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US4434262A Expired / Lapsed US ⏱️ 0.0 years remaining

Melt processable blend of a low molecular weight liquid crystalline compound and a polyolefin or polyester

Assignee: Celanese Corp
•
Filing: 1982-09-01
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Granted: 1984-02-28
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Expires: 2002-09-01
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Abstract

Abstract An improved melt processable blend is provided comprised of a polymer selected from the group consisting of a polyolefin and a polyester and a low molecular weight liquid crystalline compound which is capable of forming an anisotropic melt phase at the melt processing temperature of the blend.

Inventors

  • 👤 Alan Buckley
  • 👤 Anthony B. Conciatori
  • 👤 Gordon W. Calundann

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 17:21
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/09; C08K5/16; C08K5/17; C08K5/18

Claims Analysis

Total Claims: 31
Claim 1
Independent Claim 91 words
A melt processable blend comprising a major amount of a melt processable polymer which is not capable of forming an anisotropic melt phase apart from the blend selected from the group consisting of a polyolefin and a polyester and a minor amount of a liquid crystalline compound having a molecular weight of less than about 1000 selected from the group consisting of N,N'-bis(p-methoxybenzylidene)-alpha, alpha'-bi-p-toluidine, p-methoxycinnamic acid, N,N'-bis(4-octyloxybenzylidene)-p-phenylenediamine, and mixtures thereof which is capable of forming an anisotropic melt phase apart from the blend at the melt processing temperature of the blend.
Claim 2
Dependent Claim 91 words
A melt processable blend comprising a major amount of a melt processable polymer which is not capable of forming an anisotropic melt phase apart from the blend selected from the group consisting of a polyolefin and a polyester and a minor amount of a liquid crystalline compound having a molecular weight of less than about 1000 selected from the group consisting of N,N'-bis(p-methoxybenzylidene)-alpha, alpha'-bi-p-toluidine, p-methoxycinnamic acid, N,N'-bis(4-octyloxybenzylidene)-p-phenylenediamine, and mixtures thereof which is capable of forming an anisotropic melt phase apart from the blend at the melt processing temperature of the blend.
Claim 3
Dependent Claim 24 words
The blend of claim 1 which is capable of undergoing melt processing at a temperature within the range of approximately 150° to 370° C.
Claim 4
Dependent Claim 17 words
The blend of claim 1 wherein said polyolefin comprises alkylene units of 2 to 5 carbon atoms.
Claim 5
Dependent Claim 10 words
The blend of claim 3 wherein said polyolefin is polyethylene.
Claim 6
Dependent Claim 29 words
The blend of claim 1 wherein said liquid crystalline compound apart from said blend is capable of forming an anisotropic melt phase at a temperature below approximately 370° C.
Claim 7
Dependent Claim 31 words
The blend of claim 1 wherein said melt processable polymer is present in an amount ranging from about 50 to 99.5 percent by weight based on the weight of the blend.
Claim 8
Dependent Claim 32 words
The blend of claim 1 wherein said liquid crystalline compound is present in an amount ranging from about 0.5 to about 50 percent by weight based on the weight of the blend.
Claim 9
Dependent Claim 23 words
The blend of claim 7 wherein said liquid crystalline compound is present in an amount of less than about 10 percent by weight.
Claim 10
Dependent Claim 23 words
The blend of claim 7 wherein said liquid crystalline compound is present in an amount of less than about 5 percent by weight.
Claim 11
Dependent Claim 11 words
The blend of claim 1 wherein said polyester is poly(ethylene terephthalate).
Claim 12
Dependent Claim 28 words
The blend of claim 1 further comprising approximately 1 to 50 percent by weight of a solid filler and/or reinforcing agent based on the weight of the blend.
Claim 13
Dependent Claim 28 words
The blend of claim 1 further comprising approximately 10 to 30 percent by weight of a solid filler and/or reinforcing agent based on the weight of the blend.
Claim 14
Dependent Claim 10 words
A molded article comprised of the blend of claim 1.
Claim 15
Dependent Claim 13 words
