Flame retardant polyorganosiloxane-based graft polymers

Claim 2

A flame retardant multi-stage polyorganosiloxane-based qraft polymer composition comprising: (a) as a first stage, a substrate selected from (i) an organosiloxane polymer with units derived from a cross-linking agent or agents, and optionally units which serve as a graft linking agent or agents; (ii) a polymeric co-homopolymerized substrate comprised of, in combination, an organo-siloxane polymer and at least one vinyl-based polymer; (iii) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer, at least one vinyl-based polymer, and units which are derived from a cross-linking agent or agents; (iv) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer, at least one vinyl-based polymer, and units which serve as a graft-linking agent or agents; (v) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer, at least one vinyl-based polymer, units which are derived from a cross-linking agent or agents and units from the same or different agent or agents which serve as a graft-linking agent or agents; (vi) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer, at least one vinyl-based polymer, and a mixture of any of units which are derived from a cross-linking agent or agents, units which serve as a graft-linking agent or agents, or units derived from a cross-linking agent or agents and units from the same or different agent or agents which serve as a graft-linking agent or agents; or (vii) a mixture of (i), and at least one of (ii), (iii), (iv), (v) or (vi); and a functionally effective amount of (b) at least one subsequent stage or stages graft polymerized in the pr previous stages, the outermost stage being comprised of a vinyl-based polymer, or a cross-linked vinyl-based polymer, capable of exhibiting flame retardant properties.

Claim 3

A composition as defined in claim 1 wherein said organo-substrate (a) (ii) comprises approximately 5 to 95 weight percent of the total graft copolymer composition based upon the weight of said first stage substrate and any subsequent graft stage or stages taken together.

Claim 4

A composition as defined in claim 2 wherein said first stage substrate (a) ii) comprises approximately 30 to 90 weight percent of the total graft polymer composition.

Claim 5

A composition as defined in claim 1 wherein said first stage substrate (a) (ii) is comprised of approximately 3 to 97 weight percent of organosiloxane polymer and correspondingly 97 to 3 weight percent of vinyl-based polymer.

Claim 6

A composition as defined in claim 4 wherein said first stage substrate (a) (ii) is comprised of approximately 5 to 45 weight percent of vinyl-based polymer.

Claim 7

A composition as defined in claim 1 wherein said organosiloxane polymer is comprised primarily of a mixture of units of the formula R.sub.n SiO.sub.(4-n)/2 wherein R is hydroxen or a monovalent hydrocarbon radical of about 1 to 16 carbon atoms and n is 0, 1 or 2.

Claim 8

A composition as defined in claim 1 wherein the vinyl-based polymer component of said first stage substrate (a) (ii) is comprised primarily of polymerized alkenyl aromatic units, (meth)acrylate units or a mixture thereof.

Claim 9

A composition as defined in claim 7 wherein said vinyl-based polymer component comprises polystyrene.

Claim 10

A composition as defined in claim 1 wherein the vinyl-based polymer in any subsequent stage (b) includes monomers selected from the group consisting of alkenyl aromatic compounds, (meth)acrylate compounds, vinyl cyanide compounds, maleimide compounds, acrylamide compounds or mixtures of any of the foregoing.

Claim 11

A composition as defined in claim 9 wherein said vinyl-based polymer comprises polymerized bromostyrene, dibromostyrene, chlorostyrene, dichlorostyrene, or a mixture of any of the foregoing.

Claim 12

A composition as defined in claim 9 wherein said vinyl-based polymer comprises polymerized dibromostyrene or a mixture thereof with styrene, styrene and acrylonitrile, styrene and methyl methacrylate, or methyl methacrylate.

Claim 13

A composition as defined in claim 1 wherein said subsequent stages (b) comprise (b)(i) a second stage comprising at least one polymer, and optionally units derived from a cross-linking agent or agents, units which serve as a graft-linking agent or agents, units derived from a cross-linking agent or agents and units from the same agent or agents which serve as a graft-linking agent or agents or a mixture of any of the foregoing; and (b)(ii) a third stage comprising at least one vinyl-based polymer, or cross-linked vinyl-based polymer, capable of exhibiting flame retardant properties which is the same as, or different than (b)(i).

Claim 14

A composition as defined in claim 12 wherein the ratio of first stage substrate polymer (a) to second stage polymer (b)(i) is 10:90 to 90:10 by weight based upon 100 parts by weight of (a) and (b)(i) combined; and the amount of third stage polymer (b)(ii) comprises from about 10 to about 90 parts by weight per 100 parts by weight of (a), (b)(i), and (b)(ii) combined.

