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US4895827A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermally-responsive record material

Assignee: Appvion LLC
•
Filing: 1989-01-17
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Granted: 1990-01-23
•
Expires: 2009-01-17
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Abstract

Abstract An improved thermally-responsive record material having improved image retention is disclosed. The invention is an improved thermally-responsive record member, typically a sheet material, bearing a thermally-responsive color-forming composition comprising a chromogenic material, an acidic developer material, and a metal salt of a compound of the formula ##STR1## wherein M is a metal selected from Zn, Ca, Sn, Ni, Cu, Al, Co, and Mg; wherein m corresponds to the valency of M; wherein n is 1 to 3; wherein R 1 is selected from hydrogen, halogen, alkyl, oxyalkyl, or NO 2 , with the proviso that the alkyl group is of 1 to 50 carbons; wherein R 2 is selected from hydrogen, alkyl, or aryl, with the proviso that the alkyl group is of 1-5 carbon; and a suitable binder therefor.

Inventors

  • 👤 Steven L. Vervacke
  • 👤 Kenneth D. Glanz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 20:04
CPC Classifications
B; B41; B41M; B41M5/00; B41M5/26; B41M5/30; B41M5/32; Y; Y10; Y10S; Y10S428/00; Y10S428/913

Claims Analysis

Total Claims: 33
Claim 1
Independent Claim 140 words
A non-reversible thermally-responsive record material comprising a support member bearing a thermally-sensitive color-forming composition consisting essentially of a chromogenic material and an acidic developer material in contiguous relationship, whereby the melting, softening or sublimation of either material produces a change in color by reaction between the two, a metal salt of a compound of the formula ##STR5## wherein M is a metal selected from Zn, Ca, Sn, Ni, Cu, Al, Co, and Mg; wherein m corresponds to the valency of M; wherein n is 1 to 3; wherein R 1 is selected from hydrogen, halogen, alkyl, oxyalkyl, or NO 2 , with the proviso that the alkyl group is of 1 to 5 carbons; wherein R 2 is selected from hydrogen, alkyl, or aryl, with the proviso that the alkyl group is of 1-5 carbon; and a suitable binder therefor.
Claim 2
Dependent Claim 140 words
A non-reversible thermally-responsive record material comprising a support member bearing a thermally-sensitive color-forming composition consisting essentially of a chromogenic material and an acidic developer material in contiguous relationship, whereby the melting, softening or sublimation of either material produces a change in color by reaction between the two, a metal salt of a compound of the formula ##STR5## wherein M is a metal selected from Zn, Ca, Sn, Ni, Cu, Al, Co, and Mg; wherein m corresponds to the valency of M; wherein n is 1 to 3; wherein R 1 is selected from hydrogen, halogen, alkyl, oxyalkyl, or NO 2 , with the proviso that the alkyl group is of 1 to 5 carbons; wherein R 2 is selected from hydrogen, alkyl, or aryl, with the proviso that the alkyl group is of 1-5 carbon; and a suitable binder therefor.
Claim 3
Dependent Claim 29 words
The record material according to claim 1 wherein M is selected from Zn, Ca, Sn, Ni, Cu, Co, and Mg, wherein m is 2 and wherein n is 1.
Claim 4
Dependent Claim 21 words
The record material of claim 1 wherein in the metal salt of a cinnamic acid of formula (I), M is zinc.
Claim 5
Dependent Claim 21 words
The record material of claim 1 wherein in the metal salt of a cinnamic acid of formula (I) M is calcium.
Claim 6
Dependent Claim 22 words
The record material of claim 1 wherein in the metal salt of a cinnamic acid of formula (I), R 1 is nitro.
Claim 7
Dependent Claim 22 words
The record material of claim 1 wherein in the metal salt of a cinnamic acid of formula (I), R 1 is chlorine.
Claim 8
Dependent Claim 22 words
The record material of claim 1 wherein in the metal salt of a cinnamic acid of formula (I), R 1 is methyl.
Claim 9
Dependent Claim 22 words
The record material of claim 1 wherein in the metal salt of a cinnamic acid of formula (I), R 1 is methoxy.
Claim 10
Dependent Claim 22 words
The record material of claim 1 wherein the acid developer material is the metal salt of a cinnamic acid of formula (I).
Claim 11
Dependent Claim 19 words
The record material of claim 1 wherein the metal salt of a cinnamic acid is zinc (α-phenylcinnamate) 2 .
Claim 12
Dependent Claim 19 words
The record material of claim 1 wherein the metal salt of a cinnamic acid is zinc (α-methylcinnamate) 2 .
