Multilayered sheets having excellent adhesion

Claim 2

Sheet material comprising a first layer of copolyesterether, copolyester or a blend thereof, a second layer of polyolefin and a layer of ethylene copolymer intermediate said first and second layers. (I) said copolyester having an I.V. of about 0.8 to 1.5 and repeat units from (A) a dicarboxylic acid component consisting essentially of 1,4-cyclohexanedicarboxylic acid having a trans isomer content of at least 70%, (B) a glycol component consisting essentially of (1) about 95 to about 65 mol % 1,4-cyclohexanedimethanol, and (2) about 5 to about 35 mol % poly(oxytetramethylene) glycol having a molecular weight of about 500 to about 1100, (II) said copolyester having repeat units from terephthalic acid and at least two glycols having 2 to 10 carbon atoms, and (III) said ethylene copolymer being a copolymer of ethylene and at least one other unsaturated monomer, said ethylene copolymer having a density of about 0.85-0.91.

Claim 3

Sheet material according to claim 1 wherein said copolyester contains repeat units from terephthalic acid, ethylene glycol and 1,4-cyclohexanedimethanol.

Claim 4

Sheet material according to claim 1 wherein said ethylene copolymer is a copolymer of ethylene with a monomer selected from maleic acid, fumaric acid, acrylic acid, methacrylic acid, vinyl acetate, acrylonitrile, methacrylonitrile, butadiene and carbon monoxide.

Claim 5

Sheet material according to claim 1 wherein said ethylene copolymer has a melt flow rate of about 0.25-40 g/10 min, a tensile strength at break of at least 25 g/cm 2 , an elongation at break of greater than 100% and a melting point of at least 65°.

Claim 6

Sheet material according to claim 4 wherein said ethylene copolymer has a melt flow rate of about 0.5-20 g/10 min, and an elongation at break of greater than 400%.

Claim 7

Sheet material according to claim 1 wherein said ethylene copolymer has a melt flow rate of about 0.8-1.2 g/10 min, a tensile strength at break of about 20-40 kg/cm 2 , an elongation at break of greater than about 50%, an Izod impact strength of unbreakable, a D-shore hardness of about 14-18, an A-shore hardness of about 70-74 and a melting point of about 70°-80° C.

Claim 8

Multilayered flexible film material comprising at least one layer of copolyesterether, at least one tie layer, and at least one layer of polyolefin, said tie layer being positioned between each copolyesterether layer and polyolefin layer, the copolyetherester having an I.V. of about 0.8 to 1.5 and repeat units from (A) a dicarboxylic acid component consisting essentially of 1,4-cyclohexanedicarboxylic acid having a trans isomer content of at least 70%, (B) a glycol component consisting essentially of (1) about 95 to about 65 mol % 1,4-cyclohexane dimethanol, and (2) about 5 to about 35 mol % poly(oxytetramethylene) glycol having a molecular weight of about 500 to about 1100, the tie layer being a low molecular weight copolymer having ethylene repeat units, a melt flow rate of about 0.5 to about 20, a tensile strength at break of at least 25 kg/cm 2 , an elongation at break of greater than 400% and a melting point of at least 65° C., and the polyolefin layer being selected from polyethylene, polypropylene and ethylene/propylene copolymers.

Claim 9

Multilayered flexible film material comprising at least one layer of copolyesterether, at least one tie layer, and at least one layer of polyolefin, said tie layer being positioned between each copolyesterether layer and polyolefin layer, the copolyetherester having an I.V. of about 0.8 to 1.5 and repeat units from (A) a dicarboxylic acid component consisting essentially of 1,4-cyclohexanedicarboxylic acid having a trans isomer content of at least 70%, (B) a glycol component consisting essentially of (1) about 95 to about 65 mol % 1,4-cyclohexane dimethanol, and (2) about 5 to about 35 mol % poly(oxytetramethylene) glycol having a molecular weight of about 500 to about 1100, the tie layer being a low molecular weight copolymer having ethylene repeat units, a melt flow rate of about 0.5 to about 20, a tensile strength at break of at least 25 kg/cm 2 , an elongation at break of greater than 400% and a melting point of at least 65° C., and the polyolefin layer being selected from polyethylene, polypropylene and ethylene/propylene copolymers.

Claim 10

The film material according to claim 7 wherein said material has a three-layered structure consisting of said copolyesterether and said polyolefin as outer layers and said tie layer as an inner layer.

Claim 11

The film material according to claim 7 wherein said material has a five layered structure consisting of, in order from one surface to the other, copolyesterether, tie, polyolefin, tie and polyetherester.

Claim 12

The film material according to claim 7 formed by coextrusion of said layers.

Claim 13

A container comprising the film material of claim 7.

Claim 14

A bag comprising the film material of claim 7.