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US4891406A Expired / Lapsed US ⏱️ 0.0 years remaining

High impact strength molding compositions based on polyalkylene terephthalates

Assignee: Huels AG
•
Filing: 1987-07-09
•
Granted: 1990-01-02
•
Expires: 2007-07-09
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Abstract

Abstract The production of high impact strength molding compositions obtained by thermal treatment of synthetic resin mixtures containing predominantly polyalkylene terephthalate, in the solid form, characterized in that the synthetic resin mixture contains A. 70-95% or 60-97% by weight of polyalkylene terephthalate and B. when A is 70-95%, 5-30% by weight of a conventional, elasticizing acrylate graft copolymer, a conventional α-olefin copolymer or a conventional polyether amide, or when A is 60-97%, 3-40% of a conventional polyether ester amide, and that the synthetic resin mixture is treated at temperatures of 15°-60° C. below the melting point of the pure component A in an inert gas atmosphere.

Inventors

  • 👤 Josef Bittscheidt
  • 👤 Gernot Horlbeck
  • 👤 Salih Mumcu

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 09:31
CPC Classifications
C; C08; C08L; C08L67/00; C08L67/02

Claims Analysis

Total Claims: 46
Claim 1
Independent Claim 186 words
A process for substantially increasing the impact strength of molding compositions of a synthetic resin mixture containing predominantly a polyalkylene terephthalate with a minor amount of an impact strength modifier, the synthetic resin mixture containing: A. 70-95% or 60-97% by weight of a polyethylene terephthalate, polypropylene terephthalate or polybutylene terephthalate having a viscosity number (J) of about 55-100 cc/g and B. when A is 70-95%, 5-30% by weight of an elasticizing acrylate graft copolymer, an α-olefin copolymer or polyether amide, or when A is 60-97%, 3-40% of a polyether ester amide, the latter being obtained by condensation of at least one omega-aminocarboxylic acid or lactam of at least 10 carbon atoms with a polyalkylene glycol having a number average molecular weight of 400-6,000 and at least one dicarboxylic acid, said process comprising maintaining the synthetic resin mixture in the solid form at temperatures of 15°-60° C. below the melting point of the pure component A in an inert gas atmosphere for a time sufficient to effect recondensation of the synthetic resin mixture and to achieve a substantially higher impact strength than the non-recondensed synthetic resin mixture.
Claim 2
Dependent Claim 186 words
A process for substantially increasing the impact strength of molding compositions of a synthetic resin mixture containing predominantly a polyalkylene terephthalate with a minor amount of an impact strength modifier, the synthetic resin mixture containing: A. 70-95% or 60-97% by weight of a polyethylene terephthalate, polypropylene terephthalate or polybutylene terephthalate having a viscosity number (J) of about 55-100 cc/g and B. when A is 70-95%, 5-30% by weight of an elasticizing acrylate graft copolymer, an α-olefin copolymer or polyether amide, or when A is 60-97%, 3-40% of a polyether ester amide, the latter being obtained by condensation of at least one omega-aminocarboxylic acid or lactam of at least 10 carbon atoms with a polyalkylene glycol having a number average molecular weight of 400-6,000 and at least one dicarboxylic acid, said process comprising maintaining the synthetic resin mixture in the solid form at temperatures of 15°-60° C. below the melting point of the pure component A in an inert gas atmosphere for a time sufficient to effect recondensation of the synthetic resin mixture and to achieve a substantially higher impact strength than the non-recondensed synthetic resin mixture.
Claim 3
Dependent Claim 10 words
Molding compositions, as produced by the process of claim 1.
Claim 4
Dependent Claim 13 words
An article of manufacture formed from a molding composition according to claim 2.
Claim 5
Dependent Claim 24 words
A process according to claim 1 wherein (A) is present in a concentration of 60-97% and (B) is 3-40% of a polyether ester amide.
Claim 6
Dependent Claim 11 words
A molding composition as produced by the process of claim 4.
Claim 7
Dependent Claim 13 words
An article of manufacture formed from a molding composition according to claim 5.
Claim 8
Dependent Claim 93 words
A process according to claim 4 wherein the polyether ester amide is obtained by condensation of: (1) at least one member selected from the group consisting of omega-amino carboxylic acids and lactams of at least 10 carbon atoms, (2) a polyalkylene glycol having a number average molecular weight of 400-6,000, and (3) at least one dicarboxylic acid, the weight ratio of (1) to the sum of (2) and (3) is in a range of 20:80 to 50:50 and the hydroxy and carboxy groups of (2) and (3) are present in approximately equivalent proportions.
Claim 9
Dependent Claim 11 words
A molding composition as produced by the process of claim 7.
Claim 10
Dependent Claim 13 words
An article of manufacture formed from a molding composition according to claim 8.
Claim 11
Dependent Claim 39 words
A process according to claim 7 wherein (A) is laurolactam, (B) is polytetrahydrofurandiol having a number average molecular weight of 650-2,000, and (C) is dodecanedioic acid, the number average molecular weight of the resultant polyether ester amide being 5,000-20,000.
Claim 12
Dependent Claim 11 words
A molding composition as produced by the process of claim 10.
Claim 13
Dependent Claim 13 words
An article of manufacture formed from a molding composition according to claim 11.
Claim 14
Dependent Claim 18 words
A process according to claim 1, wherein components A and B are melt-blended prior to the recondensation step.
