Optical information recording medium

Claim 2

An optical information recording medium for carrying out recording and reproduction with laser beams which comprises a support having carried thereon at least one methine dye which comprises an azulene nucleus, at least one of the two carbon atoms at the 1 and 3 positions of which is replaced by a chalcogen atom or a nitrogen atom, and further whose 7-membered ring part is substituted with a methine bond having at the terminal an auxochrome which forms a conjugated resonance chromophore together with a 10 π electron system of the nucleus.

Claim 3

The optical information recording medium of claim 1, wherein when both carbon atoms at the 1- and 3-positions of the azulene nucleus are replaced by a chalcogen atom or a nitrogen atom, at least one of the replacing atoms is a nitrogen atom.

Claim 4

The optical information recording medium of claim 1, wherein the methine dye is represented by the following general formula (I): ##STR109## wherein E represents an auxochrome; L represents a methine bond; V 1 , V 2 , V 3 , V 4 and V 5 independently represent hydrogen atoms, halogen atoms, substituted or unsubstituted alkyl groups, acyl groups, acyloxy groups, substituted or unsubstituted alkoxycarbonyl groups, substituted or unsubstituted carbamoyl groups, substituted or unsubstituted sulfamoyl groups, carboxyl groups, cyano groups, hydroxyl groups, amino groups, acylamino groups, substituted or unsubstituted alkoxy groups, alkylthio groups, alkylsulfonyl groups, sulfonic acid groups, or aryl groups, or alternatively two of V 1 to V 5 linking to adjacent carbon atoms may combine to form a condensed ring; Y represents ##STR110## (wherein V has the same meaning as V 1 , V 2 , V 3 , V 4 and V 5 ) or a nitrogen atom, Z represents ##STR111## (wherein V has the same meaning as V 1 , V 2 , V 3 , V 4 and V 5 ), a chalcogen atom or a nitrogen atom, provided that Y and Z do not represent carbon atoms at the same time; M represents a counter ion for charge balance, m is a number of 0 or more necessary for the balance of charge; and bonding position of a methine bond L is representatively expressed as the 6-position in the formula (I), but may also be expressed as the 4-, 5-, 7- or 8-position.

Claim 5

The optical information recording medium of claim 3, wherein Z represents ##STR112## and R 1 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a heterocyclic ring group.

Claim 6

The optical information recording medium of claim 4, wherein R 1 is an unsubstituted alkyl group having 18 or less carbon atoms, or a sulfoalkyl group.

