Silver halide photographic material

Claim 1

A silver halide photographic material comprising a support having thereof at least one light-sensitive silver halide emulsion layer, wherein said material contains the combination of (i) at least one compound represented by formula (I) added to a protective layer and (ii) at least one compound represented by formulae (II) and/or (III) added to a protective layer, an interlayer, a filter layer or an antihalation layer ##STR22## wherein R 1 represents hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group; X represents a halogen atom, a nitro group, a hydroxyl group, a cyano group, a lower alkyl group, a lower alkoxy group, --COR 2 , ##STR23## or --SO 3 M; R 2 represents hydrogen, --OM, a lower alkyl group, an aryl group, an aralkyl group, a lower alkoxy group, an aryloxy group, an aralkyloxy group or ##STR24## R 3 and R 4 , which may be the same or different, each represents hydrogen, a lower alkyl group, an aryl group, an aralkyl group, --COR 7 or --SO 2 R 7 ; R 5 and R 6 , which may be the same or different, each represents hydrogen, a lower alkyl group, an aryl group or an aralkyl group; R 7 represents a lower alkyl group, an aryl group or an aralkyl group; M represents hydrogen, an alkali metal atom or a monovalent cation; m represents 0 or an integer of 1 to 4, n represents 0 or an integer of 1 to 4, and Z represents an atomic group necessary for forming a thiazolyl ring ##STR25## wherein R 8 represents a lower alkylene group, X is the same as defined for X in formula (I); p represents 0 or 1, and q represents 0 or an integer of 1 to 5; and ##STR26## wherein R 9 represents hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted aralkyl group, a substituted or unsubstituted aryl group, a heterocyclic group, ##STR27## R 10 and R 11 each represents hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a cyano group, a heterocyclic group, a substituted or unsubstituted alkylthio group, a substituted or unsubstituted arylthio group, a substituted or unsubstituted alkylsulfonyloxy group or a substituted or unsubstituted alkylsulfonyl group; R 10 and R 11 may be linked to form an aromatic ring; and R 12 and R 13 , which may be the same or different, each represents hydrogen, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a substituted or unsubstituted aralkyl group.