Abstract The invention relates to compounds of formula I ##STR1## wherein R 1 is C 12 -C 30 alkyl, R 2 is hydrogen or C 1 -C 30 alkyl, R 3 is C 1 14 Calkyl or C 1 -C 3 alkoxy, R 4 may have one of the meanings of R 3 or is halogen, k and n are each independently of the other 0, 1 or 2, and R 5 and R 6 are each independently of the other C 1 -C 4 alkyl, any of which alkyl groups as defined herein may also be partly fluorinated or perfluorinated, with the proviso that R 1 is alkyl of not less than 18 carbon atoms if R 2 is hydrogen or alkyl of less than 12 carbon atoms. From these compounds it is possible to prepare molecular aggregates, especially LB layer systems, which have reversible thermochromic and solvatochromic properties. The invention also relates to intermediates of formula II ##STR2## wherein R 1 , R 2 , R 3 and n are as defined above.
A molecular aggregate of a compound of the formula ##STR7## wherein R 1 is C 12 -C 30 alkyl, R 2 is hydrogen or C 1 -C 30 alkyl, R 3 is C 1 -C 3 alkyl or C 1 -C 3 alkoxy, R 4 has one of the meanings of R 3 or is halogen, k and n are each independently of the other 0, 1 or 2, and R 5 and R 6 are each independently of the other C 1 -C 4 alkyl, wherein the alkyl groups of R 1 , R 2 , R 3 , and R 4 have the meanings above or are partly fluorinated or perfluorinated, with the proviso that R 1 is alkyl of not less than 18 carbon atoms if R 2 is hydrogen or alkyl of less than 12 carbon atoms, wherein said aggregate is assembled in the form of mixed liposomes, microcrystalline films or Langmuir-Blodgett layers.
Claim 2
Dependent Claim
157 words
A molecular aggregate of a compound of the formula ##STR7## wherein R 1 is C 12 -C 30 alkyl, R 2 is hydrogen or C 1 -C 30 alkyl, R 3 is C 1 -C 3 alkyl or C 1 -C 3 alkoxy, R 4 has one of the meanings of R 3 or is halogen, k and n are each independently of the other 0, 1 or 2, and R 5 and R 6 are each independently of the other C 1 -C 4 alkyl, wherein the alkyl groups of R 1 , R 2 , R 3 , and R 4 have the meanings above or are partly fluorinated or perfluorinated, with the proviso that R 1 is alkyl of not less than 18 carbon atoms if R 2 is hydrogen or alkyl of less than 12 carbon atoms, wherein said aggregate is assembled in the form of mixed liposomes, microcrystalline films or Langmuir-Blodgett layers.
Claim 3
Dependent Claim
22 words
Molecular aggregates according to claim 8, which are assembled in the form of multilayer systems that are obtainable by the Langmuir-Blodgett technique.