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US4912016A Expired / Lapsed US ⏱️ 0.0 years remaining

High contrast photographic recording material and emulsion and process for their development

Assignee: Eastman Kodak Co
•
Filing: 1988-05-31
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Granted: 1990-03-27
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Expires: 2008-05-31
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Abstract

Abstract A photographic recording material and emulsion are described which are capable of providing high contrast images. The recording material and emulsion comprises negative working silver halide and contrast enhancing arylhydrazide nucleating agents. A process for utilization of the elements and emulsions is also described.

Inventors

  • 👤 Harold I. Machonkin
  • 👤 Lee J. Fleckenstein
  • 👤 Donald L. Kerr

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 09:33
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/061; C; C07; C07C; C07C323/00; C07C323/50; C07C323/51; C07C323/60

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 48 words
A photographic recording material capable of providing a high contrast silver image which comprises a support having thereon a negative-working silver halide emulsion layer and a hydrazide compound having the following structural formula: ##STR10## wherein: R is alkyl having from 4 to about 8 carbon atoms or cyclohexyl.
Claim 2
Dependent Claim 48 words
A photographic recording material capable of providing a high contrast silver image which comprises a support having thereon a negative-working silver halide emulsion layer and a hydrazide compound having the following structural formula: ##STR10## wherein: R is alkyl having from 4 to about 8 carbon atoms or cyclohexyl.
Claim 3
Dependent Claim 15 words
The photographic recording material of claim 1 wherein R is a branched chain alkyl group.
Claim 4
Dependent Claim 31 words
The photographic recording material of claim 1 wherein the R alkyl or cyclohexyl group is substituted with halogen, amino, OH, SH or alkyl comprising from 1 to about 3 carbon atoms.
Claim 5
Dependent Claim 31 words
The photographic recording material of claim 1 wherein the hydrazide compound is present in an amount of from about 10 -4 to about 10 -1 mol thereof per mol of silver.
Claim 6
Dependent Claim 31 words
The photographic recording material of claim 4 wherein the hydrazide compound is present in an amount of from about 5×10 -4 to about 5×10 -2 mol thereof per mol of silver.
Claim 7
Dependent Claim 16 words
The photographic recording material of claim 1 wherein the hydrazide compound has the structural formula: ##STR11##
Claim 8
Dependent Claim 12 words
The photographic recording material of claim 1 having the structural formula: ##STR12##
Claim 9
Dependent Claim 12 words
The photographic recording material of claim 1 having the structural formula: ##STR13##
Claim 10
Dependent Claim 12 words
The photographic recording material of claim 1 having the structural formula: ##STR14##
Claim 11
Dependent Claim 33 words
A photographic emulsion comprising negative working silver halide and a hydrazide nucleating compound having the following structural formula: ##STR15## wherein: R is alkyl having from 4 to about 8 carbon atoms or cyclohexyl.
Claim 12
Dependent Claim 33 words
A photographic emulsion comprising negative working silver halide and a hydrazide nucleating compound having the following structural formula: ##STR15## wherein: R is alkyl having from 4 to about 8 carbon atoms or cyclohexyl.
Claim 13
Dependent Claim 14 words
The photographic emulsion of claim 10 wherein R is a branched chain alkyl group.
Claim 14
Dependent Claim 30 words
The photographic emulsion of claim 10 wherein the R alkyl or cyclohexyl group is substituted with halogen, amino, OH, SH or alkyl comprising from 1 to about 3 carbon atoms.
Claim 15
Dependent Claim 30 words
The photographic emulsion of claim 10 wherein the hydrazide compound is present in an amount of from about 10 -4 to about 10 -1 mol thereof per mol of silver.
Claim 16
Dependent Claim 30 words
The photographic emulsion of claim 13 wherein the hydrazide compound is present in an amount of from about 5×10 -4 to about 5×10 -2 mol thereof per mol of silver.
Claim 17
Dependent Claim 11 words
The photographic emulsion of claim 10 having the structural formula: ##STR16##
Claim 18
Dependent Claim 11 words
The photographic emulsion of claim 10 having the structural formula: ##STR17##
Claim 19
Dependent Claim 11 words
The photographic emulsion of claim 10 having the structural formula: ##STR18##
Claim 20
Dependent Claim 11 words
The photographic emulsion of claim 10 having the structural formula: ##STR19##

References Cited (Backward Citations)

US4323643A Cited
US4429036A Cited
US4540655A Cited
US4681836A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-03-26 1993-09-25 1994-03-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-03-26 1997-09-25 1998-03-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-03-26 2001-09-25 2002-03-27 $7700.00 Window Closed / Lapsed

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