Method of manufacturing a semiconductor device, in which a negative image is formed on a semiconductor substrate in a positive photolacquer

Claim 1

A method of providing a semiconductor substrate with a patterned photolacquer layer having a substantially rectangular profile, said method substrate comprising: (a) Providing a semiconductor substrate with a photolacquer layer containing a photoactive diazo oxide compound capable of being converted to an indene carboxylic acid, a triazene compound capable of reacting with an acid to form a diazonium compound capable of reacting with a coupler to form an azo pigment which absorbs radiation having a wavelength range in which said diazo oxide compound is photosensitive, said triazene compound being of the formula ##STR4## in which X=H, 2-Me-5-Cl, 2-Me-4Cl or 4-Br and in which R 1 =R 2 =CH 3 , CH 2 --CH 2 --OH or in which R 1 R 2 =--CH 2 --CH 2 --CH 2 --CH 2 --CH 2 or --CH 2 --CH 2 --O--CH 2 --CH 2 --, and a photochemical acidifier which under the influence of the first patterned irradiation forms a strong acid, said acidifier being a halogen-containing triazine compound; (b) exposing said layer to a first patterned irradiation; (c) then heating said thus irradiated layer to thereby cause said azo pigment to form in the irradiated portions of said layer and cause said irradiated portions of said layer to become only poorly developable; (d) exposing said thus first-irradiated layer to a second non-patterned irradiation of a wavelength absorbed by said pigment and to which diazo oxide compound is photosensitive; and (e) developing said layer to thereby remove the portions of said layer non-irradiated during said first irradiation.

Claim 2

A method of providing a semiconductor substrate with a patterned photolacquer layer having a substantially rectangular profile, said method substrate comprising: (a) Providing a semiconductor substrate with a photolacquer layer containing a photoactive diazo oxide compound capable of being converted to an indene carboxylic acid, a triazene compound capable of reacting with an acid to form a diazonium compound capable of reacting with a coupler to form an azo pigment which absorbs radiation having a wavelength range in which said diazo oxide compound is photosensitive, said triazene compound being of the formula ##STR4## in which X=H, 2-Me-5-Cl, 2-Me-4Cl or 4-Br and in which R 1 =R 2 =CH 3 , CH 2 --CH 2 --OH or in which R 1 R 2 =--CH 2 --CH 2 --CH 2 --CH 2 --CH 2 or --CH 2 --CH 2 --O--CH 2 --CH 2 --, and a photochemical acidifier which under the influence of the first patterned irradiation forms a strong acid, said acidifier being a halogen-containing triazine compound; (b) exposing said layer to a first patterned irradiation; (c) then heating said thus irradiated layer to thereby cause said azo pigment to form in the irradiated portions of said layer and cause said irradiated portions of said layer to become only poorly developable; (d) exposing said thus first-irradiated layer to a second non-patterned irradiation of a wavelength absorbed by said pigment and to which diazo oxide compound is photosensitive; and (e) developing said layer to thereby remove the portions of said layer non-irradiated during said first irradiation.