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US4398012A Expired / Lapsed US ⏱️ 0.0 years remaining

Transparent copolyamide from caprolactam, cyclic diamine and cyclic dicarboxylic acid

Assignee: Honeywell International Inc
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Filing: 1982-01-19
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Granted: 1983-08-09
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Expires: 2002-01-19
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Abstract

Abstract This invention is a transparent alcohol resistant, hot water resistant, thermoplastically formable copolymer of (A) 80.4 to 88.8 weight percent epsilon-caprolactam and the remaining (B) 11.2 to 19.6 weight percent of substantially equimolar portions of a moiety derived from (1) a diamine or diisocyanate and (2) a diacid or (c) 11.2 to 19.6 weight percent para amino benzoic acid.

Inventors

  • 👤 Robert G. Merrill
  • 👤 Robert A. Lofquist
  • 👤 Gene C. Weedon
  • 👤 John C. Haylock
  • 👤 Ian C. Twilley

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 03:21
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/60; C08G18/603; C08G18/30; C08G18/38; C08G18/3819; C08G18/3821; C08G69/00; C08G69/02; C08G69/36

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 200 words
A transparent, alcohol resistant, hot water resistant, thermoplastically formable copolymer of (A) 80.4 to 88.8 weight percent epsilon-caprolactam and the remaining (B) 11.2 to 19.6 weight percent of substantially equimolar portions of a moiety derived from a (1) diamine or diisocyanate selected from the group consisting of ##STR4## and mixtures thereof, and a diacid selected from the group consisting of ##STR5## and mixtures thereof, wherein R 1 is independently selected from the group consisting of --H, --CH 3 , CH 2 CH 3 , ##STR6## and --CH 2 CH 2 CH 3 , R 2 is independently selected from the group consisting of --H, --CH 3 and --CH 2 CH 3 , R 3 is independently selected from the group consisting of --CH 2 -- and --CH 2 CH 2 --, and R 4 is independently selected from the group consisting of --CH 2 --, --CH 2 CH 2 --, --CH 2 CH 2 CH 2 -- and ##STR7## or (C) 11.2 to 19.6 weight percent of ##STR8## wherein said copolymer is thermoformable at a temperature greater than the glass transition temperature of the copolymer and withstands exposure to an alcohol for extended periods without becoming translucent, dissolving or flowing.
Claim 2
Dependent Claim 200 words
A transparent, alcohol resistant, hot water resistant, thermoplastically formable copolymer of (A) 80.4 to 88.8 weight percent epsilon-caprolactam and the remaining (B) 11.2 to 19.6 weight percent of substantially equimolar portions of a moiety derived from a (1) diamine or diisocyanate selected from the group consisting of ##STR4## and mixtures thereof, and a diacid selected from the group consisting of ##STR5## and mixtures thereof, wherein R 1 is independently selected from the group consisting of --H, --CH 3 , CH 2 CH 3 , ##STR6## and --CH 2 CH 2 CH 3 , R 2 is independently selected from the group consisting of --H, --CH 3 and --CH 2 CH 3 , R 3 is independently selected from the group consisting of --CH 2 -- and --CH 2 CH 2 --, and R 4 is independently selected from the group consisting of --CH 2 --, --CH 2 CH 2 --, --CH 2 CH 2 CH 2 -- and ##STR7## or (C) 11.2 to 19.6 weight percent of ##STR8## wherein said copolymer is thermoformable at a temperature greater than the glass transition temperature of the copolymer and withstands exposure to an alcohol for extended periods without becoming translucent, dissolving or flowing.
Claim 3
Dependent Claim 12 words
The copolymer of claim 1 wherein the copolymer withstands a lower alcohol.
Claim 4
Dependent Claim 10 words
The copolymer of claim 2 wherein the alcohol is ethanol.
Claim 5
Dependent Claim 10 words
The copolymer of claim 2 wherein the alcohol is methanol.
Claim 6
Dependent Claim 10 words
The copolymer of claim 2 wherein the alcohol is isopropanol.
Claim 7
Dependent Claim 17 words
The copolymer of claim 1 wherein the copolymer withstands a mixture of hydrocarbons and a lower alcohol.
Claim 8
Dependent Claim 26 words
The copolymer of claim 1 wherein the copolymer withstands a mixture of gasoline, 80-99 percent by weight and 1 to 20 percent by weight of ethanol.
Claim 9
Dependent Claim 15 words
The copolymer of claim 6 wherein (B)(1) is bis(4-aminocyclohexyl) methane and (B)(2) is terephthalic acid.
Claim 10
Dependent Claim 16 words
The copolymer of claim 1 wherein (B)(1) is bis(4-aminocyclohexyl) methane and (B) (2) is terephthalic acid.
Claim 11
Dependent Claim 15 words
The copolymer of claim 1 wherein (B)(1) is 1,3-cyclohexane bis(methylamine) and (B)(2) is terephthalic acid.
Claim 12
Dependent Claim 15 words
The copolymer of claim 1 wherein (B)(1) is 1,4-cyclohexane bis(methylamine) and (B)(2) is terephthalic acid.

References Cited (Backward Citations)

US2868769A Cited
US2868770A Cited
US2985628A Cited
US2985626A Cited
US3206439A Cited
US3259606A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1986-08-08 1987-02-07 1987-08-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1990-08-08 1991-02-07 1991-08-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1994-08-08 1995-02-07 1995-08-09 $7700.00 Window Closed / Lapsed

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