A fiber which has been melt spun from the blend of claim 1.
Claim 16
Dependent Claim 13 words
A film which has been melt extruded from the blend of claim 1.
Claim 17
Dependent Claim 111 words
An improved method for the melt extrusion of a polymer which is not capable of forming an anisotropic melt phase apart from the blend selected from the group consisting of a polyolefin and a polyester by which the melt viscosity of the polymer is reduced comprising providing a blend which comprises a major amount of said polymer and a minor amount of a liquid crystalline compound having a molecular weight below about 1000 selected from the group consisting of N,N'-bis(p-methoxybenzylidene)-alpha,alpha'-bi-p-toluidine, p-methoxycinnamic acid, N,N'-bis(4-octyloxybenzylidene)-p-phenylenediamine, and mixtures thereof which is capable of forming an anisotropic melt phase apart from the blend at the melt processing temperature of the blend and extruding said blend.
Claim 18
Dependent Claim 111 words
An improved method for the melt extrusion of a polymer which is not capable of forming an anisotropic melt phase apart from the blend selected from the group consisting of a polyolefin and a polyester by which the melt viscosity of the polymer is reduced comprising providing a blend which comprises a major amount of said polymer and a minor amount of a liquid crystalline compound having a molecular weight below about 1000 selected from the group consisting of N,N'-bis(p-methoxybenzylidene)-alpha,alpha'-bi-p-toluidine, p-methoxycinnamic acid, N,N'-bis(4-octyloxybenzylidene)-p-phenylenediamine, and mixtures thereof which is capable of forming an anisotropic melt phase apart from the blend at the melt processing temperature of the blend and extruding said blend.
Claim 19
Dependent Claim 26 words
The method of claim 16 wherein said blend is capable of undergoing melt processing at a temperature within the range of approximately 150° to 370° C.
Claim 20
Dependent Claim 17 words
The method of claim 16 wherein said polyolefin comprises alkylene units of 2 to 5 carbon atoms.
Claim 21
Dependent Claim 10 words
The method of claim 18 wherein said polyolefin is polyethylene.
Claim 22
Dependent Claim 29 words
The method of claim 16 wherein said liquid crystalline compound apart from said blend is capable of forming an anisotropic melt phase at a temperature below approximately 370° C.
Claim 23
Dependent Claim 31 words
The method of claim 16 wherein said melt processable polymer is present in an amount ranging from about 50 to 99.5 percent by weight based on the weight of the blend.
Claim 24
Dependent Claim 32 words
The method of claim 16 wherein said liquid crystalline compound is present in an amount ranging from about 0.5 to about 50 percent by weight based on the weight of the blend.
Claim 25
Dependent Claim 23 words
The method of claim 22 wherein said liquid crystalline compound is present in an amount of less than about 10 percent by weight.
Claim 26
Dependent Claim 23 words
The method of claim 22 wherein said liquid crystalline compound is present in an amount of less than about 5 percent by weight.
Claim 27
Dependent Claim 11 words
The method of claim 16 wherein said polyester is poly(ethylene terephthalate).
Claim 28
Dependent Claim 31 words
The method of claim 16 wherein said blend further comprises approximately 1 to 50 percent by weight of a solid filler and/or reinforcing agent based on the weight of the blend.
Claim 29
Dependent Claim 31 words
The method of claim 16 wherein said blend further comprises approximately 10 to 30 percent by weight of a solid filler and/or reinforcing agent based on the weight of the blend.
Claim 30
Dependent Claim 12 words
The blend of claim 1 wherein said liquid crystalline compound is N,N'-bis(p-methoxybenzylidene)-alpha,alpha'-bi-p-toluidine.
Claim 31
Dependent Claim 12 words
The method of claim 16 wherein said liquid crystalline polymer is N,N'-bis(p-methoxybenzylidene)-alpha,alpha'-bi-p-toluidine.

References Cited (Backward Citations)

US3974114A Cited
US4351751A Cited
US4344874A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1987-02-27 1987-08-29 1988-02-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1991-02-27 1991-08-29 1992-02-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1995-02-27 1995-08-29 1996-02-28 $7700.00 Window Closed / Lapsed

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