Patent US4936887A successfully refreshed from Google Patents.
US4936887A
Expired / Lapsed
US
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Distillation plus membrane processing of gas streams
Assignee: Phillips Petroleum Co
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Filing: 1989-11-02
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Granted: 1990-06-26
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Expires: 2009-11-02
Abstract
Abstract A membrane separation is incorporated in a distillation cycle for efficient recovery of carbon dioxide from a stream containing natural gas along with carbon dioxide. Methane and carbon dioxide are separated from a feed stream in a first distillation to produce a process stream containing essentially methane and carbon dioxide and which is substantially free to ethane and higher molecular weight hydrocarbons. The process stream consisting essentially of methane and carbon dioxide is subjected to further distillation to produce a carbon dioxide-rich product stream and a process stream enriched in methane. The methane-enriched process stream is then passed to a membrane separation unit for separating methane and carbon dioxide and for producing a high purity methane product stream.
Inventors
- 👤 Richard A. Waldo
- 👤 Jeffrey R. Burkinshaw
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 19:38
CPC Classifications
F; F25; F25J; F25J3/00; F25J3/02; F25J3/0228; F25J3/0266; B; B01; B01D; B01D53/00; B01D53/22; B01D53/229; C; C07; C07C; C07C7/00; C07C7/005; F25J3/0204; F25J3/0209; F25J3/0233; F25J3/0238; F25J3/0247; F25J2200/00; F25J2200/04; F25J2200/08; F25J2200/74; F25J2205/00; F25J2205/30; F25J2205/40; F25J2205/50; F25J2205/80; F25J2210/00; F25J2210/04; F25J2215/00; F25J2215/04; F25J2220/00; F25J2220/60; F25J2220/66; F25J2220/80; F25J2220/82; F25J2230/00; F25J2230/08; F25J2230/30; F25J2230/60; F25J2245/00; F25J2245/02; Y; Y02; Y02C; Y02C20/00; Y02C20/40; Y02P; Y02P20/00; Y02P20/151; Y10; Y10S; Y10S62/00; Y10S62/928; Y10S62/929
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
299 words
A process for separating components of a feed gas stream comprising carbon dioxide, hydrogen sulfide, nitrogen, methane, and higher molecular weight hydrocarbons to form a carbon dioxide-rich stream and a methane-rich stream, said process comprising the following steps: (a) passing said feed gas stream to a first fractional distillation column; (b) withdrawing a first overhead stream from said first fractional distillation column, said first overhead stream having a substantially increased concentration of carbon dioxide and methane and nitrogen relative to the respective concentrations of carbon dioxide, methane, and nitrogen in said feed gas stream; (c) withdrawing a first bottoms stream from said first fractional distillation column, said first bottoms stream having a substantially increased concentration of ethane and higher molecular weight hydrocarbons relative to the concentration of ethane and higher molecular weight hydrocarbons in said feed gas stream; (d) passing said first overhead stream to a second fractional distillation column; (e) withdrawing a second overhead stream wherein said second overhead stream is withdrawn from said second fractional distillation column, said second overhead stream having a substantially increased concentration of methane and nitrogen relative to the concentration of methane and nitrogen in said first overhead stream; (f) withdrawing a second bottoms stream wherein said second bottoms stream is withdrawn from said second fractional distillation column, and wherein said second bottoms stream forms said carbon dioxide-rich stream; (g) passing said second overhead stream to a membrane separation unit wherein said membrane separation unit is permeable to carbon dioxide; (h) withdrawing a residual gas stream from said membrane separation unit to form said methane-rich stream; and (i) withdrawing a residual gas stream from said membrane separation unit to form a recycle stream having a substantially increased concentration of carbon dioxide relative to the concentration of carbon dioxide in said second overhead stream.
