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US4886714A Expired / Lapsed US ⏱️ 0.0 years remaining

Platelike magnetic powder and a recording medium which uses the platelike magnetic powder

Assignee: Panasonic Holdings Corp
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Filing: 1988-05-09
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Granted: 1989-12-12
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Expires: 2008-05-09
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Abstract

Abstract The present invention provides a platelike magnetic powder made from a magnetic powder having particles each of which has a portion comprising the spinel type crystal structure and a portion comprising the magnetoplumbite type crystal structure. The magnetic powder provides a large saturation magnetization σs and a small temperature change ΔHc/ΔT of coercive force in the vicinity of the room temperature. Further, the present invention is to provide a high density magnetic recording medium which uses the magnetic powder. Furthermore, the present invention is to provide, a method to easily manufacture the magnetic powder by the coprecipitation method. A raw material powder of superfine particles is prepared. The prepared powder is fired at a low temperature in a non-oxidizing atmosphere.

Inventors

  • 👤 Hideo Torii
  • 👤 Masaki Aoki
  • 👤 Hideaki Komoda
  • 👤 Nobuyuki Aoki
  • 👤 Ikuo Ota
  • 👤 Keiichi Ochiai

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 20:13
CPC Classifications
G; G11; G11B; G11B5/00; G11B5/62; G11B5/68; G11B5/70; G11B5/706; G11B5/70626; G11B5/70642; G11B5/70678

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 297 words
An iron oxide magnetic powder of platelike particles, having a composition expressed by the formula: MFe.sup.II.sub.m-x-2[x]z Fe.sup.III.sub.12+2(m+n)-y A.sup.II.sub.x B.sup.III.sub.y C.sup.IV.sub.z O.sub.p where: M is a metallic element comprising at least one of Ba, Sr, Pb and Ca; A is at least one metallic element selected from the group consisting of Co, Cu, Ni, Zn and Mn; B is at least one metallic element selected from the group consisting of Cr, Al and In; C is at least one metallic element selected from the group consisting of Ti, Zr, Ge and Sn; x is 0.70 to 1.86; y is 0 to 0.11; z is 0.70 to 1.80; p is a number of oxygens satisfying electric neutrality; and each of m and n is a positive number satisfying the relation: 21.30≧12+3m+2n-z≧14.90, wherein each of the particles has a magnetoplumbite and spinel crystal structure, in which layers each comprising R blocks and layers each comprising S blocks are alternately arranged, where: each of the R blocks is defined as a crystal block which contains Fe 3+ ions and has, in parallel with a c plane of the magnetoplumbite structure, three layers in which a layer containing one M 2+ ion and three O 2- ions is arranged between two layers each containing nine O 2- ions; and each of the S blocks is defined as a crystal block which contains Fe 3+ ions and has, in parallel with the c plane, two symmetrical layers each containing four O 2+ ions, and wherein, in each of the particles, part of the R blocks are lacking in M 2+ ions such that said part is replaced by S blocks to reduce the number of the R blocks whereby the number of the S blocks is larger than that of the R blocks.
Claim 2
Dependent Claim 297 words
An iron oxide magnetic powder of platelike particles, having a composition expressed by the formula: MFe.sup.II.sub.m-x-2[x]z Fe.sup.III.sub.12+2(m+n)-y A.sup.II.sub.x B.sup.III.sub.y C.sup.IV.sub.z O.sub.p where: M is a metallic element comprising at least one of Ba, Sr, Pb and Ca; A is at least one metallic element selected from the group consisting of Co, Cu, Ni, Zn and Mn; B is at least one metallic element selected from the group consisting of Cr, Al and In; C is at least one metallic element selected from the group consisting of Ti, Zr, Ge and Sn; x is 0.70 to 1.86; y is 0 to 0.11; z is 0.70 to 1.80; p is a number of oxygens satisfying electric neutrality; and each of m and n is a positive number satisfying the relation: 21.30≧12+3m+2n-z≧14.90, wherein each of the particles has a magnetoplumbite and spinel crystal structure, in which layers each comprising R blocks and layers each comprising S blocks are alternately arranged, where: each of the R blocks is defined as a crystal block which contains Fe 3+ ions and has, in parallel with a c plane of the magnetoplumbite structure, three layers in which a layer containing one M 2+ ion and three O 2- ions is arranged between two layers each containing nine O 2- ions; and each of the S blocks is defined as a crystal block which contains Fe 3+ ions and has, in parallel with the c plane, two symmetrical layers each containing four O 2+ ions, and wherein, in each of the particles, part of the R blocks are lacking in M 2+ ions such that said part is replaced by S blocks to reduce the number of the R blocks whereby the number of the S blocks is larger than that of the R blocks.
Claim 3
Dependent Claim 34 words
An iron oxide magnetic powder according to claim 1, wherein the diameter of each of the particle is 0.03 to 0.15 μm and the average value of particle diameter/ thickness is 2 to 18.
Claim 4
Dependent Claim 35 words
An iron oxide magnetic powder according to claim 1, wherein, in a temperature range of 15° to 100° C., the temperature coefficient of the coercive force (ΔHc/ΔT) is in a range of -1 to +1.
Claim 5
Dependent Claim 45 words
An iron oxide magnetic powder according to claim 1, wherein the saturation magnetization value σs is 50.8 to 67.0 emu/g, the coercive force Hc is at most 1410 Oe, and axis which can be easily magnetized is in a perpendicular direction to the plate surface.
Claim 6
Dependent Claim 24 words
A recording medium which is manufactured by coating a non-magnetic carrier with an iron oxide magnetic powder of claim 1 and a resin binder.

References Cited (Backward Citations)

US4306921A Cited
JPS582225A Cited
US4584242A Cited
JPS61136923A Cited
EP0214644A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-12-11 1993-06-12 1993-12-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-12-11 1997-06-12 1997-12-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-12-11 2001-06-12 2001-12-12 $7700.00 Window Closed / Lapsed

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