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US4916185A
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Olefinic impact modifiers for compatible blends of polyphenylene ethers and linear polyester resins
Assignee: General Electric Co
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Filing: 1987-09-09
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Granted: 1990-04-10
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Expires: 2007-09-09
Abstract
Abstract Thermoplastic compositions comprising polyphenylene ethers and polyesters, impact-modified by glycidyl (meth)acrylate grafted EPDM and compatibilized by an aromatic polycarbonate exhibit high impact strength alone and when combined with other impact modifiers. Their shear sensitive viscosity properties makes them uniquely suitable for extrusion and blow molding applications.
Inventors
- 👤 John B. Yates, III
- 👤 Charles F. Pratt
- 👤 Angelika H. McHale
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 21:05
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02; C08L69/00; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/126; Y; Y10; Y10S; Y10S525/00; Y10S525/905
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
150 words
An impact modified thermoplastic composition comprising the following various components and any reaction products thereof: (a) a compatible resin composition comprising (i) at least one polyphenylene ether resin, alone, or in combination with a polystyrene resin selected from the group consisting of a styrene homopolymer, a random copolymer of styrene and a rubber modified polystyrene; (ii) at least one poly(alkylene dicarboxylate) ratio of component (i) to component (ii) being at most 1.5:1; and (iii) at least one polymer containing a substantial proportion of aromatic polycarbonate units; and (b) an effective amount of an impact modifier comprising an EPDM terpolymer grafted with a compound selected from the group consisting of glycidyl methacrylate, glycidyl acrylate and a mixture thereof, alone, or grafted in further combination with a compound selected from the group consisting of a C 1 -C 18 alkyl methacrylate, a C 1 -C 18 alkyl acrylate and a mixture thereof.
Claim 2
Dependent Claim
150 words
An impact modified thermoplastic composition comprising the following various components and any reaction products thereof: (a) a compatible resin composition comprising (i) at least one polyphenylene ether resin, alone, or in combination with a polystyrene resin selected from the group consisting of a styrene homopolymer, a random copolymer of styrene and a rubber modified polystyrene; (ii) at least one poly(alkylene dicarboxylate) ratio of component (i) to component (ii) being at most 1.5:1; and (iii) at least one polymer containing a substantial proportion of aromatic polycarbonate units; and (b) an effective amount of an impact modifier comprising an EPDM terpolymer grafted with a compound selected from the group consisting of glycidyl methacrylate, glycidyl acrylate and a mixture thereof, alone, or grafted in further combination with a compound selected from the group consisting of a C 1 -C 18 alkyl methacrylate, a C 1 -C 18 alkyl acrylate and a mixture thereof.
Claim 3
Dependent Claim
74 words
A composition as defined in claim 1 wherein component (a)(i) comprises from about 15 to about 45 percent by weight; component (a)(ii) comprises from about 15 to about 45 percent by weight component (a)(iii) comprises from about 3 to about 50 percent by weight; and component (b) comprises from about 8 to about 25 percent by weight, all percentage proportions being based on the weight of the total various resinous components in the composition.
Claim 4
Dependent Claim
17 words
A composition as defined in claim 1 wherein component (a)(i) comprises a polyphenylene ether and a polystyrene.
Claim 5
Dependent Claim
14 words
A composition as defined in claim 1 wherein said polyphenylene ether comprises poly(2,6-dimethyl-1,4-phenylene ether).
Claim 6
Dependent Claim
14 words
A composition as defined in claim 3 wherein the polyphenylene ether comprises poly(2,6-dimethyl-1,4-phenylene ether).
Claim 7
Dependent Claim
27 words
A composition as defined in claim 1 wherein component (a)(ii) comprises poly(ethylene terephthalate); poly(butylene terephthalate) or a mixture thereof and component (a)(iii) comprises bisphenol A polycarbonate units.
Claim 8
Dependent Claim
13 words
A composition as defined in claim 6 wherein component (a)(ii) comprises poly(1,4-butylene terephthalate).
Claim 9
Dependent Claim
13 words
A composition according to claim 1 wherein component (a)(iii) comprises a polycarbonate hompopolymer.
Claim 10
Dependent Claim
33 words
A composition as defined in claim 1 wherein the grafted EPDM terpolymer is derived from approximately 45 to 70 mole percent ethylene, approximately 30-55 mole percent propylene and a minor amount of 5-ethylidene-2-norbornene.
Claim 11
Dependent Claim
36 words
A composition as defined in claim 2 wherein the EPDM-glycidyl ester grafted terpolymer is present in an amount of, approximately, 10 to 20 percent by weight based on the total weight of resins in the composition.
Claim 12
Dependent Claim
31 words
A composition as defined in claim 1 wherein in component (b) the EPFDM tereplymer is grafted with 2% more by weight based on said terpolymer of glycidyl methacrylate or glycidyl acrylate.
Claim 13
Dependent Claim
19 words
An article of manufacture comprising a container blow-molded from an impact modified thermoplastic composition as defined in claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-04-09 | 1993-10-09 | 1994-04-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-04-09 | 1997-10-09 | 1998-04-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-04-09 | 2001-10-09 | 2002-04-10 | $7700.00 | Window Closed / Lapsed |