Patent US4898748A successfully refreshed from Google Patents.
US4898748A
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Method for enhancing chemical reactivity in thermal plasma processes
Assignee: Leland Stanford Junior University
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Filing: 1988-08-31
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Granted: 1990-02-06
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Expires: 2008-08-31
Abstract
Abstract A method for enhancing a chemical reaction is provided by forming a plasma that includes at least one multiatomic reactant, flowing the plasma into a reaction zone, and then elevating an electron temperature of the plasma by at least about 1,000° Kelvin. The elevated electron temperature increases the dissociation of the multiatomic reactant in the plasma and/or inhibits recombination of the multiatomic reactant when dissociated. The method may be practiced to enhance the chemical vapor deposition of materials such as silicon and diamond.
Inventors
- 👤 Charles H. Kruger, Jr.
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 05:39
CPC Classifications
C; C23; C23C; C23C16/00; C23C16/22; C23C16/26; C23C16/27; C23C16/272; C23C16/277; C23C16/44; C23C16/448; C23C16/452
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
107 words
A method for enhancing a chemical reaction during which a multiatomic reactant dissociates, comprising: providing a plasma having an initial gas temperature and an initial electron temperature in a reaction zone, the initial gas temperature and the initial electron temperature being the same or within less than about 1,000° Kelvin of each other, the plasma including at least one multiatomic species; and, elevating the electron temperature of the plasma in the reaction zone by at least about 1,000° Kelvin above the initial electron temperature and the initial gas temperature to increase the dissociation of the multiatomic species or to inhibit recombination of the multiatomic species when dissociated.
Claim 2
Independent Claim
107 words
A method for enhancing a chemical reaction during which a multiatomic reactant dissociates, comprising: providing a plasma having an initial gas temperature and an initial electron temperature in a reaction zone, the initial gas temperature and the initial electron temperature being the same or within less than about 1,000° Kelvin of each other, the plasma including at least one multiatomic species; and, elevating the electron temperature of the plasma in the reaction zone by at least about 1,000° Kelvin above the initial electron temperature and the initial gas temperature to increase the dissociation of the multiatomic species or to inhibit recombination of the multiatomic species when dissociated.
Claim 3
Dependent Claim
13 words
The method as in claim 1 wherein the plasma includes hydrogen and hydrocarbon.
Claim 4
Dependent Claim
15 words
The method as in claim 1 wherein a substrate is positioned within the reaction zone.
Claim 5
Dependent Claim
29 words
The method as in claim 1 wherein the plasma is flowed into the reaction zone and the multiatomic species is introduced into the plasma upstream of the reaction zone.
Claim 6
Dependent Claim
18 words
The method as in claim 1 wherein the reaction zone is at about atmospheric pressure during the elevating.
Claim 7
Dependent Claim
27 words
The method as in claim 5 wherein the plasma is formed from a major amount of an inert gas and lesser amounts of a hydrocarbon and hydrogen.
Claim 8
Dependent Claim
35 words
The method as in claim 6 wherein the plasma is formed from between about 1 to about 15 mole % hydrogen, between about 0.1 to about 1 mole % methane, and the rest inert gas.
Claim 9
Dependent Claim
24 words
The method as in claim 7 wherein a substrate is removably positioned in the reaction zone, and diamond or diamond-like carbon is deposited thereon.
Claim 10
Dependent Claim
22 words
The method as in claim 1 wherein the elevating is by establishing an electric field through the plasma in the reaction zone.
Claim 11
Dependent Claim
26 words
The method as in claim 9 wherein a substrate is positioned in the reaction zone and is in electrical communication with the plasma during the elevating.
Claim 12
Dependent Claim
15 words
The method as in claim 10 further comprising controlling the substrate temperature during the elevating.
Claim 13
Dependent Claim
23 words
The method as in claim 1 wherein the elevating is by irradiating the plasma in the reaction zone with substantially coherent electromagnetic radiation.
Claim 14
Dependent Claim
72 words
A plasma deposition method comprising: (a) generating a plasma at about atmospheric pressure, the plasma formed from a monoatomic gas; (b) flowing the plasma into a reaction zone, the reaction zone including a substrate; (c) feeding reactants into the plasma during step (a) or step (b); (d) elevating an electron temperature of the plasma by at least about 1,000° Kelvin; and, (e) depositing a reaction product of the reactants onto the substrate.
Claim 15
Dependent Claim
72 words
A plasma deposition method comprising: (a) generating a plasma at about atmospheric pressure, the plasma formed from a monoatomic gas; (b) flowing the plasma into a reaction zone, the reaction zone including a substrate; (c) feeding reactants into the plasma during step (a) or step (b); (d) elevating an electron temperature of the plasma by at least about 1,000° Kelvin; and, (e) depositing a reaction product of the reactants onto the substrate.
Claim 16
Dependent Claim
37 words
The deposition method as in claim 13 wherein the plasma of step (a) has an initial gas temperature, and the initial gas temperature is permitted to fall within the reaction zone during the elevating of step (d).
Claim 17
Dependent Claim
14 words
The deposition method as in claim 13 wherein the reactants are hydrogen and methane.
Claim 18
Dependent Claim
16 words
The deposition method as in claim 15 wherein the reaction product is diamond or diamond-like carbon.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1993-02-05 | 1993-08-07 | 1994-02-06 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1997-02-05 | 1997-08-07 | 1998-02-06 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2001-02-05 | 2001-08-07 | 2002-02-06 | $7700.00 | Window Closed / Lapsed |