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US4944993A Expired / Lapsed US ⏱️ 0.0 years remaining

Toughened rubber based hot melt adhesive compositions for disposable applications

Assignee: National Starch and Chemical Investment Holding Corp
•
Filing: 1988-08-17
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Granted: 1990-07-31
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Expires: 2008-08-17
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Abstract

Abstract Hot melt adhesive compositions suitable for disposable constructions are prepared from tackifying resins, oil diluent and a substantially radial styrene-butadiene block copolymer, the copolymer having a styrene content greater than about 35% by weight, a molulus at 300% elongation of at least 4.5 MPa and a solution viscosity less than about 1000 cps.

Inventors

  • 👤 Gary Raykovitz
  • 👤 Robert Schmidt
  • 👤 Paul Puletti

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 06:41
CPC Classifications
B; B32; B32B; B32B7/00; B32B7/04; B32B7/12; A; A61; A61L; A61L15/00; A61L15/16; A61L15/42; A61L15/58; A61L15/585; B32B27/00; B32B27/06; B32B27/08; B32B27/32; B32B37/00; B32B37/12; Y; Y10; Y10T; Y10T428/00; Y10T428/28; Y10T428/31504; Y10T428/31855; Y10T428/31909; Y10T428/31913; Y10T428/31917; Y10T428/31931; Y10T442/00; Y10T442/20; Y10T442/2738; Y10T442/2746; Y10T442/2861; Y10T442/291; Y10T442/2918

