0.33 to 0.54 μm, with a coated silver weight of from 2.3 to 3.8 g/m 2 , and which contains a sensitizing dye represented by formula (I) ##STR9## wherein Z and Z 1 each represents a group of non-metallic atoms forming a thiazole nucleus, a benzothiazole nucleus, or a benzoxazole nucleus; R 0 represents an alkyl group having from 1 to 6 carbon atoms, an allyl group, or an aralkyl group; R and R 1 each represents an alkyl group or an aryl group; L, L 1 , and L 2 each represents a methine group; X represents an anion; and m represents 0 or 1, and an internal salt is formed when m is 0.
Claim 3
Dependent Claim 50 words
A silver halide photosensitive material as in claim 1, wherein said monodisperse silver halide emulsion having an average grain size of at least 0.7 μm is present in an amount of from 10 to 50%, based on the total coated silver weight of the whole of the silver halide emulsion.
Claim 4
Dependent Claim 50 words
A silver halide photosensitive material as in claim 1, wherein said monodisperse silver halide emulsion having an average grain size of at least 0.7 μm is present in an amount of from 20 to 40%, based on the total coated silver weight of the whole of the silver halide emulsion.
Claim 5
Dependent Claim 45 words
A silver halide photosensitive material as in claim 1, wherein the monodisperse silver halide emulsions have a ratio of (100) plane/(111) plane of a value of at least 1/1 and contain from 10 -8 to 10 -5 mol of iridium ion per mol of silver.
Claim 6
Dependent Claim 23 words
A silver halide photosensitive material as in claim 4, wherein the ratio of (100) plane/(111) plane has a value of at least 2/1.
Claim 7
Dependent Claim 23 words
A silver halide photosensitive material as in claim 4, wherein the ratio of (100) plane/(111) plane has a value of at least 4/1.
Claim 8
Dependent Claim 21 words
A silver halide photosensitive material as in claim 4, wherein the ratio of (100) plane/(111) plane has a value of ∞.
Claim 9
Dependent Claim 23 words
A silver halide photosensitive material as in claim 4, wherein at least 50 weight % of said silver halide grains have said ratio.
Claim 10
Dependent Claim 23 words
A silver halide photosensitive material as in claim 5, wherein at least 60 weight % of said silver halide grains have said ratio.
Claim 11
Dependent Claim 23 words
A silver halide photosensitive material as in claim 6, wherein at least 80 weight % of said silver halide grains have said ratio.
Claim 12
Independent Claim 243 words
A method for processing a silver halide photosensitive material in an automatic processor with a procedure which includes at least development, fixing, water washing or stabilization and drying, said silver halide photosensitive material being a silver halide photosensitive material comprising two or more monodisperse silver halide emulsions of different average grain size on a support, wherein at least one of said monodisperse silver halide emulsions has an average grain size of at least 0.7 μm, and at least one of the silver halide emulsions has a smaller average grain size than the other, the average grain size of the silver halide emulsion as a whole being within the range of from 0.33 to 0.54 μm, with a coated silver weight of from 2.3 to 3.8 g/m 2 , and which contains a sensitizing dye represented by formula (I) ##STR10## wherein Z and Z 1 each represents a group of non-metallic atoms forming a thiazole nucleus, a benzothiazole nucleus, or a benzoxazole nucleus; R 0 represents an alkyl group having from 1 to 6 carbon atoms, an allyl group, or an aralkyl group; R and R 1 each represents an alkyl group or an aryl group; L, L 1 , and L 2 each represents a methine group; X represents an anion; and m represents 0 or 1, and an internal salt is formed when m is 0, wherein the whole process from the development through to the drying is completed within 75 seconds.
Claim 13
Independent Claim 243 words
A method for processing a silver halide photosensitive material in an automatic processor with a procedure which includes at least development, fixing, water washing or stabilization and drying, said silver halide photosensitive material being a silver halide photosensitive material comprising two or more monodisperse silver halide emulsions of different average grain size on a support, wherein at least one of said monodisperse silver halide emulsions has an average grain size of at least 0.7 μm, and at least one of the silver halide emulsions has a smaller average grain size than the other, the average grain size of the silver halide emulsion as a whole being within the range of from 0.33 to 0.54 μm, with a coated silver weight of from 2.3 to 3.8 g/m 2 , and which contains a sensitizing dye represented by formula (I) ##STR10## wherein Z and Z 1 each represents a group of non-metallic atoms forming a thiazole nucleus, a benzothiazole nucleus, or a benzoxazole nucleus; R 0 represents an alkyl group having from 1 to 6 carbon atoms, an allyl group, or an aralkyl group; R and R 1 each represents an alkyl group or an aryl group; L, L 1 , and L 2 each represents a methine group; X represents an anion; and m represents 0 or 1, and an internal salt is formed when m is 0, wherein the whole process from the development through to the drying is completed within 75 seconds.

References Cited (Backward Citations)

US3941595A Cited
US4388401A Cited
US4659646A Cited
US4677052A Cited
US4689292A Cited
US4746593A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-07-30 1994-01-29 1994-07-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-07-30 1998-01-29 1998-07-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-07-30 2002-01-29 2002-07-31 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag