US4911864A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Curable compositions
Assignee: Eneos Corp
•
Filing: 1988-03-02
•
Granted: 1990-03-27
•
Expires: 2008-03-02
Abstract
Abstract Curable compositions essentially comprise a selected class of starting compounds and a selected class of particulate metallic oxides as electrically conductive components, the oxides being coated with a selected class of hydrolyzed silicon compounds of the formula R.sub.m.sup.1 R.sub.n.sup.2 Si(OR.sup.3).sub.4-(m+n) where R 1 and R 2 each are a hydrocarbon moiety of 1 to 20 carbon atoms or an organic group containing a halogen atom or an epoxy, acrylonitrile, methacrylonitrile, mercapto or amino group, each of the hydrocarbon moiety and organic group forming a Si-C bond, R 3 is a hydrocarbon moiety of 1 to 6 carbon atoms or an oxygen-containing hydrocarbon moiety, m and n each are 0, 1 or 2, and the sum of m and n is 1 or 2. The resulting cured coating excels in transparency, abrasion resistance, adhesive strength and electrical conductivity.
Inventors
- 👤 Hisatake Sato
- 👤 Akinori Suzuki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 11:32
CPC Classifications
C; C09; C09C; C09C1/00; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/34; C08F220/343; C08F222/00; C08F222/10; C08F222/1006; C08F222/103; C09D; C09D4/00; C09D5/00; C09D5/24; H; H01; H01B; H01B1/00; H01B1/20; C01; C01P; C01P2002/00; C01P2002/50; C01P2002/52; C01P2004/00; C01P2004/60; C01P2004/62; C01P2006/00; C01P2006/40
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
195 words
A curable composition comprising: (a) a base compound having in the molecule at least two acryloyl or methacryloyl groups; and (b) an electrically-conductive particulate component selected from the group consisting of tin oxide, indium oxide, antimony-doped tin oxide and stannate-doped indium oxide, said particulate component having a particle size of not more than 0.2 micrometer, and having carried thereon a hydrolyzed silicon compound of the formula R.sub.m.sup.1 R.sub.n.sup.2 Si(OR.sup.3).sub.4-(m+n) where R 1 and R 2 each are a hydrocarbon moiety of 1 to 20 carbon atoms or an organic group containing a halogen atom or an epoxy, acrylonitrile, methacrylonitrile, mercapto or amino group, each of the hydrocarbon moiety and organic group forming a Si--C bond, R 3 is a hydrocarbon moiety of 1 to 6 carbon atoms or an oxygen-containing hydrocarbon moiety, m and n each are 0, 1, or 2, and the sum of m and n is 1 or 2, said particulate component being present in an amount of 40 to 80 percent by weight of the total composition, said silicon compound being present in an amount of 5 to 40 parts by weight per 100 parts by weight of said particulate component.
Claim 2
Dependent Claim
195 words
A curable composition comprising: (a) a base compound having in the molecule at least two acryloyl or methacryloyl groups; and (b) an electrically-conductive particulate component selected from the group consisting of tin oxide, indium oxide, antimony-doped tin oxide and stannate-doped indium oxide, said particulate component having a particle size of not more than 0.2 micrometer, and having carried thereon a hydrolyzed silicon compound of the formula R.sub.m.sup.1 R.sub.n.sup.2 Si(OR.sup.3).sub.4-(m+n) where R 1 and R 2 each are a hydrocarbon moiety of 1 to 20 carbon atoms or an organic group containing a halogen atom or an epoxy, acrylonitrile, methacrylonitrile, mercapto or amino group, each of the hydrocarbon moiety and organic group forming a Si--C bond, R 3 is a hydrocarbon moiety of 1 to 6 carbon atoms or an oxygen-containing hydrocarbon moiety, m and n each are 0, 1, or 2, and the sum of m and n is 1 or 2, said particulate component being present in an amount of 40 to 80 percent by weight of the total composition, said silicon compound being present in an amount of 5 to 40 parts by weight per 100 parts by weight of said particulate component.
Claim 3
Dependent Claim
47 words
The composition of claim 1, wherein said base compound is selected from the group consisting of ethyleneglycol diacrylate, propyleneglycol diacrylate, propylneglycol dimethacrylate, tetraethyleneglycol dimethacrylate, trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, glycerol triacrylate, glycerol trimethacrylate, pentaerythritol triacrylate, pentaerythritol trimethacrylate, tris(2-hydroxyethyl)isocyanurate acrylate, tris(2-hydroxyethyl)isocyanurate methacrylate, polyester acrylate, epoxy acrylate and polyurethane acrylate.
