US4660858A
Expired / Lapsed
US
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Hot melt adhesive composition for book lining
Assignee: Ingredion Inc
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Filing: 1986-02-20
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Granted: 1987-04-28
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Expires: 2006-02-20
Abstract
Abstract Hard bound books are disclosed wherein the lining adhesive is a hot melt pressure sensitive adhesive composition comprising: (a) 20 to 35% by weight of an A-B-A block or A-B-A-B-A-B multi-block copolymer where the A component is styrene and the B component is butadiene or hydrogenated butadiene and the copolymer contains at least 28 parts styrene per 100 parts copolymer; (b) 45 to 70% by weight of a compatible tackifying resin; (c) 5 to 30% by weight of a plasticizing oil; (d) 0 to 5% by weight of a petroleum derived wax; and (e) 0.1 to 2% by weight of a stabilizer.
Inventors
- 👤 Thomas P. Flanagan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-31 17:27
CPC Classifications
B; B42; B42C; B42C9/00; B32; B32B; B32B27/00; B32B27/12; C; C09; C09J; C09J153/00; C09J153/02; C08; C08L; C08L2666/00; C08L2666/02; C08L2666/28
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
155 words
A process for lining hard bound book blocks comprising the steps of applying a molten film of a hot melt pressure sensitive adhesive to the bound edges of the book block; applying thereto a scrim; applying a second molten film of a hot melt pressure sensitive adhesive and affixing thereto a strip of kraft paper in registered relation to the book spine; wherein the pressure sensitive hot melt adhesive composition comprises: (a) 20 to 35% by weight of an A-B-A block or A-B-A-B-A-B multi-block copolymer where the A component is styrene and the B component is butadiene or hydrogenated butadiene and the copolymer contains at least 28 parts styrene per 100 parts copolymer; (b) 45 to 70% by weight of a compatible tackifying resin; (c) 5 to 30% by weight of a plasticizing oil; (d) 0 to 5% by weight of a petroleum derived wax; and (e) 0.1 to 2% by weight of a stabilizer.
Claim 2
Dependent Claim
155 words
A process for lining hard bound book blocks comprising the steps of applying a molten film of a hot melt pressure sensitive adhesive to the bound edges of the book block; applying thereto a scrim; applying a second molten film of a hot melt pressure sensitive adhesive and affixing thereto a strip of kraft paper in registered relation to the book spine; wherein the pressure sensitive hot melt adhesive composition comprises: (a) 20 to 35% by weight of an A-B-A block or A-B-A-B-A-B multi-block copolymer where the A component is styrene and the B component is butadiene or hydrogenated butadiene and the copolymer contains at least 28 parts styrene per 100 parts copolymer; (b) 45 to 70% by weight of a compatible tackifying resin; (c) 5 to 30% by weight of a plasticizing oil; (d) 0 to 5% by weight of a petroleum derived wax; and (e) 0.1 to 2% by weight of a stabilizer.
Claim 3
Dependent Claim
118 words
The process of claim 1 wherein the tackifier in the hot melt adhesive composition is any compatible resin or mixture thereof selected from the group consisting of (1) natural and modified rosins: (2) glycerol and pentaerythritol esters of natural and modified rosins; (3) copolymers and terpolymers of natured terpenes; (4) polyterpene resins having a softening point, as determined by ASTM method E28-58T, of from about 80° to 150° C.; (5) phenolic modified terpene resins and hydrogenated derivatives thereof; (6) aliphatic petroleum hydrocarbon resins having a Ball and Ring softening point of from about 70° to 135° C.; (7) aromatic petroleum hydrocarbon resins and the hydrogenated derivatives thereof; and (8) alicyclic petroleum hydrocarbon resins and the hydrogenated derivatives thereof.
Claim 4
Dependent Claim
30 words
The process of claim 1 wherein there is additionally present in the hot melt adhesive up to 10% of an ethylene vinyl acetate copolymer containing 17 to 42% vinyl acetate.