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 82 words
A hot melt adhesive composition suitable for disposable constructions consisting essentially of: (a) 10 to 40% by weight of a substantially radial styrene-butadiene block copolymer having a styrene content greater than 35% by weight, a modulus at 300% elongation of at least 4.5 MPa and a solution viscosity less than 1000 cps; (b) 20 to 65% by weight of at least one compatible tackifying resin; (c) 0.1 to 4% by weight stabilizer; the remainder (to 100%) comprising at least one oil diluent.
Claim 2
Dependent Claim 82 words
A hot melt adhesive composition suitable for disposable constructions consisting essentially of: (a) 10 to 40% by weight of a substantially radial styrene-butadiene block copolymer having a styrene content greater than 35% by weight, a modulus at 300% elongation of at least 4.5 MPa and a solution viscosity less than 1000 cps; (b) 20 to 65% by weight of at least one compatible tackifying resin; (c) 0.1 to 4% by weight stabilizer; the remainder (to 100%) comprising at least one oil diluent.
Claim 3
Dependent Claim 35 words
The adhesive of claim 1 wherein the styrene butadiene copolymer contains 37 to 40% styrene, has a modulus at 300% elongation of at least 4.6 MPa and a solution viscosity of 640 to 750 cps.
Claim 4
Dependent Claim 99 words
The adhesive of claim 1 wherein the tackifying resin is selected from the group consisting of natural and modified rosins; glycerol and pentaerythritol esters of natural and modified rosins; copolymers and terpolymers of natural terpenes; polyterpene resins having a softening point, as determined by ASTM method E28-58T, of from about 80° to 150° C.; phenolic modified terpene resins and hydrogenated derivatives thereof; aliphatic petroleum hydrocarbon resins having a Ball and Ring softening point of from about 70° to 135° C.; aromatic petroleum hydrocarbon resins and the hydrogenated derivatives thereof; and alicyclic petroleum hydrocarbon resins and the hydrogenated derivatives thereof.
Claim 5
Dependent Claim 24 words
The hot melt adhesive composition of claim 1 wherein the styrene butadiene copolymer is present in an amount of 15 to 25% by weight.
Claim 6
Dependent Claim 102 words
A disposable article comprising at least one polyethylene or polypropylene substrate bonded to at least one tissue, elastic, non-woven, polyethylene or polypropylene substrate using a hot melt adhesive composition consisting essentially of: (a) 10 to 40% by weight of a substantially radial styrene-butadiene bench copolymer having a styrene content greater than 35% by weight, a modulus at 300% elongation of at least 4.5 MPa and a solution viscosity less than 1000 cps; (b) 20 to 65% by weight of at least one compatible tackifying resin; (c) 0.1 to 4% by weight stabilizer; the remainder (to 100%) comprising at least one oil diluent.
Claim 7
Dependent Claim 102 words
A disposable article comprising at least one polyethylene or polypropylene substrate bonded to at least one tissue, elastic, non-woven, polyethylene or polypropylene substrate using a hot melt adhesive composition consisting essentially of: (a) 10 to 40% by weight of a substantially radial styrene-butadiene bench copolymer having a styrene content greater than 35% by weight, a modulus at 300% elongation of at least 4.5 MPa and a solution viscosity less than 1000 cps; (b) 20 to 65% by weight of at least one compatible tackifying resin; (c) 0.1 to 4% by weight stabilizer; the remainder (to 100%) comprising at least one oil diluent.
Claim 8
Dependent Claim 39 words
The disposable article of claim 5 wherein the styrene butadiene wherein the styrene butadiene copolymer contains 37 to 40% styrene, has a modulus at 300% elongation of at least 4.6 and a solution viscosity of 640 to 750 cps.
Claim 9
Dependent Claim 104 words
A disposable article of the multi-line construction comprising at least one polyethylene or polypropylene substrate bonded to at least one tissue, non-woven, polyethylene or polypropylene substrate using a hot multi-adhesive composition consisting essentially of: (a) 10 to 40% by weight of a substantially radial styrene-butadiene bench copolymer having a styrene content greater than 35% by weight, a modulus at 300% elongation of at least 4.5 MPa and a solution viscosity less than 1000 cps; (b) 20 to 65% by weight of at least one compatible tackifying resin; (c) 0.1 to 4% by weight stabilizer; the remainder (to 100%) comprising at least one oil diluent.
Claim 10
Dependent Claim 104 words
A disposable article of the multi-line construction comprising at least one polyethylene or polypropylene substrate bonded to at least one tissue, non-woven, polyethylene or polypropylene substrate using a hot multi-adhesive composition consisting essentially of: (a) 10 to 40% by weight of a substantially radial styrene-butadiene bench copolymer having a styrene content greater than 35% by weight, a modulus at 300% elongation of at least 4.5 MPa and a solution viscosity less than 1000 cps; (b) 20 to 65% by weight of at least one compatible tackifying resin; (c) 0.1 to 4% by weight stabilizer; the remainder (to 100%) comprising at least one oil diluent.
Claim 11
Dependent Claim 35 words
The disposable article of claim 7 wherein the styrene butadiene copolymer contains 37 to 40% styrene, has a modulus at 300% elongation of at least 4.6 and a solution viscosity of 640 to 750 cps.
Claim 12
Independent Claim 101 words
A method for imparting elongation resistant gathers to disposable articles wherein elastic is bonded to a polyethylene, polypropylene, tissue or non-woven substrate using a hot melt adhesive composition consisting essentially of: (a) 10 to 40% by weight of a substantially radial styrene-butadiene bench copolymer having a styrene content greater than 35% by weight, a modulus at 300% elongation of at least 4.5 MPa and a solution viscosity less than 1000 cps; (b) 20 to 65% by weight of at least one compatible tackifying resin; (c) 0.1 to 4% by weight stabilizer; the remainder (to 100%) comprising at least one oil diluent.
Claim 13
Independent Claim 101 words
A method for imparting elongation resistant gathers to disposable articles wherein elastic is bonded to a polyethylene, polypropylene, tissue or non-woven substrate using a hot melt adhesive composition consisting essentially of: (a) 10 to 40% by weight of a substantially radial styrene-butadiene bench copolymer having a styrene content greater than 35% by weight, a modulus at 300% elongation of at least 4.5 MPa and a solution viscosity less than 1000 cps; (b) 20 to 65% by weight of at least one compatible tackifying resin; (c) 0.1 to 4% by weight stabilizer; the remainder (to 100%) comprising at least one oil diluent.
Claim 14
Dependent Claim 35 words
The disposable article of claim 9 wherein the styrene butadiene copolymer contains 37 to 40% styrene, has a modulus at 300% elongation of at least 4.6 and a solution viscosity of 640 to 750 cps.

References Cited (Backward Citations)

US4136699A Cited
US4411954A Cited
US4526577A Cited
US4578302A Cited
US4712808A Cited
US4722650A Cited
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US4704110A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-07-30 1994-01-29 1994-07-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-07-30 1998-01-29 1998-07-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-07-30 2002-01-29 2002-07-31 $7700.00 Window Closed / Lapsed

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