Claim 2
Dependent Claim
299 words
A process for separating components of a feed gas stream comprising carbon dioxide, hydrogen sulfide, nitrogen, methane, and higher molecular weight hydrocarbons to form a carbon dioxide-rich stream and a methane-rich stream, said process comprising the following steps: (a) passing said feed gas stream to a first fractional distillation column; (b) withdrawing a first overhead stream from said first fractional distillation column, said first overhead stream having a substantially increased concentration of carbon dioxide and methane and nitrogen relative to the respective concentrations of carbon dioxide, methane, and nitrogen in said feed gas stream; (c) withdrawing a first bottoms stream from said first fractional distillation column, said first bottoms stream having a substantially increased concentration of ethane and higher molecular weight hydrocarbons relative to the concentration of ethane and higher molecular weight hydrocarbons in said feed gas stream; (d) passing said first overhead stream to a second fractional distillation column; (e) withdrawing a second overhead stream wherein said second overhead stream is withdrawn from said second fractional distillation column, said second overhead stream having a substantially increased concentration of methane and nitrogen relative to the concentration of methane and nitrogen in said first overhead stream; (f) withdrawing a second bottoms stream wherein said second bottoms stream is withdrawn from said second fractional distillation column, and wherein said second bottoms stream forms said carbon dioxide-rich stream; (g) passing said second overhead stream to a membrane separation unit wherein said membrane separation unit is permeable to carbon dioxide; (h) withdrawing a residual gas stream from said membrane separation unit to form said methane-rich stream; and (i) withdrawing a residual gas stream from said membrane separation unit to form a recycle stream having a substantially increased concentration of carbon dioxide relative to the concentration of carbon dioxide in said second overhead stream.
Claim 3
Dependent Claim
125 words
A process of separating carbon dioxide from hydrocarbons comprising the following steps: (a) separating ethane and higher molecular weight hydrocarbons from a feed gas stream comprising carbon dioxide, methane, ethane, and higher molecular weight hydrocarbons to produce a primary process stream essentially containing carbon dioxide and methane; (b) separating a portion of the carbon dioxide from the methane in said primary process stream to produce a carbon dioxide-rich stream and a secondary process stream having a substantially reduced concentration of carbon dioxide relative to the concentration of carbon dioxide in said primary process stream; and (c) passing said secondary process stream to a membrane separation unit to separate carbon dioxide from methane and to produce a carbon dioxide permeate stream and a methane-rich residual stream.
Claim 4
Dependent Claim
125 words
A process of separating carbon dioxide from hydrocarbons comprising the following steps: (a) separating ethane and higher molecular weight hydrocarbons from a feed gas stream comprising carbon dioxide, methane, ethane, and higher molecular weight hydrocarbons to produce a primary process stream essentially containing carbon dioxide and methane; (b) separating a portion of the carbon dioxide from the methane in said primary process stream to produce a carbon dioxide-rich stream and a secondary process stream having a substantially reduced concentration of carbon dioxide relative to the concentration of carbon dioxide in said primary process stream; and (c) passing said secondary process stream to a membrane separation unit to separate carbon dioxide from methane and to produce a carbon dioxide permeate stream and a methane-rich residual stream.
Claim 5
Dependent Claim
22 words
A process in accordance with claim 2 wherein said feed gas stream is characterized by containing a large percentage of carbon dioxide.
Claim 6
Dependent Claim
94 words
A process in accordance with claim 2 wherein step (a) comprises the following steps: (a) passing said feed gas stream to a first fractional distillation column; (b) withdrawing an overhead stream from said first fractional distillation column to form said primary process stream; and (c) withdrawing a bottoms stream from said first factional distillation column, said bottom stream withdrawn from said first fractional distillation column having a substantially increased concentration of ethane and higher molecular weight hydrocarbons relative to the respective concentrations of ethane and higher molecular weight hydrocarbons in said feed gas stream.
Claim 7
Dependent Claim
85 words
A process in accordance with claim 4 wherein step (b) comprises the following steps: (a) passing said primary process stream to a second fractional distillation column; (b) withdrawing an overhead stream from said second fractional distillation column to form said secondary process stream; and (c) withdrawing said carbon dioxide-rich stream from said second fractional distillation column wherein said carbon dioxide-rich stream is a bottoms stream having a substantially increased concentration of carbon dioxide relative to the concentration of carbon dioxide in, said primary process stream.
Claim 8
Dependent Claim
55 words
The process of claim 4 wherein said bottom stream from said first fractional distillation column is subjected to further distillation where butane and higher molecular weight hydrocarbons are recovered therefrom and a portion of the recovered butane is recycled to said first fractional distillation column, and the remaining butane is taken as a product stream.
Claim 9
Dependent Claim
21 words
A process in accordance with claim 4 wherein said carbon dioxide permeate stream is recycled to said first fractional distillation column.
