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Catalyst of aluminosilicate type containing at least one noble metal and its use for isomerizing a C8 aromatic cut

Assignee: IFP Energies nouvelles
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Filing: 1988-08-12
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Granted: 1990-05-08
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Expires: 2008-08-12
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Abstract

Abstract Catalyst of aluminosilicate type for isomerization of a C8 aromatic cut, characterized by the following composition, expressed by weight: (a) 0.01 to 1.5% of at least one metal selected from platinum and palladium, (b) 0 to 99.49% of a matrix, (c) 0.5 to 99.99% of a zeolite corresponding to the following approximate formula: M2/n O, Al2O3, X SiO2, wherein M is a proton and/or a metal cation, n is the valence of said cation, x is a number from 12 to 1000, the zeolite, of MFI structure, synthesized in fluoride medium, containing a fluorine proportion, incorporated therewith during the synthesis, in the range from 0.02 to 1.5% by weight.

Inventors

  • 👤 Christine Travers
  • 👤 Francis Raatz
  • 👤 Jean-Louis Guth
  • 👤 Henri Kessler

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 23:52
CPC Classifications
B; B01; B01J; B01J29/00; B01J29/04; B01J29/06; B01J29/40; B01J29/42; B01J29/44; C; C07; C07C; C07C5/00; C07C5/22; C07C5/27; C07C5/2702; C07C5/2724; B01J2229/00; B01J2229/10; B01J2229/26; B01J2229/30; B01J2229/42

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 112 words
An aluminosilicate catalyst comprising by weight: (a) 0.01 to 1.5% of at least one metal selected from platinum and palladium, (b) 0 to 99.49% of a matrix selected from the group formed of alumina, silica, magnesia, a clay or any combination of at least two of the above-mentioned compounds, and (c) 0.5 to 99.9% of a zeolite of MFI structure having a SiO 2 /Al 2 O 3 molar ratio from 12 to 1000, said zeolite, previously synthesized in fluoride medium at a pH lower than 10, having a fluorine content from 0.02 to 1.5% by weight, being characterized by an X-ray diffraction diagram as shown in table 1 of the description.
Claim 2
Dependent Claim 112 words
An aluminosilicate catalyst comprising by weight: (a) 0.01 to 1.5% of at least one metal selected from platinum and palladium, (b) 0 to 99.49% of a matrix selected from the group formed of alumina, silica, magnesia, a clay or any combination of at least two of the above-mentioned compounds, and (c) 0.5 to 99.9% of a zeolite of MFI structure having a SiO 2 /Al 2 O 3 molar ratio from 12 to 1000, said zeolite, previously synthesized in fluoride medium at a pH lower than 10, having a fluorine content from 0.02 to 1.5% by weight, being characterized by an X-ray diffraction diagram as shown in table 1 of the description.
Claim 3
Dependent Claim 18 words
A catalyst according to claim 1, wherein the platinum content ranges from 0.03 to 0.4 %, by weight.
Claim 4
Dependent Claim 18 words
A catalyst according to claim 1, wherein the zeolite content ranges from 40 to 90 % by weight.
Claim 5
Dependent Claim 19 words
A catalyst according to claim 1, wherein the matrix content ranges from about 10 to 60 % by weight.
Claim 6
Dependent Claim 23 words
A catalyst according to claim 1, wherein the fluorine content in proportion to said zeolite ranges from 0.2 to 1 % by weight.
Claim 7
Dependent Claim 42 words
A catalyst according to claim 1, wherein the zeolite has the formula M 2/n O: Al 2 O 3 :xSiO 2 , wherein M is a proton and/or a metal cation, n is the cation valence, and x is 12 to 1000.
Claim 8
Dependent Claim 18 words
A catalyst according to claim 1, wherein the amount of the zeolite in (C) is 40 to 90%.
Claim 9
Dependent Claim 18 words
A catalyst according to claim 1, wherein the amount of the zeolite in (c) is 60 to 85%.

References Cited (Backward Citations)

US4542117A Cited
US4588701A Cited
EP0201856A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-05-07 1993-11-06 1994-05-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-05-07 1997-11-06 1998-05-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-05-07 2001-11-06 2002-05-08 $7700.00 Window Closed / Lapsed

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