Patent US4927496A successfully refreshed from Google Patents.
US4927496A
Expired / Lapsed
US
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Sizing pulp
Assignee: Hercules LLC
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Filing: 1988-05-25
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Granted: 1990-05-22
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Expires: 2008-05-25
Abstract
Abstract Increased resistance of the cut edges of liquid packaging board to penetration by hot hydrogen peroxide is obtained by adding an aqueous emulsion of ketene dimer, cationic rosin size and insolubilizing agent either separately or in preblended form to the aqueous pulp slurry at a neutral to alkaline pH.
Inventors
- 👤 Stephen A. Walkden
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 03:17
CPC Classifications
D; D21; D21C; D21C3/00; D21H; D21H27/00; D21H27/10; D21H17/00; D21H17/03; D21H17/05; D21H17/17; D21H17/62; D21H17/71; D21H23/00; D21H23/02; D21H23/04; D21H23/06; D21H23/08; D21H23/10
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
96 words
The process of using an aqueous emulsion of from about 0.01 to about 0.6 percent, based on the dry weight of the pulp, of ketene dimer size, from about 0.4 to about 4 percent, based on the dry weight of the pulp, of cationic rosin size and insolubilizing agent, for increasing the resistance of the cut edges of liquid packaging board to penetration by hot hydrogen peroxide, said process comprising adding both sizes and the insolubilizing agent either separately or in preblended form to the aqueous pulp slurry at a pH of at least about 7.0.
Claim 2
Dependent Claim
96 words
The process of using an aqueous emulsion of from about 0.01 to about 0.6 percent, based on the dry weight of the pulp, of ketene dimer size, from about 0.4 to about 4 percent, based on the dry weight of the pulp, of cationic rosin size and insolubilizing agent, for increasing the resistance of the cut edges of liquid packaging board to penetration by hot hydrogen peroxide, said process comprising adding both sizes and the insolubilizing agent either separately or in preblended form to the aqueous pulp slurry at a pH of at least about 7.0.
Claim 3
Dependent Claim
27 words
The process of claim 1 wherein the insolubilizing agent is present in an amount of from about 0.5 to about 2 parts per part of cationic rosin.
Claim 4
Dependent Claim
19 words
The process of claim 1 wherein the ketene dimer has the formula: [R--CH═C═O].sub.2 where R is a hydrocarbon radical.
Claim 5
Dependent Claim
56 words
The process of claim 3 wherein the hydrocarbon radical of the ketene dimer is selected from the group consisting of alkyl having at least 6 C atoms, cycloalkyl having at least 6 C atoms, aryl having at least 6 C atoms, aralkyl having at least 8 C atoms, and alkaryl having at least 10 C atoms.
Claim 6
Dependent Claim
108 words
The process of claim 4 wherein the ketene dimer is selected from the group consisting of (a) octyl, decyl, dodecyl, tetradecyl, hexadecyl, octadecyl, eicosyl, docosyl, tetracosyl, phenyl, benzyl, beta-napthyl and cyclohexyl ketene dimers and the ketene dimers prepared from organic acids selected from the group consisting of montanic acid, naphthenic acid 9,10-decylenic acid 9,10-dodecylenic acid, palmitoleic acid, oleic acid, ricinoleic acid, linoleic acid, eleostearic acids, naturally occurring mixtures of fatty acids found in coconut oil, babassu oil, palm kernel oil, palm oil, olive oil, peanut oil, rape oil, beef tallow, lard (leaf) and whale blubber, and mixtures of any of the above named fatty acids with each other.
Claim 7
Dependent Claim
18 words
The process of claim 1 wherein the cationic rosin size comprises fortified rosin in liquid cationic dispersing agent.
Claim 8
Dependent Claim
16 words
The process of claim 6 wherein the liquid cationic dispersing agent is a cationic polyamide resin.
Claim 9
Dependent Claim
11 words
The process of claim 1 wherein the insolubilizing agent is alum.