Claim 7

The optical information recording medium of claim 3, wherein the methine dye is represented by one of the following formula (II) to (IX): ##STR113## wherein V 1 to V 5 , Y, Z, M and m have the same meanings as those in the general formula (I); position of the methine bond may be any of the 4-, 5-, 6-, 7- and 8-positions, as is in the general formula (I); Q 1 represents an atomic group necessary for forming a 5- or 6-membered nitrogen-containing ring; L 1 , L 2 , L 3 , L 4 and L 5 each represent methine groups which may optionally be substituted; R 2 represents a substituted or unsubstituted alkyl group; l represents an integer of 0 to 3; and n 1 represents 0 or 1; ##STR114## wherein V 1 to V 5 , Y, Z, M and m have the same meanings as those in the general formula (I); position of the methine bond may be any of the 4-, 5-, 6-, 7- and 8-positions, as is in the general formula (I); Q 2 represents an atomic group necessary for forming a 5- or 6-membered nitrogen-containing ring; L 6 , L 7 , L 8 , L 9 and L 10 have the same meanings with L 1 , L 2 , L 3 , L 4 and L 5 ; R 3 represents a substituted or unsubstituted alkyl group; l 2 represents an integer of 0 to 3; and n 2 represents 0 or 1; ##STR115## wherein V 1 to V 5 , Y, Z, M and m have the same meanings as those in the general formula (I); Y' and Z' have the same meanings with Y an Z, respectively; position of the methine bond may be any of the 4-, 5-, 6-, 7- and 8-positions; V 1 ' to V 5 ' have the same meanings with V 1 to V 5 , respectively; L 11 , L 12 and L 13 have the same meanings with L 1 , L 2 , L 3 , L 4 and L 5 ; and l 3 represents an integer of 0 to 3; ##STR116## wherein V 1 to V 5 , Y, Z, M and m have the same meanings as those in the general formula (I); position of the methine bond may be any of the 4-, 5-, 6-, 7- and 8-positions, as is in the general formula (I); D 1 and D 1 ' each represent atomic groups necessary for forming an acidic nucleus, and may be non-cyclic or cyclic; L 14 , L 15 , L 16 and L 17 have the same meanings with L 1 , L 2 , L 3 , L 4 and L 5 ; l 4 represents an integer of 0 to 3; and n 3 represents 0 or 1; ##STR117## wherein V 1 to V 5 , Y, Z, M and m have the same meanings as those in the general formula (I); position of the methine bond may be any of the 4-, 5-, 6-, 7- and 8-positions, as is in the general formula (I); R 4 and R 5 represent substituents known in general tertiary amines, and R 4 and R 5 may combine to form a ring; L 18 and L 19 have the same meanings with L 1 , L 2 , L 3 , L 4 and L 5 ; and l represents an integer of 0 to 3; ##STR118## wherein E and E' each is E 1 or E 2 , provided that at least one of E and E' is E 1 ; V 1 to V 5 , Y, Z, M and m have the same meanings as those in the general formula (I); positions of the methine bond in E 1 may be any of the 4-, 5-, 6-, 7- and 8-positions, as is in the general formula (2); W 1 represents an atomic group necessary for forming a 5- or 6-membered heterocyclic ring; R 6 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group or a heterocyclic group; Q 3 and R 7 have the same meanings with Q 1 and R 2 in the general formula (II), respectively; L 20 , L 21 , L 22 , L 23 , L 24 , L 25 and L 26 have the same meanings with L 1 , L 2 , L 13 , L 14 and L 5 ; l 6 and l 7 are integers of 0 to 3; and n 4 is 0 or 1; ##STR119## wherein V 1 to V 5 , Y, Z, M and m have the same meanings as those in the general formula (I); position of the methine bond may be any of the 4-, 5-, 6-, 7- and 8-positions, as is in the general formula (I): W 2 has the same meaning with W 1 ; R 8 has the same meaning with R 6 ; D 2 and D 2 ' have the same meanings with D 1 and D 1 ' in the general formula (V), respectively; L 27 , L 28 , L 29 , L 30 , L 31 and L 32 have the same meanings with L 1 , L 2 , L 3 , L 4 and L 5 ; l 8 and l 9 are integers of 0 to 3; and n 5 represents 0 or 1; ##STR120## ##STR121## wherein V 1 to V 5 , Y, Z, M and m have the same meanings as those in the general formula (I); position of the methine bond may be any of the 4-, 5-, 6- and 8-positions, as is in the general formula (I); L 33 and L 34 have the same meanings with L 1 , L 2 , L 3 , L 4 and L 5 ; Ar represents an aromatic group; and l 10 represents an integer of 0 to 3.

Claim 8

The optical information recording medium of claim 6, wherein V 1 , V 2 , V 3 , V 4 , V 5 , V 1 ', V 2 ', V 3 ', V 4 ' and V 5 ' independently represents hydrogen atoms, halogen atoms selected from the group consisting of chlorine atoms, fluorine atoms, and bromine atoms, unsubstituted alkyl groups having 10 or less carbon atoms, substituted alkyl groups having 18 or less carbon atoms, acyl groups having 10 or less carbon atoms, acyloxy groups having 10 or less carbon atoms, substituted or unsubstituted alkoxycarbonyl groups, substituted or unsubstituted carbamoyl groups, substituted or unsubstituted sulfamoyl groups, carboxyl groups, cyano groups, hydroxyl groups, amino groups, acylamino groups having 8 or less carbon atoms, substituted or unsubstituted alkoxy groups having 10 or less carbon atoms, alkylthio groups, alkylsufonyl groups, sulfonic acid groups or aryl groups.

