US4927732A
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US
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Positive-working photosensitive composition containing a dye and positive-working photosensitive recording material prepared therefrom
Assignee: CLARIANT AZ (DEUTSCHLAND) AG
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Filing: 1988-10-20
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Granted: 1990-05-22
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Expires: 2008-10-20
Abstract
Abstract A positive-working photosensitive composition is disclosed that comprises a photosensitive compound which is either of the o-quinone diazide type or comprises a photolytic acid donor in combination with a compound containing a C-O-C group, a binder which is soluble or swellable in an aqueous-alkaline solution and a dye of the general formula I <IMAGE> (I) The photosensitive composition of the present invention has a higher photosensitivity than comparable compositions containing other dyes.
Inventors
- 👤 Hans-Joachim Merrem
- 👤 Gerhard Buhr
- 👤 Ruediger Lenz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-03 19:09
CPC Classifications
G; G03; G03C; G03C1/00; G03F; G03F7/00; G03F7/004; G03F7/09; G03F7/091
Claims Analysis
Total Claims: 22
Claim 1
Independent Claim
195 words
Positive-working photosensitive composition comprising, in admixture: a positive-working photosensitive compound in an amount sufficient to render exposed areas soluble in a developer, said compound being selected from the group consisting of (1) an o-quinone diazide and (2) a combination of photolytic acid donor with an acid-cleavable compound, a binder that is isoluble in water and soluble or swellable in an aqueous-alkaline solution, present in an amount such that said composition forms a uniform film when applied to a substrate, and a dye comprising a non-bleachable compound that absorbs light in the region of actinic radiation to which the photosensitive compound responds and corresponds to the general formula I ##STR3## wherein R 1 denotes hydrogen, alkyl, aryl, alkoxy or nitrilo, R 2 and R 3 are identical or different and denote hydrogen, hydroxy, alkyl, aryl, alkoxy, aryloxy, nitrilo, amino, alkylamino or halogen, and R 4 , R 5 , R 6 and R 7 are identical or different and denote hydrogen, hydroxy, alkyl, aryl, alkoxy, aryloxy, amino, alkylamino or halogen wherein said dye is present in an amount sufficient to significantly reduce the effects of reflection when said composition is coated on a substrate and exposed.
Claim 2
Dependent Claim
195 words
Positive-working photosensitive composition comprising, in admixture: a positive-working photosensitive compound in an amount sufficient to render exposed areas soluble in a developer, said compound being selected from the group consisting of (1) an o-quinone diazide and (2) a combination of photolytic acid donor with an acid-cleavable compound, a binder that is isoluble in water and soluble or swellable in an aqueous-alkaline solution, present in an amount such that said composition forms a uniform film when applied to a substrate, and a dye comprising a non-bleachable compound that absorbs light in the region of actinic radiation to which the photosensitive compound responds and corresponds to the general formula I ##STR3## wherein R 1 denotes hydrogen, alkyl, aryl, alkoxy or nitrilo, R 2 and R 3 are identical or different and denote hydrogen, hydroxy, alkyl, aryl, alkoxy, aryloxy, nitrilo, amino, alkylamino or halogen, and R 4 , R 5 , R 6 and R 7 are identical or different and denote hydrogen, hydroxy, alkyl, aryl, alkoxy, aryloxy, amino, alkylamino or halogen wherein said dye is present in an amount sufficient to significantly reduce the effects of reflection when said composition is coated on a substrate and exposed.
Claim 3
Dependent Claim
25 words
A photosensitive composition as claimed in claim 1, wherein the dye has an absorption peak in the range of the emission of mercury vapor lamps.
Claim 4
Dependent Claim
23 words
A photosensitive composition as claimed in claim 1, wherein the dye has an absorption peak in the region from 365 to 436 nm.
Claim 5
Dependent Claim
16 words
A photosensitive composition as claimed in claim 1, wherein the photosensitive compound comprises an o-quinone diazide.
Claim 6
Dependent Claim
26 words
A photosensitive composition as claimed in claim wherein the photosensitive compound comprises a photolytic acid donor in combination with an acid-cleavable compound containing a C--O--C group.
