Hemiacetals

Claim 2

All possible isomeric forms of a compound of the formula ##STR21## wherein A has a structure selected from the group consisting of ##STR22## wherein Y 1 and Y 2 are individually selected from the group consisting of hydrogen, fluorine, chlorine, bromine and alkyl of 1 to 6 carbon atoms, or Y 1 and Y 2 together with the carbon to which they are attached form a carbon homocycle of 3 to 7 carbon atoms and Z is selected from the group consisting of hydrogen, chlorine, bromine and iodine, Y is selected from the group consisting of hydrogen, alkyl of 1 to 18 carbon atoms unsubstituted or substituted with at least one halogen and the β, α bond together with Y can be part of A and R is selected from the group consisting of non-heterocyclic primary, secondary or tertiary alcohol moiety having at least one asymetric carbon atom or the remainder of a substituted alcohol with a chirality due to the dissymetric configuration of the entire molecule.

Claim 3

A compound of claim 1 wherein R is selected from the group consisting of ##STR23## wherein X' is selected from the group consisting of --CN and alkyl, alkenyl and alkynyl of up to 6 carbon atoms.

Claim 4

A compound of claim 1 wherein A has the structure ##STR24## wherein Y 1 and Y 2 are individually selected from the group consisting of hydrogen, fluorine, bromine, chlorine and alkyl of 1 to 6 carbon atoms or taken together with the carbon atom to which they are attached form a carbon homocycle of 3 to 7 carbon atoms.

Claim 5

A compound of claim 1, wherein A has the structure ##STR25##

Claim 6

A compound of claim 1 wherein A has the structure selected from the group consisting of ##STR26##

Claim 7

A compound of claim 1 wherein R is ##STR27##

Claim 8

A compound of claim 11 selected from the group consisting of (1R,2R,4R,5S) 6,6-dimethyl-3-oxa-2-[S-cyano-(3-phenoxy-phenyl)-methoxy]-4-(2-methyl-2-propyl)-bicyclo-[3.1.0] hexane, (1R,2R,4R,5S) 6,6-dimethyl-3-oxa-2-[R-cyano-(3-phenoxy-phenyl) methoxy]-4-(2-methyl-2-propyl)-bicyclo-[3.1.0] hexane, (1R,2R,4R,5S) 6,6-dimethyl-4-trichloromethyl-2-[(R)2-methyl-4-oxo-3-(2-propen-1-yl)-cyclopent-2-enyloxy]-3-oxa-bicyclo-[3.1.0] hexane, (1R,2R,4R,5S) 6,6-dimethyl-4-trichloromethyl-2-(1S) 2-methyl-[3.1.0] hexane, (1R,2R,4R,5S) 6,6-dimethyl-3-oxa-2-[S-cyano-(3-phenoxy-phenyl)-methoxy]-bicyclo-[3.1.0] hexane, (1R,2R,5S) 6,6-dimethyl-3-oxa-2-[R-cyano (3-phenoxy-phenyl)-methoxy]-bicyclo-[3.1.0] hexane, (1R,2S,4R,5S) 6,6-dimethyl-4-trichloromethyl-2-[(S)-cyano-(3-phenoxyphenyl)-methoxy]-3-oxa-bicyclo-[3.1.0] hexane, (1R,2R,4R,5S) 6,6-dimethyl-4-trichloromethyl-2-[(R)-cyano-(3-phenoxyphenyl)-methoxy]-3-oxa-bicyclo-[3.1.0] hexane, (1R,2R,4R,5S) 6,6-dimethyl-4-tribromomethyl-2-[(R) 2-methyl-4-oxo-3]-2-propen-1-yl)-cyclopent-2-enyloxy]-3-oxa-bicyclo-[3.1.0] hexane, (1R,2R,4R,5S) 6,6-dimethyl-4-tribromomethyl-2-[1(S) 2-methyl-4-oxo-3-(2-propen-1-yl)-cyclopent-2-enyloxy]-3-oxa-bicyclo-[3.1.0] hexane, (3aR,4R,7S,7aS,1R) 1-[R-(cyano-3-phenoxyphenyl)-methoxy]-tetrahydro-4,7-methano-isobenzofurane, (3aR,4R,7S,7aS,1R)-1-[S-(cyano-3-phenoxyphenyl)-methoxy]-tetrahydro-4,7-methano-isobenzofurane, (11S,12R,15R) 12-[S-(cyano-3-phenoxyphenyl)-methoxy]-9,10,11,12,14,15-hexahydro-9,10-(3',4')-furanoanthracene, (11R,12S,15S)-12-[S-(cyano-3-phenoxyphenyl)-methoxy]-9,10,11,12,14,15-hexahydro-9,10-(3',4')-furanoanthracene, (11R,12S,15S) 12-[1S-2-methyl-4-oxo-3-(2-propen-1-yl)cyclopent-2-enyloxy-9,10,11,12,14,15-hexahydro-9,10-[3',4']-furanoanthracene, (11R,12S,15S)-12-[1R-2-methyl-4-oxo-3-(2-propen-1-yl)-cyclopent-2-enyloxy] -9,10,11,12,14,15-hexahydro-9,10-[3',4']-furanoanthracene, (11S,12R,15S) 12-[(1R,2S,5R) 2-prop-2-yl-5-methyl-cyclohexyloxy]-9,10,11,12,14,15-hexahydro-9,10-[3',4']-furanoanthracene, (11R,12S,15S)12-[(1R,2S,5R)-2-prop-2-yl-5-methyl cyclohexyloxy]-9,10,11,12,14,15-hexahydro-9,10-[3',4']-furanoanthracene, (1R,2R,5S) 6,6-dimethyl-3-oxa-2-[(R)cyano-(3-phenoxy-4-fluoro-phenyl)-methoxy]-bicyclo [3.1.0] hexane, (1R,2R,5S) 6,6-dimethyl-3-oxa-2-[(S)cyano-(3-phenoxy-4-fluoro-phenyl)-methoxy]-bicyclo[3.1.0] hexane, 2R-(6-bromohexahydro-3,5-methano-2H-cyclopenta[b]furan-2-yl)-oxy (S)α-cyano-3-phenoxy-benzyl and 2S-(6-bromohexahydro-3,5-methano-2H-cyclopenta[b]furan-2-yl)-oxy (S)α-cyano-3-phenoxy-benzyl.