Claim 10
Dependent Claim
52 words
A process in accordance with claim 4 additionally comprising the steps of: (a) raising the pressure of said feed gas substantial-y above atmospheric pressure; and (b) lowering the temperature of said feed gas substantially below ambient temperature, so that said feed gas comprises both vapor and liquid phases prior to step (a).
Claim 11
Dependent Claim
173 words
Apparatus comprising: (a) first separating means for separating ethane and higher molecular weight hydrocarbons from a feed gas stream comprising carbon dioxide, methane, ethane, and higher molecular weight hydrocarbons and for producing a primary process stream consisting essentially of carbon dioxide and methane; (b) second separating means operatively connected to said first separating means for separating a portion of the carbon dioxide from methane in said primary process stream and for producing a carbon dioxide-rich stream and a secondary process stream, said secondary process stream having a substantially reduced concentration of carbon dioxide relative to the concentration of carbon dioxide in said primary process stream; (c) membrane separator unit means operatively connected to said second separating means for receiving said secondary process stream and for separating carbon dioxide from methane therein and producing a methane-rich residual stream and a carbon dioxide permeate stream; (d) means for withdrawing said methane-rich residual stream from said membrane separator unit means; and (e) means for withdrawing said carbon dioxide permeate stream from said membrane separator unit means.
Claim 12
Dependent Claim
173 words
Apparatus comprising: (a) first separating means for separating ethane and higher molecular weight hydrocarbons from a feed gas stream comprising carbon dioxide, methane, ethane, and higher molecular weight hydrocarbons and for producing a primary process stream consisting essentially of carbon dioxide and methane; (b) second separating means operatively connected to said first separating means for separating a portion of the carbon dioxide from methane in said primary process stream and for producing a carbon dioxide-rich stream and a secondary process stream, said secondary process stream having a substantially reduced concentration of carbon dioxide relative to the concentration of carbon dioxide in said primary process stream; (c) membrane separator unit means operatively connected to said second separating means for receiving said secondary process stream and for separating carbon dioxide from methane therein and producing a methane-rich residual stream and a carbon dioxide permeate stream; (d) means for withdrawing said methane-rich residual stream from said membrane separator unit means; and (e) means for withdrawing said carbon dioxide permeate stream from said membrane separator unit means.
Claim 13
Dependent Claim
128 words
Apparatus in accordance with claim 9 wherein said first separating means comprises: (a) a first fractional distillation column; (b) means for providing a feed stream to said first fractional distillation column; (c) overhead accumulator means operatively related to said first fractional distillation column; (d) means for providing a liquid reflux stream to said first fractional distillation column from said overhead accumulator means; (e) means for withdrawing an overhead vapor stream from said overhead accumulator means to form said primary process stream; and (f) means for withdrawing a liquid bottoms stream from said first fractional distillation column, said liquid bottoms stream having a substantially increased concentrations of ethane and higher molecular weight hydrocarbons relative to the respective concentrations of ethane and higher molecular weight hydrocarbons in said feed stream.
Claim 14
Dependent Claim
101 words
Apparatus in accordance with claim 10 wherein said second separating means comprises: (a) a second fractional distillation column; (b) means for providing said primary process stream as a feed stream to said second fractional distillation column; (c) means for withdrawing an overhead vapor stream from said second fractional distillation column to form said secondary process stream; and (d) means for withdrawing a liquid bottoms stream from said second fractional distillation column, said liquid bottoms stream having a substantially increased concentration of carbon dioxide relative to the concentration of carbon dioxide in said primary process stream to form said carbon dioxide-rich stream.
Claim 15
Dependent Claim
22 words
Apparatus in accordance with claim 9 additionally comprising means for recycling said carbon dioxide permeate stream to said first fractional distillation column.
Claim 16
Dependent Claim
43 words
Apparatus in accordance with claim 9 additionally comprising: (a) means for compressing said feed gas stream; and (b) means for cooling said feed gas stream so that said feed gas stream to said first fractional distillation column comprises both vapor and liquid phases.
Claim 17
Dependent Claim
41 words
Apparatus in accordance with claim 13 additionally comprising means for subjecting said bottom stream from said first fractional distillation column to further distillation to separate C 3 and lighter hydrocarbon components from said bottom stream from said first fractional distillation column.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-06-25 | 1993-12-25 | 1994-06-26 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-06-25 | 1997-12-25 | 1998-06-26 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-06-25 | 2001-12-25 | 2002-06-26 | $7700.00 | Window Closed / Lapsed |