US4915867A
Expired / Lapsed
US
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Liquid crystal high molecular material
Assignee: Idemitsu Kosan Co Ltd
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Filing: 1987-07-16
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Granted: 1990-04-10
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Expires: 2007-07-16
Abstract
Abstract This invention comprises a liquid crystalline high molecular weight polymer material which comprises the hydrogen bonded reaction product of a non-liquid crystalline polymer having a proton donor and/or a proton acceptor and a low molecular weight compound having bonded in the molecule respectively a proton acceptor and/or a proton donor which can be bond to said proton donor and/or proton acceptor respectively through hydrogen bonding and having liquid crystallinity. This material forms a smectic phase at a lower temperature than a simple mixture and has usefulness in the field of optical electronics.
Inventors
- 👤 Kazuharu Morita
- 👤 Satoshi Hachiya
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 06:22
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/04; C09K19/38; C09K2323/00
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
210 words
A liquid crystal high molecular weight material comprising the hydrogen bonded product of a non-liquid crystalline polymer having proton transfer functionality selected from a group consisting of polyacrylic acid, polymethacrylic acid, polyacrylate, polymethacrylate, polyacrylamide, polyvinyl alcohol and its partial hydrolysis, and polyvinyl acetate, the polymerization degree of the polymer being 10-10,000; and a low molecular weight compound having the formula A--X--Y--Z, which has proton transfer functionality opposite to and reactive with the proton transfer functionality of said polymer, to produce hydrogen bending, said low molecular weight compound being at least one compound having a terminal group A having a proton donor and/or a proton acceptor selected from: ##STR38## a cyclic group X selected from: ##STR39## ##STR40## wherein k represents and integer of about 1 or 2, a bridging group Y selected from --O--, --COO--, --OCO--, --CO--S--, --CH═C(CN)--, --CH═CH-- and --CO--CH 2 --, and a chiral terminal group Z represented by the following formula: ##STR41## wherein R represents a lower alkyl group, a halogen atom or a nitrile group, m represents an integer of 0-5 and n represents 0 or 1, the number of proton transfer functional groups of the low molecular weight compounds being about the same as the number of proton transfer functional groups of the non-liquid crystalline polymer.
Claim 2
Dependent Claim
210 words
A liquid crystal high molecular weight material comprising the hydrogen bonded product of a non-liquid crystalline polymer having proton transfer functionality selected from a group consisting of polyacrylic acid, polymethacrylic acid, polyacrylate, polymethacrylate, polyacrylamide, polyvinyl alcohol and its partial hydrolysis, and polyvinyl acetate, the polymerization degree of the polymer being 10-10,000; and a low molecular weight compound having the formula A--X--Y--Z, which has proton transfer functionality opposite to and reactive with the proton transfer functionality of said polymer, to produce hydrogen bending, said low molecular weight compound being at least one compound having a terminal group A having a proton donor and/or a proton acceptor selected from: ##STR38## a cyclic group X selected from: ##STR39## ##STR40## wherein k represents and integer of about 1 or 2, a bridging group Y selected from --O--, --COO--, --OCO--, --CO--S--, --CH═C(CN)--, --CH═CH-- and --CO--CH 2 --, and a chiral terminal group Z represented by the following formula: ##STR41## wherein R represents a lower alkyl group, a halogen atom or a nitrile group, m represents an integer of 0-5 and n represents 0 or 1, the number of proton transfer functional groups of the low molecular weight compounds being about the same as the number of proton transfer functional groups of the non-liquid crystalline polymer.
Claim 3
Dependent Claim
26 words
A liquid crystal high molecular weight material as claimed in claim 1 wherein said polymer contains a proton acceptor and said compound contains a proton donor.
Claim 4
Dependent Claim
26 words
A liquid crystal high molecular weight material as claimed in claim 1 wherein said polymer contains a proton donor and said compound contains a proton acceptor.
Claim 5
Dependent Claim
28 words
A liquid crystal high molecular weight material according to claim 1 wherein said non-liquid crystalline polymer is at least one of polyacrylic acid, polyvinyl acetate or polyvinyl alcohol.
Claim 6
Dependent Claim
25 words
A liquid crystal high molecular weight material according to claim 1 wherein said low molecular weight compound is selected from the group consisting of ##STR42##
Claim 7
Dependent Claim
25 words
A liquid crystal high molecular weight material according to claim 2 wherein said low molecular weight compound is selected from the group consisting of ##STR43##
Claim 8
Dependent Claim
10 words
A shaped article comprising the materials claimed in claim 1.
Claim 9
Dependent Claim
11 words
A material as claimed in claim 1 in the smectic phase.
References Cited (Backward Citations)
JPS5842685A
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JPS5891759A
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DE3324770A1
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US4434262A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-04-09 | 1993-10-09 | 1994-04-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-04-09 | 1997-10-09 | 1998-04-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-04-09 | 2001-10-09 | 2002-04-10 | $7700.00 | Window Closed / Lapsed |