Claim 10
Dependent Claim
45 words
The process of claim 1 wherein the cationic rosin size and the insolubilizing agent are added to the vessel in which the aqueous pulp slurry is formed and the ketene dimer size is added immediately before the slurry is fed to the board forming machine.
Claim 11
Dependent Claim
113 words
The process of claim 5 wherein the ketene dimer is present in an amount of from about 0.01 to about 0.6 db, the cationic rosin size comprises fortified rosin and cationic polyamide resin and is present in an amount of from about 0.4 to about 4 percent db, the solubilizing agent is alum and is present in an amount of from about 0.5 to about 2 parts per part of cationic rosin and wherein the cationic rosin size and the insolubilizing agent are added to the vessel in which the aqueous pulp slurry is formed and the ketene dimer size is added immediately before the slurry is fed to the board forming machine.
Claim 12
Dependent Claim
28 words
The process of claim 10 wherein the ketene dimer is selected from the group consisting of ketene dimers prepared from palmitoleic acid or eleostearic acid or mixtures thereof.
Claim 13
Dependent Claim
19 words
The process of claim 10 wherein the ketene dimer is present in an amount of about 0.12 percent db.
Claim 14
Dependent Claim
20 words
The process of claim 10 wherein the cationic rosin size is present in an amount of about 1 percent db.
Claim 15
Dependent Claim
26 words
The process of claim 10 wherein the alum is present in an amount of from about 1 to about 1.5 parts per part of cationic rosin.
Claim 16
Dependent Claim
61 words
The process of claim 11 wherein the ketene dimer is present in an amount of about 0.12 percent based on the dry weight of the pulp, the cationic rosin size is present in an amount of about 1 percent db and the alum is present in an amount of from about 1 to about 1.5 parts per part of cationic rosin.
Claim 17
Dependent Claim
32 words
The process of claim 15 wherein liquid packaging board is produced from the aqueous pulp slurry, container is made of said liquid packaging board, and said container contains latic acid containing liquid.
Claim 18
Dependent Claim
121 words
In a process for making a container for consumable liquids including the steps of forming paper board from a pulp slurry at a pH of at least about 7.0, cutting the board to packaging size and thereby exposing cut edges of the board, coating the board with polyethylene, treating it with a hot aqueous solution of hydrogen peroxide and forming the final packaging unit, the improvement comprising adding to the pulp before the paper board forming step an emulsion of from about 0.01 to about 0.6 percent, based on the dry weight of the pulp, of ketene dimer size, from about 0.4 to about 4 percent, based on the dry weight of the pulp, of cationic rosin size, and insolubilizing agent.
Claim 19
Dependent Claim
121 words
In a process for making a container for consumable liquids including the steps of forming paper board from a pulp slurry at a pH of at least about 7.0, cutting the board to packaging size and thereby exposing cut edges of the board, coating the board with polyethylene, treating it with a hot aqueous solution of hydrogen peroxide and forming the final packaging unit, the improvement comprising adding to the pulp before the paper board forming step an emulsion of from about 0.01 to about 0.6 percent, based on the dry weight of the pulp, of ketene dimer size, from about 0.4 to about 4 percent, based on the dry weight of the pulp, of cationic rosin size, and insolubilizing agent.
Claim 20
Dependent Claim
94 words
In a process for making a container for consumable liquids including the steps of forming paper board from a pulp slurry at neutral to alkaline pH, cutting the board to packaging size and thereby exposing cut edges of the board, coating the board with polyethylene, treating it with a hot aqueous solution of hydrogen peroxide and forming the final packaging unit, the improvement comprising adding to the pulp before the paper board forming step the ketene dimer, cationic rosin size and insolubilizing agent according to the process of claims 5, 10, 15 or 16.
References Cited (Backward Citations)
US4522686A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1993-05-21 | 1993-11-20 | 1994-05-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-05-21 | 1997-11-20 | 1998-05-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-05-21 | 2001-11-20 | 2002-05-22 | $7700.00 | Window Closed / Lapsed |