Claim 9

The optical information recording medium of claim 6, wherein Q 1 or Q 2 comprises a thiazole nucleus, a benzothiazole nucleus, a naphthothiazole nucleus, a thiazoline nucleus, an oxazole nucleus, an oxazoline nucleus, a selenazole nucleus, a selenazoline nucleus, a tellurazole nucleus, a tellurazoline nucleus, a 3,3-dialkylindolenine nucleus, an imidazole nucleus, a pyridine nucleus, a quinoline nucleus, an imidazo(4,5-b)-quinoxaline nucleus, an oxadiazole nucleus, a thiadiazole nucleus, a tetrazole nucleus and a pyrimidine nucleus.

Claim 10

The optical information recording medium of claim 6, wherein R 2 , R 3 and R 7 are selected from the group consisting of an unsubstituted alkyl group having 18 or less carbon atoms and a substituted alkyl group.

Claim 11

The optical information recording medium of claim 6, wherein D 1 and D 1 ' or D 2 and D 2 ' combine to form a nucleus comprising 1,3-dialkylbarbituric acid, 1,3-dialkyl-2-thiobarbituric acid or 3-alkylrhodanine.

Claim 12

The optical information recording medium of claim 6, wherein R 4 and R 5 , which may be the same or different, comprise unsubstituted alkyl groups each having 18 or less carbon atoms, substituted alkyl groups, cyano groups, alkoxy groups, aryloxy groups, alkoxycarbonyl groups, or R 4 and R 5 may combine together to form a heterocyclic ring with the proviso that the heterocyclic ring is not an aromatic heterocyclic ring.

Claim 13

The optical information recording medium of claim 1, which comprises a recording layer as the dye layer and a subbing layer provided on the support, a protective layer provided on the recording layer, and/or a reflecting layer provided on the support or on the recording layer.

Claim 14

The optical information recording medium of claim 1, wherein a single oxygen quencher is further carried thereon.

Claim 15

The optical information recording medium of claim 13, wherein the quencher is contained in the recording layer.

Claim 16

The optical information recording medium of claim 13, wherein the quencher is used in an amount of 0.05 to 12 moles per 1 mole of the methine dye(s).

Claim 17

The optical information recording medium of claim 1, wherein the film thickness of the recording layer is 0.01 to 2 μm.

Claim 18

The optical information recording medium of claim 1, wherein the chalcogen atom is selected from the group consisting of oxygen, sulfur, selenium and tellurium atoms.

Claim 19

The optical information recording medium of claim 1, further comprising a quencher represented by formulae (XXI) and (XXII): ##STR122## wherein (Cat 1 ) and (Cat 2 ) each represent a cation necessary for making each compound neutral, M 1 and M 2 each represent nickel, copper, cobalt, palladium or platinum, and n represents 1 or 2.

Claim 20

The optical information recording medium of claim 18, wherein the cations (Cat 1 ) and (Cat 2 ) are represented by formulae (XXIII-a), (XXIII-b), (XXIII-c), (XXIII-d) or (XXIII-e): ##STR123## wherein R 11 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 , R 18 , R 19 , R 20 , R 21 and R 22 each represent a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, or a substituted or unsubstituted aryl group having 6 to 14 carbon atoms, and Z 1 and Z 2 each represent a nonmetal atomic group which forms a 5-membered or a 6-membered ring together with a nitrogen atom or a phosphorus atom in each formula.

Claim 21

The optical information recording medium of claim 18, wherein the quencher of formula (XXI) is selected from the group consisting of (XXI-1), (XXI-2), (XXI-3) and (XXI-4): ##STR124##