US4898896A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Transparent copolyamide from oligomeric amide and cycloaliphatic diamine and process for the production thereof
Assignee: Arkema France SA
•
Filing: 1988-09-26
•
Granted: 1990-02-06
•
Expires: 2008-09-26
Abstract
Abstract A transparent polyamide containing terephthalic acid radicals or radicals of the mixture of terephthalic and isophthalic acids and a cycloaliphatic diamine radical and having the chain formations: ##STR1## in which: y 1 +y 2 is between 10 and 200 with y 1 /(y 1 +y 2 )>0.5; m, p, m' and p' are whole numbers equal to or greater than zero, such that: ##EQU1## is between 0.5 and 10, taken statistically over the marcomolecule; Z and Z' are the same or different and are either a polymethylene segment --(CH 2 )-- n where n is a whole number equal to or greater than 6 or a sequence containing an amide resulting from condensation of an aliphatic diamine containing at least 6 carbon atoms between the amine functions and an aliphatic dicarboxylic acid containing at least 4 carbon atoms between the acid functions; A and B are the same or different and represent hydrogen or a methyl, ethyl, or isopropyl radical; X and Y are the same or different and represent hydrogen or a methyl radical; and q is a whole number between 0 to 6. The process of making such polyamide comprises a first stage wherein terephthalic acid or a mixture of terephthalic and isophthalic acids containing more than 50 mol. % terephthalic acid are reacted with a lactam followed by a second stage where the oligomeric diacid obtained is reacted with a cycloaliphatic diamine.
Inventors
- 👤 Philippe Maj
- 👤 Philippe Blondel
- 👤 Daniel Cuzin
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 16:21
CPC Classifications
C; C08; C08G; C08G69/00; C08G69/02; C08G69/36; C08G69/26
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
185 words
A transparent polyamide containing terephthalic acid radicals or radicals of the mixture of terephthalic and isophthalic acids and a cycloaliphatic diamine radical and having the chain formations: ##STR4## in which: y 1 +y 2 is between 10 and 200 with y 1 /(y 1 +y 2 )>0.5; m, p, m' and p' are whole numbers equal to or greater than zero, such that: ##EQU3## is between 0.5 and 10, taken statistically over the macromolecule; Z and Z' are the same or different and are either a polymethylene segment --(CH 2 )-- n where n is a whole number equal to or greater than 6 or a sequence containing an amide resulting from condensation of an aliphatic diamine containing at least 6 carbon atoms between the amine functions and an aliphatic dicarboxylic acid containing at least 4 carbon atoms between the acid functions; A and B are the same or different and represent hydrogen or a methyl, ethyl, or isopropyl radical; X and Y are the same or different and represent hydrogen or a methyl radical; and q is a whole number between 0 and 6.
Claim 2
Dependent Claim
185 words
A transparent polyamide containing terephthalic acid radicals or radicals of the mixture of terephthalic and isophthalic acids and a cycloaliphatic diamine radical and having the chain formations: ##STR4## in which: y 1 +y 2 is between 10 and 200 with y 1 /(y 1 +y 2 )>0.5; m, p, m' and p' are whole numbers equal to or greater than zero, such that: ##EQU3## is between 0.5 and 10, taken statistically over the macromolecule; Z and Z' are the same or different and are either a polymethylene segment --(CH 2 )-- n where n is a whole number equal to or greater than 6 or a sequence containing an amide resulting from condensation of an aliphatic diamine containing at least 6 carbon atoms between the amine functions and an aliphatic dicarboxylic acid containing at least 4 carbon atoms between the acid functions; A and B are the same or different and represent hydrogen or a methyl, ethyl, or isopropyl radical; X and Y are the same or different and represent hydrogen or a methyl radical; and q is a whole number between 0 and 6.
Claim 3
Dependent Claim
36 words
The polyamide of claim 1, wherein the ratio between the terephthalic acid radical or the radicals of the mixture of terephthalic and isophthalic acids and the residue of the cycloaliphatic diamine is between 1:0.90 and 1:1.10.
Claim 4
Dependent Claim
21 words
The polyamide of claim 1 or 2, wherein the aliphatic segments represent between 20 and 60 wt. % of the macromolecule.
Claim 5
Dependent Claim
150 words
A process for producing a transparent polyamide by reacting, with a cycloaliphatic diamine, the oligomeric amide product of the reaction between terephthalic acid and a lactam or a mixture of terephthalic and isophthalic acids and a lactam, or an omega-amino acid or a mixture of one or more diamines and one or more dicarboxylic acids, wherein: (a) in a first stage, terephthalic acid or a mixture of terephthalic and isophthalic acids containing more than 50 mol. % terephthalic acid is reacted with a lactam having at least 7 carbon atoms in its molecule, or an omega-amino acid, or the equimolecular combination of one or more diamines having at least 6 carbon atoms between the amine functions and with one or more dicarboxylic acids having at least 4 carbon atoms between the carboxylic acid functions; and (b) in a second stage, the resulting diacid oligomer is reacted with the cycloaliphatic diamine.
Claim 6
Dependent Claim
150 words
A process for producing a transparent polyamide by reacting, with a cycloaliphatic diamine, the oligomeric amide product of the reaction between terephthalic acid and a lactam or a mixture of terephthalic and isophthalic acids and a lactam, or an omega-amino acid or a mixture of one or more diamines and one or more dicarboxylic acids, wherein: (a) in a first stage, terephthalic acid or a mixture of terephthalic and isophthalic acids containing more than 50 mol. % terephthalic acid is reacted with a lactam having at least 7 carbon atoms in its molecule, or an omega-amino acid, or the equimolecular combination of one or more diamines having at least 6 carbon atoms between the amine functions and with one or more dicarboxylic acids having at least 4 carbon atoms between the carboxylic acid functions; and (b) in a second stage, the resulting diacid oligomer is reacted with the cycloaliphatic diamine.
Claim 7
Dependent Claim
41 words
The process of claim 4, wherein in the first stage, the quantity of lactam, amino acid or mixture of diamine and diacid reacted is between 0.5 and 10 moles per mole of terephthalic acid or mixture of terephthalic and isophthalic acids.
Claim 8
Dependent Claim
60 words
The process of claim 4 or 5, wherein the cycloaliphatic diamine has the formula: ##STR5## in which: A and B are the same or different and represent hydrogen or a methyl, ethyl, or isopropyl radical; X and Y are the same or different and represent hydrogen or a methyl radical; and q is a whole number between 0 and 6.
Claim 9
Dependent Claim
28 words
The process of claim 4 or 5, wherein the molar ratio between the diacid oligomer and cycloaliphatic diamine used in the second stage is between 1:0.90 and 1:1.10.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-02-05 | 1993-08-07 | 1994-02-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-02-05 | 1997-08-07 | 1998-02-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-02-05 | 2001-08-07 | 2002-02-06 | $7700.00 | Window Closed / Lapsed |