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Patterned thin film and process for preparing the same

Assignee: Kanegafuchi Chemical Industry Co Ltd
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Filing: 1988-09-23
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Granted: 1990-07-24
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Expires: 2008-09-23
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Abstract

Abstract A patterned thin film suitable for use in electric and electronic devices, prepared from a polymer or a mixture of the polymer and other known compounds capable of forming a thin film by LB technique, said polymer having linear recurring units wherein an organic group R 1 having at least 2 carbon atoms and a valence of at least 2 is combined alternately with an organic group R 2 having at least 2 carbon atoms and a valence of at least 2 through a bivalent group formed by a reaction of an acid group A containing a hetero atom and a basic group B containing a hetero atom, and wherein a hydrocarbon-containing group R 3 having 10 to 30 carbon atoms which may contain a substituent group, is linked by covalent or ionic bond to said recurring units, the number of groups R 3 being at least 2 per 10 recurring units. The patterned thin film is prepared by building up a layer or layers of the polymer or a mixture of the polymer and a compound capable of forming a film by LB technique onto a substrate according to the LB technique, irradiating patternwise the built-up film with high enerty rays, and developing the irradiated film, or by forming the built-up film in the same manner as above on a patterned, removal film formed on a substrate, and removing the patterned film from the substrate, and if desired, by further subjecting the obtained pattern to a reaction to convert the polymer, when it has a structure s a precursor, into a polymer having a 5-membered or 6-membered heterocyclic structure.

Inventors

  • 👤 Masakazu Uekita
  • 👤 Hiroshi Awaji
  • 👤 Makoto Murata
  • 👤 Satoshi Mizunuma

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 08:22
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/60; H10P14/68; H10P14/683; B; B05; B05D; B05D1/00; B05D1/18; B05D1/20; B05D1/202; B82; B82Y; B82Y30/00; B82Y40/00; G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/414; H10D; H10D1/00; H10D1/60; H10D1/68; H10D64/00; H10D64/60; H10D64/66; H10D64/68; H10D64/691; H10K; H10K30/00; H10K30/354; H10K50/00; H10K50/10; H10K50/11; H10K71/00; H10K71/20; H10K85/00; H10K85/10; H10K85/111; H10K85/154; H10K85/60; H10K85/615; H10K85/621; H10K85/701; H10N; H10N60/00; H10N60/80; H10N60/805; H10N70/00; H10P14/63; H10P14/6326; H10P14/6342; H10P14/6344; H10P14/65; H10P14/6516; H10P14/6536; H10P14/6538; Y; Y02; Y02E; Y02E10/00; Y02E10/50; Y02E10/549; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31721

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 76 words
A patterned, heat resistant thin film consisting essentially of a polymer having linear recurring units wherein an organic group R 1 having at least 2 carbon atoms and a valence of at least 3 is combined alternatively with an organic group R 2 having at least 2 carbon atoms and a valence of at least 2 through two bonding groups at least one of which has a 5-membered or 6-membered ring structure containing a hetero atom.
Claim 2
Dependent Claim 76 words
A patterned, heat resistant thin film consisting essentially of a polymer having linear recurring units wherein an organic group R 1 having at least 2 carbon atoms and a valence of at least 3 is combined alternatively with an organic group R 2 having at least 2 carbon atoms and a valence of at least 2 through two bonding groups at least one of which has a 5-membered or 6-membered ring structure containing a hetero atom.
Claim 3
Dependent Claim 27 words
The patterned thin film of claim 1, having a thickness of not more than 1,000 Å and a dielectric strength of not less than 1×10 6 V/cm.
Claim 4
Dependent Claim 119 words
A patterned thin film consisting essentially of a polymer having linear recurring units wherein a first organic group R 1 having at least 2 carbon atoms and a valence of at least 2 is combined alternately with a second organic group R 2 having at least 2 carbon atoms and having a valence of at least 2 through a bivalent group formed by a reaction of an acid group A containing a hetero atom and a basic group B containing a hetero atom, and wherein a hydrocarbon-containing group R 3 having 10 to 30 carbon atoms is linked by covalent bond to said recurring units, the number of groups R 3 being at least 2 per 10 recurring units.
Claim 5
Dependent Claim 119 words
A patterned thin film consisting essentially of a polymer having linear recurring units wherein a first organic group R 1 having at least 2 carbon atoms and a valence of at least 2 is combined alternately with a second organic group R 2 having at least 2 carbon atoms and having a valence of at least 2 through a bivalent group formed by a reaction of an acid group A containing a hetero atom and a basic group B containing a hetero atom, and wherein a hydrocarbon-containing group R 3 having 10 to 30 carbon atoms is linked by covalent bond to said recurring units, the number of groups R 3 being at least 2 per 10 recurring units.
Claim 6
Dependent Claim 15 words
The patterned thin film of claim 1, wherein said group R 3 has a substituent.
Claim 7
Dependent Claim 21 words
The patterned thin film of claim 1, wherein each of said recurring units has at least one group R 3 .
Claim 8
Dependent Claim 21 words
The patterned thin film of claim 1, wherein each of said recurring units has at least two groups R 3 .
Claim 9
Dependent Claim 32 words
The patterned thin film of claim 1, wherein at least one group of R 1 and group R 2 is a group characterized by benzenoid unsaturation having at least 6 carbon atoms.
Claim 10
Dependent Claim 27 words
The patterned thin film of claim 1, wherein said recurring units have a precursor structure capable of forming a 5-membered or 6-membered ring having a hetero atom.
Claim 11
Dependent Claim 28 words
The patterned thin film of claim 1, which is prepared from a mixture of said polymer and a compound capable of forming a thin film by Langmuir-Blodgett technique.

References Cited (Backward Citations)

US4337289A Cited
US4839219A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-07-23 1994-01-22 1994-07-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-07-23 1998-01-22 1998-07-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-07-23 2002-01-22 2002-07-24 $7700.00 Window Closed / Lapsed

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