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US4906968A Expired / Lapsed US ⏱️ 0.0 years remaining

Percolating cermet thin film thermistor

Assignee: Cornell Research Foundation Inc
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Filing: 1988-10-04
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Granted: 1990-03-06
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Expires: 2008-10-04
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Abstract

Abstract A cermet thin film resistor having small particles of a refractory metal embedded in a ceramic insulator at compositions near the percolation transition. The cermets are produced by co-deposition in a dual-electron beam evaporator. The refractory metal is typically Mo or Pt. The insulator is typically a Al 2 O 3 , although other insulators, for example SiO 2 may be used. Deposition occurs onto a suitable substrate such as a sapphire under an oxygen environment, typically 10 -5 Torr O 2 with the stage heated in the range of typically 400° C. Such is done to increase the size of the metallic regions. The microstructure is 10-50 Å embedded metal in the ceramic. The resulting films are in the range of 1500 Å thick which provides a film having a typical resistivity of 400 mΩ - cm which may then be patterned using lithography techniques to form two or four terminal resistors.

Inventors

  • 👤 Neil Gershenfeld
  • 👤 Watt W. Webb
  • 👤 Jeffrey E. VanCleve
  • 👤 Joseph V. Mantese
  • 👤 Eric T. Swartz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 12:50
CPC Classifications
H; H01; H01C; H01C7/00; H01C7/04; H01C7/041

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 45 words
A thermometry element comprising: an oxide substrate, and a thin cermet film deposited on said substrate and having the formula M-C where M is a refractory metal and C is a ceramic insulator processed just below the percolation transition, said cermet having 45-50% metal volume.
Claim 2
Dependent Claim 45 words
A thermometry element comprising: an oxide substrate, and a thin cermet film deposited on said substrate and having the formula M-C where M is a refractory metal and C is a ceramic insulator processed just below the percolation transition, said cermet having 45-50% metal volume.
Claim 3
Dependent Claim 10 words
The element of claim 1, wherein the metal is Pt.
Claim 4
Dependent Claim 10 words
The element of claim 1, wherein the metal is Mo.
Claim 5
Dependent Claim 11 words
The element of claim 1, wherein the ceramic insulator is sapphire.
Claim 6
Dependent Claim 16 words
The element of claim 1, wherein said thin cermet film has a thickness approximately 1,500 Å.
Claim 7
Dependent Claim 24 words
The element of claim 1, wherein said cermet comprises a metallic particle size in the range of 10-50 Å embedded in said ceramic insulator.
Claim 8
Dependent Claim 20 words
The element of claim 1, wherein said thin film is patterned and further comprises at least a pair of terminals.
Claim 9
Dependent Claim 14 words
The element of claim 1, wherein said oxide substrate is a single crystal sapphire.
Claim 10
Dependent Claim 12 words
The element of claim 1, wherein said substrate is SiO 2 .
Claim 11
Dependent Claim 17 words
The element of claim 1, wherein said element has a temperature sensitive range of 50 mk-300 mk.
Claim 12
Dependent Claim 37 words
A temperature sensitive resistor comprising; an oxide substrate, and a thin film cermet made from a refractory metal-ceramic mixture deposited on said substrate and processed to just below the percolation transition, said cermet having 45-50 metal volume.
Claim 13
Dependent Claim 37 words
A temperature sensitive resistor comprising; an oxide substrate, and a thin film cermet made from a refractory metal-ceramic mixture deposited on said substrate and processed to just below the percolation transition, said cermet having 45-50 metal volume.
Claim 14
Dependent Claim 10 words
The element of claim 11, wherein the metal is Pt.
Claim 15
Dependent Claim 10 words
The element of claim 11, wherein the metal is Mo.
Claim 16
Dependent Claim 10 words
The element of claim 11, wherein the ceramic is sapphire.
Claim 17
Dependent Claim 16 words
The element of claim 11, wherein said thin cermet film has a thickness approximately 1,500 Å.
Claim 18
Dependent Claim 22 words
The element of claim 11, wherein said cermet having a particle size in the range of 10-50 Åmetal embedded in said ceramic.
Claim 19
Dependent Claim 20 words
The element of claim 11, wherein said thin film is patterned and further comprises at least a pair of terminals.
Claim 20
Dependent Claim 14 words
The element of claim 11, wherein said oxide substrate is a single crystal sapphire.
Claim 21
Dependent Claim 12 words
The element of claim 11, wherein said substrate is SiO 2 .
Claim 22
Dependent Claim 17 words
The element of claim 11, wherein said element has a temperature sensitive range of 50 mk-300 mk.

References Cited (Backward Citations)

US4104421A Cited
US4183746A Cited
US4100524A Cited
US4104607A Cited
US4280114A Cited
US4398169A Cited
US4454495A Cited
US4609903A Cited
US4526785A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-03-05 1993-09-04 1994-03-06 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-03-05 1997-09-04 1998-03-06 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-03-05 2001-09-04 2002-03-06 $7700.00 Window Closed / Lapsed

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