Claim 15

A composition as defined in claim 12 wherein subsequent stage (b)(i) comprises a cross-linked butyl acrylate polymer and subsequent stage (b)(ii) comprises a dibromostyrene/styrene/acrylonitrile terpolymer.

Claim 16

A composition comprising (A) A normally-flammable thermoplastic resin, and (B) an effective flame retarding amount of a multi-stage polyorganosiloxane-based graft polymer composition comprising: (a) as a first stage, a substrate selected from (i) an organosiloxane polymer with units derived from a cross-linking agent or agents and optionally units which serve as a graft-linking agent or agents; (ii) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer and at least one vinyl-based polymer; (iii) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer, at least one vinyl-based polymer, and units which are derived from a cross-linking agent or agent; (iv) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer, at least one vinyl-based polymer, and units which serve as a graft-linking agent or agents; (v) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer, at least one vinyl-based polymer, units which are derived from a cross-linking agent or agents and units from the same or different agent or agents which serve as a graft-linking agent or agents; (vi) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer, at least one vinyl-based polymer, and a mixture of any of units which are derived from a cross-linking agent or agents, units which serve as a graft-linking agent or agents, or units derived from a cross-linking agent or agents and units from the same or different agent or agents which serve as a graft-linking agent or agents; or (vii) a mixture of and at least one of (ii), (iii), (iv), (v) or (vi); and a functionally effective amount of (b) at least one subsequent stage or stages graft polymerized in the presence of any previous stages, the outermost stage being comprised of a vinyl-based polymer, or a cross-linked vinyl-based polymer, capable of exhibiting flame retardant properties.

Claim 17

A composition comprising (A) A normally-flammable thermoplastic resin, and (B) an effective flame retarding amount of a multi-stage polyorganosiloxane-based graft polymer composition comprising: (a) as a first stage, a substrate selected from (i) an organosiloxane polymer with units derived from a cross-linking agent or agents and optionally units which serve as a graft-linking agent or agents; (ii) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer and at least one vinyl-based polymer; (iii) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer, at least one vinyl-based polymer, and units which are derived from a cross-linking agent or agent; (iv) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer, at least one vinyl-based polymer, and units which serve as a graft-linking agent or agents; (v) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer, at least one vinyl-based polymer, units which are derived from a cross-linking agent or agents and units from the same or different agent or agents which serve as a graft-linking agent or agents; (vi) a polymeric co-homopolymerized substrate comprised of, in combination, an organosiloxane polymer, at least one vinyl-based polymer, and a mixture of any of units which are derived from a cross-linking agent or agents, units which serve as a graft-linking agent or agents, or units derived from a cross-linking agent or agents and units from the same or different agent or agents which serve as a graft-linking agent or agents; or (vii) a mixture of and at least one of (ii), (iii), (iv), (v) or (vi); and a functionally effective amount of (b) at least one subsequent stage or stages graft polymerized in the presence of any previous stages, the outermost stage being comprised of a vinyl-based polymer, or a cross-linked vinyl-based polymer, capable of exhibiting flame retardant properties.

Claim 18

A composition as defined in claim 15 wherein component (A) comprises from about 1 to about 99 parts by weight and component (B) comprises from about 99 to about 1 part by weight per 100 parts by weight of (A) and (B) together.

Claim 19

A composition as defined in claim 16 wherein component (A) comprises from about 99 to about 30 parts by weight and component (B) comprises from about 1 to about 70 parts by weight.

Claim 20

A composition as defined in claim 15 wherein said thermoplastic resin (A) comprises a polyvinylic resin, a polyester resin, a polyamide resin, a polycarbonate resin, a polyacetal resin, a polyether resin, a poly(etherester) resin, a poly(etherimide) resin, a poly(ethermide ester) resin, interpolymers comprising units of any of the foregoing resins, and blends of any of the foregoing resins, interpolymers or combinations thereof.

Claim 21

A composition as defined in claim 18 wherein said thermoplastic resin (A) comprises a polycarbonate resin.

Claim 22

A composition as defined in claim 15 wherein said first stage substrate (a) (i) or (a) (ii) comprises approximately from 3 to 97 weight percent of the total graft polymer composition based upon the weight of said first stage and any subsequent graft stages taken together.

