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Hydrocarbon tolerant hair fixing compositions

Assignee: National Starch and Chemical Investment Holding Corp
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Filing: 1989-06-21
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Granted: 1990-06-12
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Expires: 2009-06-21
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Abstract

Abstract This invention presents two series of novel hair fixing compositions, the first comprising copolymers of acrylates, N-substituted acrylamides and acrylic acid; and the second comprising copolymers of vinyl acetate or propionate, vinyl esters of a α-branched carboxylic acids, and alkyl maleates. Such materials, when neutralized with NaOH, KOH, or mixtures of these bases with certain long chain amines, exhibit an enhanced tolerance of non-halogenated hydrocarbons and are particularly useful.

Inventors

  • 👤 Frank A. Nowak, Jr.
  • 👤 Albert L. Micchelli
  • 👤 3 William M. Rouse

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 22:17
CPC Classifications
A; A61; A61K; A61K8/00; A61K8/18; A61K8/72; A61K8/81; A61K8/8164; A61K8/02; A61K8/04; A61K8/046; A61K8/8141; A61K8/8158; A61Q; A61Q5/00; A61Q5/06

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 176 words
An improved hair fixing composition having increased hydrocarbon tolerance, for use in aerosol formulations, comprising a copolymer of 20-35% (by wt.) of vinyl acetate or vinyl propionate, 35-50% (by wt.) of a vinyl ester of a C 5 -C 18 α-branched carboxylic acid, 25-40% (by wt.) of a C 3 -C 8 monoalkyl maleate, and up to 20% if a comonomer selected from the group consisting of acrylic and methacrylic esters of C 1 -C 12 aliphatic alcohols, hydroxy alkyl esters of acrylic and methacrylic acids, C 1 -C 4 alkyl/C 2 -C 4 amino alkyl esters of acrylic and methacrylic acids, styrene and alkyl substituted styrene monomers vinyl esters, C 1 -C 8 dialkyl maleates, N-vinyl pyrroliodone, and N-substituted alkyl (C 1 -C 8 ) maleamic acid, wherein percentages total 100% and all the improvement comprises neutralizing at least 70% of the carboxylic acid functionalities with an alkaline neutralizing agent comprising at least one base selected from the group consisting of NaOH and KOH, such that the tolerance of the copolymer to hydrocarbons is enhanced.
Claim 2
Dependent Claim 176 words
An improved hair fixing composition having increased hydrocarbon tolerance, for use in aerosol formulations, comprising a copolymer of 20-35% (by wt.) of vinyl acetate or vinyl propionate, 35-50% (by wt.) of a vinyl ester of a C 5 -C 18 α-branched carboxylic acid, 25-40% (by wt.) of a C 3 -C 8 monoalkyl maleate, and up to 20% if a comonomer selected from the group consisting of acrylic and methacrylic esters of C 1 -C 12 aliphatic alcohols, hydroxy alkyl esters of acrylic and methacrylic acids, C 1 -C 4 alkyl/C 2 -C 4 amino alkyl esters of acrylic and methacrylic acids, styrene and alkyl substituted styrene monomers vinyl esters, C 1 -C 8 dialkyl maleates, N-vinyl pyrroliodone, and N-substituted alkyl (C 1 -C 8 ) maleamic acid, wherein percentages total 100% and all the improvement comprises neutralizing at least 70% of the carboxylic acid functionalities with an alkaline neutralizing agent comprising at least one base selected from the group consisting of NaOH and KOH, such that the tolerance of the copolymer to hydrocarbons is enhanced.
Claim 3
Dependent Claim 34 words
An aerosol hairspray formulation comprising 0.50 to 12% (by wt.) of the hair fixing composition of claim 1, 8-90% (by wt.) of an alcohol solvent, and 10-85% (by wt.) of a non-halogenated hydrocarbon propellant.
Claim 4
Dependent Claim 20 words
The formulation of claim 2, wherein the alcohol solvent is a C 1 -C 4 straight or branched chain alcohol.
Claim 5
Dependent Claim 26 words
The formulation of claim 2, wherein the non-halogenated hydrocarbon propellant is selected from group consisting of C 4 -C 6 branched chain hydrocarbons, and mixtures thereof.

References Cited (Backward Citations)

US2996471A Cited
US3577517A Cited
US3405084A Cited
US3445566A Cited
US3810977A Cited
US3927199A Cited
US4192861A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-06-11 1993-12-11 1994-06-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-06-11 1997-12-11 1998-06-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-06-11 2001-12-11 2002-06-12 $7700.00 Window Closed / Lapsed

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