Claim 13
Dependent Claim 22 words
The record material of claim 1 wherein in the metal salt of a cinnamic acid of formula (I), R 2 is hydrogen.
Claim 14
Dependent Claim 19 words
The record material of claim 12 wherein the metal salt of a cinnamic acid is zinc (cinnamate) 2 .
Claim 15
Dependent Claim 19 words
The record material of claim 12 wherein the metal salt of a cinnamic acid is zinc (2-chlorocinnamate) 2 .
Claim 16
Dependent Claim 19 words
The record material of claim 12 wherein the metal salt of a cinnamic acid is zinc (3-chlorocinnamate) 2 .
Claim 17
Dependent Claim 19 words
The record material of claim 12 wherein the metal salt of a cinnamic acid is zinc (4-chlorocinnamate) 2 .
Claim 18
Dependent Claim 19 words
The record material of claim 12 wherein the metal salt of a cinnamic acid is zinc (2-methoxycinnamate) 2 .
Claim 19
Dependent Claim 19 words
The record material of claim 12 wherein the metal salt of a cinnamic acid is zinc (3-methoxycinnamate) 2 .
Claim 20
Dependent Claim 19 words
The record material of claim 12 wherein the metal salt of a cinnamic acid is zinc (4-methoxycinnamate) 2 .
Claim 21
Dependent Claim 19 words
The record material of claim 12 wherein the metal salt of a cinnamic acid is zinc (3,4,5-trimethoxycinnamate) 2 .
Claim 22
Dependent Claim 17 words
The record material of claim 12 wherein the metal salt of a cinnamic acid is zinc (4-methylcinnamate).
Claim 23
Dependent Claim 19 words
The record material of claim 12 wherein the metal salt of a cinnamic acid is zinc (2-nitrocinnamate) 2 .
Claim 24
Dependent Claim 19 words
The record material of claim 12 wherein the metal salt of a cinnamic acid is zinc (3-nitrocinnamate) 2 .
Claim 25
Dependent Claim 16 words
The record material of claim 1 in which the acidic developer material is a phenol compound.
Claim 26
Dependent Claim 33 words
The record material of claim 24 in which the phenol compound is selected from the group consisting of 4,4'-isopropylindinediphenol, ethyl-4,4-bis(4-hydroxyphenyl)-pentanoate, n-propyl-4,4-bis(4-hydroxyphenyl)pentanoate, isopropyl-4,4-bis(4-hydroxyphenyl)pentanoate, methyl-4,4-bis(4-hydroxyphenyl)-pentanoate, allyl-4,4-bis(hydroxyphenyl)pentanoate, 2,2-bis(4-hydroxyphenyl)-4-methylpentane, p-hydroxybenzophenone, 2,4-dihydroxybenzophenone, 1,1-bis(4-hydroxyphenyl)cyclohexane, 2,2-bis(4-hydroxyphenyl)-5-methylhexane, benzyl-p-hydroxybenzoate, and mixtures thereof.
Claim 27
Dependent Claim 13 words
The record material of claim 24 in which the phenol compound is 2,2-bis(4-hydroxyphenyl)-4-methylpentane.
Claim 28
Dependent Claim 13 words
The record material of claim 24 in which the phenol compound is benzyl-p-hydroxybenzoate.
Claim 29
Dependent Claim 21 words
The record material of claim 1 wherein in the metal salt of the compound of the formula (I), M is zinc.
Claim 30
Dependent Claim 21 words
The record material of claim 1 wherein in the metal salt of the compound of the formula (I), M is calcium.
Claim 31
Dependent Claim 36 words
The record material of claim 1 in which the chromogenic material is selected from the group consisting of 3-diethylamino-6-methyl-7-anilinofluoran; 7-(1-ethyl-2-methyl-indol-3-yl)-7-(4-diethylamino-2-ethoxyphenyl)-5,7-dihydrofur 3[3,4-b]pyridin-5-one; 3-diethylamino-7-(2-chloroanilino)fluoran; 3-(N-methylcyclohexylamino)-6-methyl-7-anilinofluoran; 7-(1-octyl-2-methyl-indol-3-yl)-7-(4-diethylamino-2-ethoxyphenyl)-5,7-dihydrofur o[3,4-b]pyridin-5-one; 3'-phenyl-7-dibenzylamino-2,2'-spiro-di-[2H-1-benzopyran]; 3-dibutylamino-6-methyl-7-anilinofluoran; 3-(N-ethyl-N-tetrahydrofurfurylamino)-6-methyl-7-anilinofluoran; 3-dibutylamino-7-(2-chloroanilino)fluoran; 3,3-bis(4-dimethylaminophenyl)-6-dimethylaminophthalide; 7-(1-ethyl-2-methyl-indol-3-yl)-7-(4-diethylamino-2-ethoxyphenyl)-5,7-dihydrofur o,[3,4-b]pyridine-5-one; 3,5',6-tris(dimethylamino)spiro[9H-fluorene-9,1'(3'H)-isobenzofuran]3'-one, and mixtures thereof.
Claim 32
Dependent Claim 11 words
The record material of claim 1 comprising in addition a sensitizer.
Claim 33
Dependent Claim 17 words
The record material of claim 31 wherein the sensitizer is selected from 1,2-diphenoxyethane, acetoacet-o-toluedine, p-benzylbiphenyl, and phenyl-1-hydroxy-2-naphthoate.

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-01-22 1993-07-24 1994-01-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-01-22 1997-07-24 1998-01-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-01-22 2001-07-24 2002-01-23 $7700.00 Window Closed / Lapsed

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