Claim 15
Dependent Claim 11 words
A molding composition, as produced by the process of claim 13.
Claim 16
Dependent Claim 13 words
An article of manufacture formed from a molding composition according to claim 14.
Claim 17
Dependent Claim 18 words
A process according to claim 4, wherein components A and B are melt-blended prior to the recondensation step.
Claim 18
Dependent Claim 11 words
A molding composition, as produced by the process of claim 5.
Claim 19
Dependent Claim 13 words
An article of manufacture formed from a molding composition according to claim 6.
Claim 20
Dependent Claim 13 words
A process according to claim 1, wherein said polyalkylene terephthalate is polybutylene terephthalate.
Claim 21
Dependent Claim 14 words
A molding composition according to claim 2, wherein the polyalkylene terephthalate is polybutylene terephthalate.
Claim 22
Dependent Claim 15 words
An article of manufacture according to claim 3, wherein the polyalkylene terephthalate is polybutylene terephthalate.
Claim 23
Dependent Claim 13 words
A process according to claim 4, wherein said polyalkylene terephthalate is polybutylene terephthalate.
Claim 24
Dependent Claim 14 words
A molding composition according to claim 5, wherein the polyalkylene terephthalate is polybutylene terephthalate.
Claim 25
Dependent Claim 15 words
An article of manufacture according to claim 6, wherein the polyalkylene terephthalate is polybutylene terephthalate.
Claim 26
Dependent Claim 13 words
A process according to claim 7, wherein said polyalkylene terephthalate is polybutylene terephthalate.
Claim 27
Dependent Claim 14 words
A molding composition according to claim 8, wherein the polyalkylene terephthalate is polybutylene terephthalate.
Claim 28
Dependent Claim 15 words
An article of manufacture according to claim 9, wherein the polyalkylene terephthalate is polybutylene terephthalate.
Claim 29
Dependent Claim 13 words
A process according to claim 10, wherein said polyalkylene terephthalate is polybutylene terephthalate.
Claim 30
Dependent Claim 14 words
A molding composition according to claim 11, wherein the polyalkylene terephthalate is polybutylene terephthalate.
Claim 31
Dependent Claim 15 words
An article of manufacture according to claim 12, wherein the polyalkylene terephthalate is polybutylene terephthalate.
Claim 32
Dependent Claim 13 words
A process according to claim 13, wherein said polyalkylene terephthalate is polybutylene terephthalate.
Claim 33
Dependent Claim 14 words
A molding composition according to claim 14, wherein the polyalkylene terephthalate is polybutylene terephthalate.
Claim 34
Dependent Claim 15 words
An article of manufacture according to claim 15, wherein the polyalkylene terephthalate is polybutylene terephthalate.
Claim 35
Dependent Claim 13 words
A process according to claim 16, wherein said polyalkylene terephthalate is polybutylene terephthalate.
Claim 36
Dependent Claim 14 words
A molding composition according to claim 17, wherein the polyalkylene terephthalate is polybutylene terephthalate.
Claim 37
Dependent Claim 15 words
An article of manufacture according to claim 18, wherein the polyalkylene terephthalate is polybutylene terephthalate.
Claim 38
Dependent Claim 29 words
An article of manufacture according to claim 15, wherein component A is polybutylene terephthalate, said article of manufacture having a minimum notched impact strength at -20° C. of 11.1.
Claim 39
Dependent Claim 29 words
An article of manufacture according to claim 15, wherein component A is polybutylene terephthalate, said article of manufacture having a minimum notched impact strength at -20° C. of 17.5.
Claim 40
Dependent Claim 29 words
An article of manufacture according to claim 24, wherein component A is polybutylene terephthalate, said article of manufacture having a minimum notched impact strength at -20° C. of 11.1.
Claim 41
Dependent Claim 29 words
An article of manufacture according to claim 24, wherein component A is polybutylene terephthalate, said article of manufacture having a minimum notched impact strength at -20° C. of 17.5.
Claim 42
Dependent Claim 26 words
A molding composition according to claim 20, said molding composition being capable of yielding articles having notched impact strengths of at least 11.1 at -20° C.
Claim 43
Dependent Claim 26 words
A molding composition according to claim 20, said molding composition being capable of yielding articles having notched impact strengths of at least 17.5 at -20° C.
Claim 44
Dependent Claim 34 words
A molding composition according to claim 14, wherein component A is polybutylene terephthalate and the molding composition is capable of yielding articles having a notched impact strength of at least 11.1 at -20° C.
Claim 45
Dependent Claim 34 words
A molding composition according to claim 14, wherein component A is polybutylene terephthalate and the molding composition is capable of yielding articles having a notched impact strength of at least 17.5 at -20° C.
Claim 46
Dependent Claim 19 words
A process according to claim 1, wherein the impact strength is increased by at least 250% at 23° C.

References Cited (Backward Citations)

US3580965A Cited
US3578729A Cited
US4025492A Cited
US4022748A Cited
US4096202A Cited
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US4309518A Cited
US4360661A Cited
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US4434276A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1993-01-01 1993-07-03 1994-01-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1997-01-01 1997-07-03 1998-01-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2001-01-01 2001-07-03 2002-01-02 $7700.00 Window Closed / Lapsed

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