Claim 23

A composition as defined in claim 20 wherein said first stage substrate (a)(i) or (a)(ii) comprises approximately 30 to 90 weight percent of the total graft polymer composition.

Claim 24

A composition as defined in claim 15 wherein said first stage substrate (a)(ii) is comprised of approximately 3 to 97 weight percent of organosiloxane polymer and correspondingly about 97 to 3 weight percent of vinyl-based polymer.

Claim 25

A composition as defined in claim 22 wherein said first stage substrate (a)(ii) is comprised of approximately 5 to 45 weight percent vinyl-based polymer.

Claim 26

A composition as defined in claim 15 wherein said organosiloxane polymer is comprised primarily of a mixture of units of the formula R.sub.n SiO.sub.(4-n)/2 wherein R is hydrogen or a monovalent hydrocarbon radical of about 1 to 16 carbon atoms and n is 0, 1 or 2.

Claim 27

A composition as defined in claim 15 wherein said vinyl-based polymer component of said first stage (a)(ii) is comprised primarily of polymerized alkenyl aromatic units, (meth)acrylate units or a mixture thereof.

Claim 28

A composition as defined in claim 25 wherein said vinyl-based polymer component comprises polystyrene.

Claim 29

A composition as defined in claim 15 wherein said vinyl-based polymer in any subsequent stage (b) includes monomers selected from the group consisting of polymerized alkenyl aromatic compounds, (meth)acrylate compounds, vinyl cyanide compounds, maleimide compounds and acrylamide compounds.

Claim 30

A composition as defined in claim 27 wherein said vinyl-based polymer comprises polymerized bromostyrene, dibromostyrene, chlorostyrene, dichlorostyrene, or a mixture of any of the foregoing.

Claim 31

A composition as defined in claim 28 wherein said vinyl polymer comprises polymerized dibromostyene, or a mixture thereof with styrene, styrene and acrylonitrile, styrene and methyl methacrylate, or methyl methacrylate.

Claim 32

A composition as defined in claim 15 wherein in component B said subsequent stages (b) comprise (b)(i) a second stage comprising at least one said vinyl-based polymer and optionally units derived from at least one cross-linking agent or agents, units which serve as a graft-linking agent or agents, units derived from at least one cross-linking agent or agents and graft-linking agent or agents or a mixture of any of the foregoing; and (b)(ii) a third stage comprising at least one vinyl-based polymer, or cross-linked vinyl-based polymer, capable of exhibiting flame retardant properties, which is the same as, or different than (b)(i).

Claim 33

A composition as defined in claim 30 wherein the ratio of substrate polymer (a) to second stage polymer (b)(i) is 10:90 to 90:10 by weight based upon 100 parts by weight of (a) and (b)(i) combined and the amount of third stage polymer (b)(ii) comprises from about 10 to about 90 parts by weight per 100 parts by weight of (a), (b)(i), and (b)(ii) combined.

Claim 34

A composition as defined iu claim 30 wherein subsequent stage (b)(i) comprises a cross-linked butyl acrylate polymer and subsequent stage (b)(ii) comprises a dibromostyrene/styrene/acrylonitrile terpolymer.

Claim 35

A composition as defined in claim 15 which also includes (C) an effective amount of a reinforcing filler.

Claim 36

A composition as defined in claim 30 which also includes (C) an effective amount of a reinforcing filler.

Claim 37

A composition as defined in claim 15 which also includes (D) an effective amount of at least one additional flame retardant agent which may be the same as or different than (B).

Claim 38

A composition as defined in claim 30 which also includes (D) an effective amount of at least one additional flame retardant agent which may be the same as or different than (B).

Claim 39

A composition as defined in claim 15 which also includes (C) an effective amount of a reinforcing filler; and (D) an effective amount of at least one additional flame retardant agent which may be the same as or different than (B).

Claim 40

A composition as defined in claim 30 which also includes (C) an effective amount of a reinforcing filler, and (D) an effective amount of at least one additional flame retardant agent which may be the same as or different than (B).

Claim 41

An article molded from a composition as defined in claim 15.

Claim 42

An article molded from a composition as defined in claim 30.

Claim 43

An article extruded from a composition as defined in claim 15.

Claim 44

An article extruded from a composition as defined in claim 30.

Claim 45

An article thermoformed from a composition as defined in claim 15.

Claim 46

An article thermoformed from a composition as defined in claim 30.