Chromatographic arylcarboxamide polysiloxanes

Claim 1

A compound useful for chromatographic separations of formula ##STR10## wherein; a is an integer from 2 to about 14; b is an integer of 0 or 1; c is an integer of 0 or 1; d is an integer from 1 to about 4; e is an integer from 10 to about 40; f is an integer of 0 or 1; and g is an integer from 3 to about 100; Aryl is phenyl or naphthyl or their nitrogen-containing analogs; A is any alkyl of 1 to 22 carbons, aryl selected from the group consisting of phenyl, naphthyl and biphenyl or their nitrogen containing analogs, and pyridyl and furyl and the lower alkyl, lower alkoxy, lower alkoxycarbonyl and lower alkylamido substituents thereof; lower aralkyl, any alkoxy- or aryloxycarbonyl group (--CO 2 R 1 ) where R 1 is any alkyl of 1 to 22 carbons or phenyl, naphthyl or biphenyl; any mono- or disubstituted carboxamide group [C(O)NR 2 R 3 ] where R 2 is any alkyl of 1 to 22 carbons or phenyl, naphthyl or biphenyl or any alkyl ester of an amino acid unit such as alanine or phenylalanine (the nitrogen atom of the carboxamide group would be the nitrogen atom of the amine group of the amino acid, alkyl ester), any alkyl ester of a di- or tripeptide (the nitrogen atom of the carboxamide group would be one of the nitrogen atoms of the amine groups of the di- or tripeptide), a phenyl or methylene unit substituted with any lower oligoethyleneoxy unit ending with a methoxy or ethoxy group or substitutions of any of the foregoing and R 3 is hydrogen, any alkyl of 1 to 8 carbon atoms or phenyl; B is any alkyl of 1 to 22 carbons, aryl selected from the group consisting of phenyl, naphthyl and biphenyl or their nitrogen containing analogs, and pyridyl and furyl and the lower alkyl, lower alkoxy, lower alkoxycarbonyl and lower alkylamido substituents thereof; lower aralkyl; and * indicates that the carbon is chiral; R 1 and R 7 are selected from the group consisting of lower alkyl, lower alkenyl, lower haloalkyl and phenyl; R 2 , R 3 , R 4 , and R 5 are members selected from the group consisting of hydrogen, lower alkyl, phenyl, phenyl substituted lower alkyl, lower alkyl substituted phenyl, lower alkoxy substituted phenyl and halosubstituted phenyl; R 6 is a member selected from the group consisting of alkyl of 1 to 12 carbon atoms, alkenyl of 2 to 8 carbon atoms, phenyl substituted lower alkyl and lower alkyl substituted phenyl.