Claim 4
Dependent Claim
32 words
The composition of claim 1, said base compound further including one member selected from the group consisting of 2-ethylhexyl acrylate, 2-hydroxyethyl acrylate and 2-hydroxypropyl arylate in an amount sufficient to depress viscosity.
Claim 5
Dependent Claim
62 words
The composition of claim 1, wherein said silicon compound is selected from the group consisting of methyltrimethoxysilane, methytriethoxysilane, methyltrimethoxyethoxysilane, methyltriacetoxysilane, methyltributoxysilane, ethyltrimethoxysilane, ethyltriethoxysilane, vinyltrimethoxysilane, vinyltriethoxysilane, vinyltriacetoxysilane, vinyltrimethoxysilane, phenyltrimethoxysilane, phenyltriethoxysilane, phenyltriacetoxysilane, gamma-chloropropyltrimethoxysilane, gamma-chloropropyltriethoxysilane, gamma-chloropropyltriacetoxysilane, 3,3,3-trichloropropyltrimethoxysilane, gamma-glycidoxypropyltrimethoxysilane, gamma-glycidoxypropyltriethoxysilane, gamma-(beta-glycidoxyethoxy)propyltrimethoxysilane, beta-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, beta-(3,4-epoxycyclohexyl)ethyltriethoxysilane, gamma-methacryloxypropyltrimethoxysilane, gamma-aminopropyltrimethoxysilane, gamma-aminopropyltriethoxysilane, gamma-mercaptopropyltrimethoxysilane, N-beta-(aminoethyl)-gamma-aminopropyltriethoxysilane, beta-cyanoethyltriethoxysilane, methyldimethoxysilane, phenylmethyldimethoxysilane, dimethyldiethoxysilane, gamma-glycidoxypropylmethyldiethoxysilane, gamma-glycidoxypropylmethyldiethoxysilane, gamma-chloropropylmethyldimethoxssilane, gamma-chloropropylmethyldiethoxysilane, gamma-methacyloxypropylmethyldimethoxysilane, gamma-methacryloxypropylmethyldiethoxysilane, gamma-mercaptopropylmethyldimethoxysilane, gamma-mercaptopropylmethyldiethoxysilane, gamma-aminopropylmethyldimethoxysilane, gamma-aminopropylmethyldiethoxysilane, methylvinyldiethoxysilane and combinations thereof.
Claim 6
Dependent Claim
23 words
The composition of claim 1, further including a photosensitizer in an amount of 0.1 to 10 percent by weight of the total composition.
Claim 7
Dependent Claim
49 words
The composition of claim 5, wherein said photosensitizer is selected from the group consisting of benzyldimethyl ketal, benzyldimethyl ether, benzoinethyl ether, benzoin-1-propyl ether, benzoin, alphamethylbenzoin, 9,10-anthraquinone, 1-chloro-anthraquinone, 2-chloroanthraquinone, 2-ethylanthraquinone, benzophenone, p-chlorobenzophenone, p-dimethylaminobenzophenone, 2-hydroxy-2-methylpropiophenone, 1-(4-isopropylphenone)-2-hydroxy-2 methylpropiophenone, dibenzosuberone, diphenyl disulfide, tetramethyl thiuram disulfide, thioxanthone, methylene blue, eosine, fluorescein and combinations thereof.
Claim 8
Dependent Claim
12 words
The composition of claim 1, wherein said electrically-conductive component is tin oxide.
Claim 9
Dependent Claim
12 words
The composition of claim 1, wherein said electrically-conductive component is indium oxide.
Claim 10
Dependent Claim
13 words
The composition of claim 1, wherein said electrically-conductive component is stannate-doped indium oxide.
Claim 11
Dependent Claim
13 words
The composition of claim 1, wherein said electrically-conductive component is antimony-doped tin oxide.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-03-26 | 1993-09-25 | 1994-03-27 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-03-26 | 1997-09-25 | 1998-03-27 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-03-26 | 2001-09-25 | 2002-03-27 | $7700.00 | Window Closed / Lapsed |