Claim 5
Dependent Claim
9 words
A book lined by the process of claim 1.
Claim 6
Dependent Claim
157 words
A process for lining hard bound book blocks comprising the steps of applying a molten film of a hot melt pressure sensitive adhesive to the bound edges of the book block; applying thereto a scrim; applying a second molten film of a hot melt pressure sensitive adhesive and affixing thereto a strip of kraft paper in registered relation to the book spine; wherein the pressure sensitive hot melt adhesive composition comprises: (a) 20 to 35% by weight of an A-B-A-B-A-B multi-block copolymer wherein the A component is styrene and the B component is butadiene and wherein the styrene component is present in an amount of at least 35 parts per 100 parts of the copolymer; (b) 45 to 70% by weight of a compatible tackifying resin; (c) 5 to 30% by weight of a plasticizing oil; (d) 0 to 5% by weight of a petroleum derived wax; and (e) 0.1 to 2% by weight of a stabilizer.
Claim 7
Dependent Claim
157 words
A process for lining hard bound book blocks comprising the steps of applying a molten film of a hot melt pressure sensitive adhesive to the bound edges of the book block; applying thereto a scrim; applying a second molten film of a hot melt pressure sensitive adhesive and affixing thereto a strip of kraft paper in registered relation to the book spine; wherein the pressure sensitive hot melt adhesive composition comprises: (a) 20 to 35% by weight of an A-B-A-B-A-B multi-block copolymer wherein the A component is styrene and the B component is butadiene and wherein the styrene component is present in an amount of at least 35 parts per 100 parts of the copolymer; (b) 45 to 70% by weight of a compatible tackifying resin; (c) 5 to 30% by weight of a plasticizing oil; (d) 0 to 5% by weight of a petroleum derived wax; and (e) 0.1 to 2% by weight of a stabilizer.
Claim 8
Dependent Claim
20 words
The process of claim 5 wherein the block copolymer in the adhesive comprises 57 parts butadiene and 43 parts styrene.
Claim 9
Dependent Claim
20 words
The process of claim 5 wherein the block copolymer in the adhesive comprises 50 parts butadiene and 50 parts styrene.
Claim 10
Dependent Claim
118 words
The process of claim 5 wherein the tackifier in the hot melt adhesive composition is any compatible resin or mixture thereof selected from the group consisting of (1) natural and modified rosins: (2) glycerol and pentaerythritol esters of natural and modified rosins; (3) copolymers and terpolymers of natured terpenes; (4) polyterpene resins having a softening point, as determined by ASTM method E28-58T, of from aboutg 80° to 150° C.; (5) phenolic modified terpene resins and hydrogenated derivatives thereof; (6) aliphatic petroleum hydrocarbon resins having a Ball and Ring softening point of from about 70° to 135° C.; (7) aromatic petroleum hydrocarbon resins and the hydrogenated derivatives thereof; and (8) alicyclic petroleum hydrocarbon resins and the hydrogenated derivatives thereof.
Claim 11
Dependent Claim
28 words
The process of claim 8 wherein the tackifying resin in the adhesive is a modified terpene resin having a Ring and Ball softening part of about 100°-120° C.
Claim 12
Dependent Claim
22 words
The process of claim 8 wherein the tackifying resin in the adhesive is an aromatic petroleum hydrocarbon resin or hydrogenated derivative thereof.
Claim 13
Dependent Claim
30 words
The process of claim 5 wherein there is additionally present in the hot melt adhesive up to 10% of an ethylene vinyl acetate copolymer containing 17 to 42% vinyl acetate.
Claim 14
Dependent Claim
9 words
A book lined by the process of claim 5.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-04-27 | 1990-10-27 | 1991-04-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-04-27 | 1994-10-27 | 1995-04-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-04-27 | 1998-10-27 | 1999-04-28 | $7700.00 | Window Closed / Lapsed |