Patent US4904752A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4904752A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid crystal copolyester having blocked molecular chain terminal

Assignee: Polyplastics Co Ltd
•
Filing: 1987-11-13
•
Granted: 1990-02-27
•
Expires: 2007-11-13
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A liquid crystal copolyester having a blocked molecular chain terminal comprising a copolyester which exhibits anisotropy in a molten state and has a functional group located at the terminal of its molecular chain and is blocked with a low-molecular compound having at least one aromatic ring and a molecular weight of 350 or less.

Inventors

  • 👤 Toshio Kanoe
  • 👤 Kenji Hijikata

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 22:06
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/12; C08G63/40; C08G63/68; C08G63/688; C08G63/60; C08G63/605; C08G63/685; C09; C09K; C09K19/00; C09K19/04; C09K19/38; C09K19/3804; C09K19/3809

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 188 words
A liquid crystal copolyester having a blocked molecular chain terminal, comprising a copolyester which exhibits anisotropy in a molten state and has a functional group located at the terminal of the molecular chain thereof and is blocked with a low-molecular compound having at least one aromatic ring and a molecular weight of 350 or less, wherein said low-molecular compound used for blocking said molecular chain terminal is at least one member selected from the compounds represented by following formulae (A) to (I): ##STR22## wherein R 1 and R 2 are each a substituent selected from alkyl having 1 to 10 carbon atoms, --Cl, --Br, --OCH 3 , --CN, --NO 2 , --NH 2 , vinyl, ethynyl, acrylate, phenyl, benzyl, alkylurea, alkyl ester, and maleimino; Y is a group selected from alkylene having 1 to 4 carbon atoms, alkylidene, --O--, --S--, --SO--, --SO 2 --, and --CO--; n is an integer of 1 to 2; and x is a functional group selected from aldehyde, hydroxyl, carboxyl, amino, imino, glycidyl ether, glycidyl ester, methyl, isocyanato, acetoxy, carboxyalkyl ester (wherein the alkyl has 1 to 4 carbon atoms) and carboxyphenyl ester.
Claim 2
Dependent Claim 188 words
A liquid crystal copolyester having a blocked molecular chain terminal, comprising a copolyester which exhibits anisotropy in a molten state and has a functional group located at the terminal of the molecular chain thereof and is blocked with a low-molecular compound having at least one aromatic ring and a molecular weight of 350 or less, wherein said low-molecular compound used for blocking said molecular chain terminal is at least one member selected from the compounds represented by following formulae (A) to (I): ##STR22## wherein R 1 and R 2 are each a substituent selected from alkyl having 1 to 10 carbon atoms, --Cl, --Br, --OCH 3 , --CN, --NO 2 , --NH 2 , vinyl, ethynyl, acrylate, phenyl, benzyl, alkylurea, alkyl ester, and maleimino; Y is a group selected from alkylene having 1 to 4 carbon atoms, alkylidene, --O--, --S--, --SO--, --SO 2 --, and --CO--; n is an integer of 1 to 2; and x is a functional group selected from aldehyde, hydroxyl, carboxyl, amino, imino, glycidyl ether, glycidyl ester, methyl, isocyanato, acetoxy, carboxyalkyl ester (wherein the alkyl has 1 to 4 carbon atoms) and carboxyphenyl ester.
Claim 3
Dependent Claim 39 words
A liquid crystal copolyester according to claim 1, wherein the functional group X of said low-molecular compound used for blocking said molecular chain terminal is a reactive group selected from among hydroxyl, carboxyl, amino and esters thereof, and glycidyl.
Claim 4
Dependent Claim 44 words
A liquid crystal copolyester according to claim 1 or 2, wherein said copolyester which exhibits anisotropy in a molten state contains in part of the molecular chain thereof an aromatic polyester or an aromatic polyesteramide which does not exhibit anisotropy, or a mixture thereof.
Claim 5
Dependent Claim 21 words
A liquid crystal copolyester according to claim 3, wherein said aromatic polyester which does not exhibit anisotropy is a polyalkylene terephthalate.
Claim 6
Dependent Claim 21 words
A liquid crystal copolyester according to claim 4, wherein the alkylene of said polyalkylene terephthalate has 4 or less carbon atoms.
Claim 7
Dependent Claim 85 words
A liquid crystal copolyester according to claim 1, wherein said copolyester which exhibits anisotropy in a molten state is comprised of at least one component selected from ○1 naphthalene compounds, ○2 phenyl compounds, ○3 4,4'-biphenyl compounds, and ○4 compounds represented by the following general formula: ##STR23## wherein Z is alkylene (C 1 ˜C 4 ), alkylidene (C 1 ˜C 4 ), --O--, --S--, --SO--, --SO 2 --, and --CO--, and R and R' are each a reactive group selected from hydroxyl, carboxyl or esters thereof.
Claim 8
Dependent Claim 25 words
A liquid crystal copolyester according to claim 6, wherein said component is at least one compound selected from 2,6-dicarboxynaphthalene, 2,6-dihydroxynaphthalene, 2-hydroxy-6-naphthoic acid, and esters thereof.
Claim 9
Dependent Claim 32 words
A liquid crystal copolyester according to claim 6, wherein said component is at least one compound selected from p-hydroxybenzoic acid, terephthalic acid, hydroquinone, p-aminophenol, and substituted derivatives thereof and ester compounds thereof.
Claim 10
Dependent Claim 24 words
A liquid crystal copolyester according to claim 6, wherein said component is at least one compound selected from 4,4'-dihydroxybiphenyl, 4,4'-dicarboxybiphenyl, 4-hydroxy-4'-carboxy-biphenyl, and esters thereof.
Claim 11
Dependent Claim 26 words
A liquid crystal copolyester according to claim 1, wherein said copolyester which exhibits anisotropy in a molten state has a molecular weight of 30,000 or less.

References Cited (Backward Citations)

JPS4817559B1 Cited
US3657191A Cited
US4184996A Cited
US4728698A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-02-26 1993-08-28 1994-02-27 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-02-26 1997-08-28 1998-02-27 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-02-26 2001-08-28 2002-02-27 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag