US4918150A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Composition comprising vinyl ester, unsaturated urethane and polybasic acid
Assignee: DIC Corp
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Filing: 1988-11-30
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Granted: 1990-04-17
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Expires: 2008-11-30
Abstract
Abstract An activation energy-curable resin composition comprising as an essential ingredient a resin obtained by reacting (a) a reaction product of a novolak-epoxy compound and an unsaturated monocarboxylic acid, (b) a reaction product of a diisocyanate and a poly(meth)acrylate having a hydroxyl group per moleucle and (c) at least one of an aromatic, aliphatic or alicyclic polybasic acid (or an anhydride thereof).
Inventors
- 👤 Shigeru Sakakibara
- 👤 Shunji Arimoto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 02:50
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/42; C08F; C08F299/00; C08F299/02; C08F299/022; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/6705; C08G18/70; C08G18/81; C08G18/8141; C08G18/815; C08G18/8158; C08G18/8175; C08L; C08L63/00; C08L63/10; Y; Y10; Y10S; Y10S525/00; Y10S525/92
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
65 words
An activation energy-curable resin composition comprising as an essential ingredient a resin obtained by reacting (a) a reaction product of a novolak-epoxy compound and an unsaturated monocarboxylic acid, (b) a reaction product having one isocyanate group of a diisocyanate and a poly(meth)acrylate having a hydroxyl group per molecule and (c) at least one of an aromatic, aliphatic or alicyclic polybasic acid or an anhydride thereof.
Claim 2
Dependent Claim
65 words
An activation energy-curable resin composition comprising as an essential ingredient a resin obtained by reacting (a) a reaction product of a novolak-epoxy compound and an unsaturated monocarboxylic acid, (b) a reaction product having one isocyanate group of a diisocyanate and a poly(meth)acrylate having a hydroxyl group per molecule and (c) at least one of an aromatic, aliphatic or alicyclic polybasic acid or an anhydride thereof.
Claim 3
Dependent Claim
40 words
An activation energy-curable resin composition according to claim 1, wherein said reaction product (a) of the novolak-epoxy compound and the unsaturated monocarboxylic acid is obtained by the addition reaction of a polycondensate of phenol and formaldehyde with epichlorohydrin or β-methylepichlorohydrin.
Claim 4
Dependent Claim
50 words
An activation energy-curable resin composition according to claim 1, wherein said reaction product (a) of the novolak-epoxy compound and the unsaturated monocarboxylic acid is obtained by the addition reaction of a polycondensate of an alkyl phenol having a C 1 -C 9 alkyl group and formaldehyde with epichlorohydrin or β-methylepichlorohydrin.
Claim 5
Dependent Claim
27 words
An activation energy-curable resin composition according to any one of claims 1, 2 or 3 wherein said novolak-epoxy compound contains from 3 to 8 phenol nucleus residues.
Claim 6
Dependent Claim
24 words
An activation energy-curable resin composition according to claim 1 wherein the unsaturated monocarboxylic acid is acrylic acid, methacrylic acid, crotonic acid or cinnamic acid.
Claim 7
Dependent Claim
50 words
An activation energy-curable resin composition according to claim 1, wherein the reaction product (a), the novolak-epoxy compound and the unsaturated monocarboxylic acid are reacted at an equivalent ratio of the epoxy group of the novolak-epoxy compound to the carboxyl group of the monocarboxylic acid in the range of from 1.0-1.7:1.0.
Claim 8
Dependent Claim
68 words
An activation energy-curable resin composition according to claim 1 wherein the resin is obtained by reacting the reaction product (a), reaction product (b) and polybasic acid or anhydride (c) at equivalent ratios of the isocyanate group (--NCO) of the reaction product (b), the group ##STR5## of the polycarboxylic acid or anhydride thereof (c) and the hydroxyl group (--OH) of the reaction product (a) in the following ranges ##STR6##
Claim 9
Dependent Claim
41 words
An activation energy-curable resin composition according to claim 1 wherein the poly(meth)acrylate having an hydroxyl group per molecule is at least one compound selected from the group consisting of pentaerythritol tri(meth)acrylate, dipentaerythritol penta(meth)acrylate, trimethylol-propane di(meth)acrylate, glycerol di(meth)acrylate and tris(hydroxyethyl) isocyanurate di(meth)acrylate.
Claim 10
Dependent Claim
55 words
An activation energy-curable resin composition according to claim 1 or 8 wherein the reaction product (b) is prepared by reacting the hydroxyl group-containing poly(meth)acrylate and the diisocyanate at an equivalent ratio of the hydroxyl group of the hydroxyl group-containing poly(meth)acrylate to the isocyanate group of the diisocyanate in the range of from 1.0:2.0 to 1.3:2.0.
Claim 11
Dependent Claim
68 words
An activation energy-curable resin composition according to claim 1 wherein the resin is obtained by reacting the reaction product (a), reaction product (b) and polybasic acid or anhydride (c) at equivalent ratios of the isocyanate group (--NCO) of the reaction product (b), the group ##STR7## of the polycarboxylic acid or anhydride thereof (c) and the hydroxyl group (--OH) of the reaction product (a) in the following ranges ##STR8##
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-04-16 | 1993-10-16 | 1994-04-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-04-16 | 1997-10-16 | 1998-04-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-04-16 | 2001-10-16 | 2002-04-17 | $7700.00 | Window Closed / Lapsed |