US4398012A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Transparent copolyamide from caprolactam, cyclic diamine and cyclic dicarboxylic acid
Assignee: Honeywell International Inc
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Filing: 1982-01-19
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Granted: 1983-08-09
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Expires: 2002-01-19
Abstract
Abstract This invention is a transparent alcohol resistant, hot water resistant, thermoplastically formable copolymer of (A) 80.4 to 88.8 weight percent epsilon-caprolactam and the remaining (B) 11.2 to 19.6 weight percent of substantially equimolar portions of a moiety derived from (1) a diamine or diisocyanate and (2) a diacid or (c) 11.2 to 19.6 weight percent para amino benzoic acid.
Inventors
- 👤 Robert G. Merrill
- 👤 Robert A. Lofquist
- 👤 Gene C. Weedon
- 👤 John C. Haylock
- 👤 Ian C. Twilley
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 03:21
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/60; C08G18/603; C08G18/30; C08G18/38; C08G18/3819; C08G18/3821; C08G69/00; C08G69/02; C08G69/36
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
200 words
A transparent, alcohol resistant, hot water resistant, thermoplastically formable copolymer of (A) 80.4 to 88.8 weight percent epsilon-caprolactam and the remaining (B) 11.2 to 19.6 weight percent of substantially equimolar portions of a moiety derived from a (1) diamine or diisocyanate selected from the group consisting of ##STR4## and mixtures thereof, and a diacid selected from the group consisting of ##STR5## and mixtures thereof, wherein R 1 is independently selected from the group consisting of --H, --CH 3 , CH 2 CH 3 , ##STR6## and --CH 2 CH 2 CH 3 , R 2 is independently selected from the group consisting of --H, --CH 3 and --CH 2 CH 3 , R 3 is independently selected from the group consisting of --CH 2 -- and --CH 2 CH 2 --, and R 4 is independently selected from the group consisting of --CH 2 --, --CH 2 CH 2 --, --CH 2 CH 2 CH 2 -- and ##STR7## or (C) 11.2 to 19.6 weight percent of ##STR8## wherein said copolymer is thermoformable at a temperature greater than the glass transition temperature of the copolymer and withstands exposure to an alcohol for extended periods without becoming translucent, dissolving or flowing.
Claim 2
Dependent Claim
200 words
A transparent, alcohol resistant, hot water resistant, thermoplastically formable copolymer of (A) 80.4 to 88.8 weight percent epsilon-caprolactam and the remaining (B) 11.2 to 19.6 weight percent of substantially equimolar portions of a moiety derived from a (1) diamine or diisocyanate selected from the group consisting of ##STR4## and mixtures thereof, and a diacid selected from the group consisting of ##STR5## and mixtures thereof, wherein R 1 is independently selected from the group consisting of --H, --CH 3 , CH 2 CH 3 , ##STR6## and --CH 2 CH 2 CH 3 , R 2 is independently selected from the group consisting of --H, --CH 3 and --CH 2 CH 3 , R 3 is independently selected from the group consisting of --CH 2 -- and --CH 2 CH 2 --, and R 4 is independently selected from the group consisting of --CH 2 --, --CH 2 CH 2 --, --CH 2 CH 2 CH 2 -- and ##STR7## or (C) 11.2 to 19.6 weight percent of ##STR8## wherein said copolymer is thermoformable at a temperature greater than the glass transition temperature of the copolymer and withstands exposure to an alcohol for extended periods without becoming translucent, dissolving or flowing.
Claim 3
Dependent Claim
12 words
The copolymer of claim 1 wherein the copolymer withstands a lower alcohol.
Claim 4
Dependent Claim
10 words
The copolymer of claim 2 wherein the alcohol is ethanol.
Claim 5
Dependent Claim
10 words
The copolymer of claim 2 wherein the alcohol is methanol.
Claim 6
Dependent Claim
10 words
The copolymer of claim 2 wherein the alcohol is isopropanol.
Claim 7
Dependent Claim
17 words
The copolymer of claim 1 wherein the copolymer withstands a mixture of hydrocarbons and a lower alcohol.
Claim 8
Dependent Claim
26 words
The copolymer of claim 1 wherein the copolymer withstands a mixture of gasoline, 80-99 percent by weight and 1 to 20 percent by weight of ethanol.
Claim 9
Dependent Claim
15 words
The copolymer of claim 6 wherein (B)(1) is bis(4-aminocyclohexyl) methane and (B)(2) is terephthalic acid.
Claim 10
Dependent Claim
16 words
The copolymer of claim 1 wherein (B)(1) is bis(4-aminocyclohexyl) methane and (B) (2) is terephthalic acid.
Claim 11
Dependent Claim
15 words
The copolymer of claim 1 wherein (B)(1) is 1,3-cyclohexane bis(methylamine) and (B)(2) is terephthalic acid.
Claim 12
Dependent Claim
15 words
The copolymer of claim 1 wherein (B)(1) is 1,4-cyclohexane bis(methylamine) and (B)(2) is terephthalic acid.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1986-08-08 | 1987-02-07 | 1987-08-09 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1990-08-08 | 1991-02-07 | 1991-08-09 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1994-08-08 | 1995-02-07 | 1995-08-09 | $7700.00 | Window Closed / Lapsed |