Claim 7
Dependent Claim
18 words
A photosensitive composition as claimed in claim 5, wherein the photolytic acid donor comprises an organic halogen compound
Claim 8
Dependent Claim
15 words
A photosensitive composition as claimed in claim wherein the binder comprises a novolak condensation resin.
Claim 9
Dependent Claim
28 words
A photosensitive composition as claimed in claim 7, wherein the alkali-soluble novolak condensation resin is blended with up to 20% by weight of at least one other resin.
Claim 10
Dependent Claim
13 words
A photosensitive composition as claimed in claim 1, which comprises a crosslinking agent.
Claim 11
Dependent Claim
20 words
A positive-working photosensitive recording material comprising: a support, and a photosensitive layer comprising a composition as claimed in claim 1.
Claim 12
Dependent Claim
13 words
A photosensitive composition according to claim 1, consisting essentially of the recited components.
Claim 13
Dependent Claim
82 words
A photosensitive composition as claimed in claim 1, wherein R 1 denotes hydrogen, (C 1 -C 3 )alkyl or phenyl, R 2 and R 3 denote hydrogen, hydroxy, (C 1 -C 3 )alkyl, (C 6-C 10 )aryl, (C 1 -C 3 )alkoxy, amino, (C 1 -C 3 )alkylamino, halogen, and R 4 , R 5 , R 6 , and R 7 denote hydrogen (C 1 -C 3 )alkyl, (C 6 -C 10 )aryl, (C 1 -C 3 )alkoxy, amino or halogen.
Claim 14
Dependent Claim
60 words
A photosensitive composition as claimed in claim 1, wherein R 1 denotes hydrogen, R 2 and R 3 denote hydrogen, hydroxy, (C 1 -C 3 )alkyl, phenyl, amino or chlorine, and R 4 and R 6 and R 5 and R 7 are identical and denote hydrogen, (C 1 -C 3 )alkyl, (C 1 -C 3 )alkoxy, amino or chlorine.
Claim 15
Dependent Claim
50 words
A photosensitive composition as claimed in claim 1, wherein R 1 denotes hydrogen, R 2 and R 3 denote hydrogen, hydroxy or (C 1 -C 3 )alkyl and R 4 and R 6 and R 5 and R 7 are identical and denote hydrogen or (C 1 -C 3 )alkyl.
Claim 16
Dependent Claim
19 words
A photosensitive composition as claimed in claim 1, wherein the radicals R 1 to R 7 are all hydrogen.
Claim 17
Dependent Claim
27 words
A photosensitive composition as claimed in claim 1, wherein the radicals R 1 and R 3 to R 7 are all hydrogen and R 2 is methyl.
Claim 18
Dependent Claim
23 words
A photosensitive composition as claimed in claim 13, wherein R 2 and/or R 3 are hydroxy, (C 1 -C 3 )alkyl or phenyl.
Claim 19
Dependent Claim
29 words
A photosensitive composition as claimed in claim 17, wherein R 2 and/or R 3 are in each case in the o-position with respect to the tertiary aromatic amino group.
Claim 20
Dependent Claim
32 words
A photosensitive composition as claimed in claim 12, wherein R 2 and R 3 denote chlorine or bromine and R 4 , R 5 , R 6 and R 7 denote chlorine.
Claim 21
Dependent Claim
30 words
A photosensitive composition as claimed in claim 1, wherein the mixture comprises from 0.05 to 5% by weight of the dye, based on the nonvolatile constituents of the photosensitive composition.
Claim 22
Dependent Claim
30 words
A photosensitive composition as claimed in claim 1, wherein the mixture comprises from 0.02 to 2% by weight of the dye, based on the nonvolatile constituents of the photosensitive composition.
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Cited
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-05-21 | 1993-11-20 | 1994-05-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-05-21 | 1997-11-20 | 1998-05-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-05-21 | 2001-11-20 | 2002-05-22 | $7700.00 | Window Closed / Lapsed |