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US4915867A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid crystal high molecular material

Assignee: Idemitsu Kosan Co Ltd
•
Filing: 1987-07-16
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Granted: 1990-04-10
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Expires: 2007-07-16
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Abstract

Abstract This invention comprises a liquid crystalline high molecular weight polymer material which comprises the hydrogen bonded reaction product of a non-liquid crystalline polymer having a proton donor and/or a proton acceptor and a low molecular weight compound having bonded in the molecule respectively a proton acceptor and/or a proton donor which can be bond to said proton donor and/or proton acceptor respectively through hydrogen bonding and having liquid crystallinity. This material forms a smectic phase at a lower temperature than a simple mixture and has usefulness in the field of optical electronics.

Inventors

  • 👤 Kazuharu Morita
  • 👤 Satoshi Hachiya

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 06:22
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/04; C09K19/38; C09K2323/00

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 210 words
A liquid crystal high molecular weight material comprising the hydrogen bonded product of a non-liquid crystalline polymer having proton transfer functionality selected from a group consisting of polyacrylic acid, polymethacrylic acid, polyacrylate, polymethacrylate, polyacrylamide, polyvinyl alcohol and its partial hydrolysis, and polyvinyl acetate, the polymerization degree of the polymer being 10-10,000; and a low molecular weight compound having the formula A--X--Y--Z, which has proton transfer functionality opposite to and reactive with the proton transfer functionality of said polymer, to produce hydrogen bending, said low molecular weight compound being at least one compound having a terminal group A having a proton donor and/or a proton acceptor selected from: ##STR38## a cyclic group X selected from: ##STR39## ##STR40## wherein k represents and integer of about 1 or 2, a bridging group Y selected from --O--, --COO--, --OCO--, --CO--S--, --CH═C(CN)--, --CH═CH-- and --CO--CH 2 --, and a chiral terminal group Z represented by the following formula: ##STR41## wherein R represents a lower alkyl group, a halogen atom or a nitrile group, m represents an integer of 0-5 and n represents 0 or 1, the number of proton transfer functional groups of the low molecular weight compounds being about the same as the number of proton transfer functional groups of the non-liquid crystalline polymer.
Claim 2
Dependent Claim 210 words
A liquid crystal high molecular weight material comprising the hydrogen bonded product of a non-liquid crystalline polymer having proton transfer functionality selected from a group consisting of polyacrylic acid, polymethacrylic acid, polyacrylate, polymethacrylate, polyacrylamide, polyvinyl alcohol and its partial hydrolysis, and polyvinyl acetate, the polymerization degree of the polymer being 10-10,000; and a low molecular weight compound having the formula A--X--Y--Z, which has proton transfer functionality opposite to and reactive with the proton transfer functionality of said polymer, to produce hydrogen bending, said low molecular weight compound being at least one compound having a terminal group A having a proton donor and/or a proton acceptor selected from: ##STR38## a cyclic group X selected from: ##STR39## ##STR40## wherein k represents and integer of about 1 or 2, a bridging group Y selected from --O--, --COO--, --OCO--, --CO--S--, --CH═C(CN)--, --CH═CH-- and --CO--CH 2 --, and a chiral terminal group Z represented by the following formula: ##STR41## wherein R represents a lower alkyl group, a halogen atom or a nitrile group, m represents an integer of 0-5 and n represents 0 or 1, the number of proton transfer functional groups of the low molecular weight compounds being about the same as the number of proton transfer functional groups of the non-liquid crystalline polymer.
Claim 3
Dependent Claim 26 words
A liquid crystal high molecular weight material as claimed in claim 1 wherein said polymer contains a proton acceptor and said compound contains a proton donor.
Claim 4
Dependent Claim 26 words
A liquid crystal high molecular weight material as claimed in claim 1 wherein said polymer contains a proton donor and said compound contains a proton acceptor.
Claim 5
Dependent Claim 28 words
A liquid crystal high molecular weight material according to claim 1 wherein said non-liquid crystalline polymer is at least one of polyacrylic acid, polyvinyl acetate or polyvinyl alcohol.
Claim 6
Dependent Claim 25 words
A liquid crystal high molecular weight material according to claim 1 wherein said low molecular weight compound is selected from the group consisting of ##STR42##
Claim 7
Dependent Claim 25 words
A liquid crystal high molecular weight material according to claim 2 wherein said low molecular weight compound is selected from the group consisting of ##STR43##
Claim 8
Dependent Claim 10 words
A shaped article comprising the materials claimed in claim 1.
Claim 9
Dependent Claim 11 words
A material as claimed in claim 1 in the smectic phase.

References Cited (Backward Citations)

JPS5842685A Cited
JPS5891759A Cited
DE3324770A1 Cited
US4434262A Cited
JPS6137892A Cited
JPS6147427A Cited
JPS6160734A Cited
JPS62238243A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-04-09 1993-10-09 1994-04-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-04-09 1997-10-09 1998-04-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-04-09 2001-10-09 2002-04-10 $7700.00 Window Closed / Lapsed

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