Patent US4910255A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4910255A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable composition

Assignee: Kanegafuchi Chemical Industry Co Ltd
•
Filing: 1988-04-28
•
Granted: 1990-03-20
•
Expires: 2008-04-28
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A curable composition. The composition contain (A) a copolymer that has silicon-containing functional groups capable of crosslinking by forming siloxane bonds and whose molecular chain consists substantially of: (1) an alkyl acrylate ester monomeric unit and/or an alkyl methacrylate ester monomeric unit, the alkyl of each being 1 to 8 carbon atoms; and (2) an alkyl acrylate ester monomeric unit and/or an alkyl methacrylate ester monomeric unit, the alkyl of each being at least 10 carbon atoms; (B) an oxyalkylene polymer having silicon-containing functional groups that are capable of crosslinking by forming siloxane bonds; and (C) at least one compound selected from (i) a hydrolyzable organic silane monomer represented by the formula (I): R.sup.1.sub.4-n SiX.sub.n wherein X is a hydrolyzable group, R 1 is a monovalent organic group having 1 to 18 carbon atoms, n is an integer of 1 to 4, and each R 1 or X can be the same or different when two or more R 1 or X groups are attached, (ii) a partial hydrolysis condensate of the organic silane monomer represented by the formula (I), and (iii) an orthoorganic acid ester represented by the formula (II): R.sup.2 C(OR.sup.3).sub.3 wherein R 2 is hydrogen or methyl, R 3 is a monovalent organic group having 1 to 8 carbon atoms, and the three R 3 groups do not need to be the same.

Inventors

  • 👤 Hiroshi Wakabayashi
  • 👤 Katsuhiko Isayama

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 12:21
CPC Classifications
C; C08; C08K; C08K5/00; C08K5/04; C08K5/06; C08K5/54; C08L; C08L33/00; C08L33/04

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 254 words
A curable composition which comprises: (A) a copolymer having silicon-containing functional groups capable of crosslinking by forming siloxane bonds and whose molecular chain consists substantially of: (1) at least one monomeric unit selected from the group consisting of an alkyl acrylate ester monomeric unit and an alkyl methacrylate ester monomeric unit, the alkyl group of each having 1 to 8 carbon atoms; and (2) at least one monomeric unit selected from the group consisting of an alkyl acrylate ester monomeric unit and an alkyl methacrylate ester monomeric unit, the alkyl group of each having at least 10 carbon atoms; (B) an oxyalkylene polymer having silicon-containing functional groups that are capable of crosslinking by forming siloxane bonds; and (C) at least ne compound selected from the group consisting of: (i) a hydrolyzable organic silane monomer represented by the formula (I) R.sup.1.sub.4-n SiX.sub.n (I) wherein X is a hydrolyzable group, R 1 is a monovalent organic group having 1 to 18 carbon atoms, n is an integer of 1 to 4, and each R 1 or X can be the same or different when two or more R 1 or X groups are attached, (ii) a partial hydrolysis condensate of the organic silane monomer represented by the formula (I), and (iii) an orthoorganic acid ester represented by the formula (II): R.sup.2 C(OR.sup.3).sub.3 (II) wherein R 2 is a hydrogen atom or a methyl group, R 3 is a monovalent organic group having 1 to 8 carbon atoms, and each R 3 is the same or different.
Claim 2
Dependent Claim 254 words
A curable composition which comprises: (A) a copolymer having silicon-containing functional groups capable of crosslinking by forming siloxane bonds and whose molecular chain consists substantially of: (1) at least one monomeric unit selected from the group consisting of an alkyl acrylate ester monomeric unit and an alkyl methacrylate ester monomeric unit, the alkyl group of each having 1 to 8 carbon atoms; and (2) at least one monomeric unit selected from the group consisting of an alkyl acrylate ester monomeric unit and an alkyl methacrylate ester monomeric unit, the alkyl group of each having at least 10 carbon atoms; (B) an oxyalkylene polymer having silicon-containing functional groups that are capable of crosslinking by forming siloxane bonds; and (C) at least ne compound selected from the group consisting of: (i) a hydrolyzable organic silane monomer represented by the formula (I) R.sup.1.sub.4-n SiX.sub.n (I) wherein X is a hydrolyzable group, R 1 is a monovalent organic group having 1 to 18 carbon atoms, n is an integer of 1 to 4, and each R 1 or X can be the same or different when two or more R 1 or X groups are attached, (ii) a partial hydrolysis condensate of the organic silane monomer represented by the formula (I), and (iii) an orthoorganic acid ester represented by the formula (II): R.sup.2 C(OR.sup.3).sub.3 (II) wherein R 2 is a hydrogen atom or a methyl group, R 3 is a monovalent organic group having 1 to 8 carbon atoms, and each R 3 is the same or different.
Claim 3
Dependent Claim 39 words
A curable composition as in claim 1, wherein the monomeric unit (1) of copolymer (A) is represented by formula (III) ##STR21## where R 4 is alkyl of 1 to 8 carbon atoms; and R 5 is hydrogen or methyl.
Claim 4
Dependent Claim 39 words
A curable composition as in claim 1, wherein the monomeric unit (2) of copolymer (A) is represented by formula (IV) ##STR22## where R 5 is hydrogen or methyl; and R 6 is alkyl of at least 10 carbon atoms.
Claim 5
Dependent Claim 27 words
A curable composition as in claim 1, wherein the total amount of the monomeric units (1) and (2) in copolymer (A) is 50 weight % or more.
Claim 6
Dependent Claim 20 words
A curable composition as in claim 1, wherein the weight ratio of the monomeric units (1):(2) is 95:4 to 40:60.
Claim 7
Dependent Claim 21 words
A curable composition as in claim 1, wherein a copolymer (A) has a number average molecular weight of 500 to 100,000.
Claim 8
Dependent Claim 35 words
A curable composition as in claim 1, wherein said oxyalkylene polymer (B) has a repeating unit of formula --R 10 --O--, wherein R 10 is a divalent hydrocarbon group having 1 to 8 carbon atoms.

References Cited (Backward Citations)

EP0108946A2 Cited
US4593068A Cited
US4444974A Cited
US4689369A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-03-19 1993-09-18 1994-03-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-03-19 1997-09-18 1998-03-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-03-19 2001-09-18 2002-03-20 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag