Elastomer modified polycarbonate compositions of improved impact strength

Claim 2

A thermoplastic polycarbonate composition of improved impact strength which comprises a polymer blend of: (a) a thermoplastic polycarbonate plastics material; and (b) an impact modifier comprising (i) an elastomer component which contains from 45-55 wt.% ethylene selected from highly amorphous ethylene-higher alpha olefin copolymers, highly amorphous ethylene-higher alpha olefin-polyene terpolymers and mixtures thereof, and (ii) a plastics component selected from ethylene homo- and copolymers.

Claim 3

A composition according to claim 1 which comprises from 2-30 wt % impact modifier (b) based on the weight of polycarbonate material (a).

Claim 4

A composition according to claim 2 which comprises from 3-20 wt % (b).

Claim 5

A composition according to claim 1 wherein the modifier (b) comprises from 50∝85 wt % elastomer component (i), based on the total weight of (b).

Claim 6

A composition according to claim 4 wherein the modifier (b) comprises from 60-75 wt % (i).

Claim 7

A composition according to claim 1 wherein said elastomer component (i) has a Mooney ML (1+8) at 127° C. of 55-65 (ASTM D1646).

Claim 8

A composition according to claim 1 wherein the elastomer component (i) comprises EPM copolymer, EPDM terpolymer or a mixture thereof, the terms EPM and EPDM being used herein in accordance with their ASTM designations.

Claim 9

A composition according to claim 1 wherein component (ii) of modifier (b) comprises a homopolyethylene having a Tg value below -80° C.

Claim 10

A composition according to claim 8 wherein component (ii) comprises high density polyethylene of melt index from 1.5 to 2.5.

Claim 11

A composition according to claim 1 which comprises, in addition to the polymer blend, a polyalkyleneterephthalate material.

Claim 12

A composition according to claim 10 wherein the said polyalkyleneterephthalate material is selected from polyethyleneterephthalate, polybuteneterephthalate and mixtures thereof.

Claim 13

A composition according to claim 10 which comprises from 2-100 wt % said polyalkyleneterephthalate material, based on the weight of polycarbonate.

Claim 14

A composition according to claim 10 which comprises from 5-50 wt % said polyalkyleneterephthalate material.

Claim 15

A thermoplastic polycarbonate composition of improved impact strength which comprises a polymer blend of: (a) a thermoplastic polycarbonate plastics material; and (b) an effective amount of an impact modifier comprising (i) an elastomer component selected from high viscosity, highly amorphous EPM copolymers and EPDM terpolymers containing from 45-55 wt % ethylene and having a Mooney ML (1+8) at 127° C. of from 55-65 (ASTM D 1646), and (ii) a high density polyethylene of melt index from 0.5 to 5.0 (ASTM 1238 Condition E) and Tg value below -80° C.

Claim 16

A thermoplastic polycarbonate composition of improved impact strength which comprises a polymer blend of: (a) a thermoplastic polycarbonate plastics material; and (b) an effective amount of an impact modifier comprising (i) an elastomer component selected from high viscosity, highly amorphous EPM copolymers and EPDM terpolymers containing from 45-55 wt % ethylene and having a Mooney ML (1+8) at 127° C. of from 55-65 (ASTM D 1646), and (ii) a high density polyethylene of melt index from 0.5 to 5.0 (ASTM 1238 Condition E) and Tg value below -80° C.

Claim 17

A method of producing a composition according to claim 1 which comprises (I) forming a molten preblend of modifier components (i) and (ii); (II) admixing component (a) with said preblended modifier, optionally together with process aids and conventional additives for thermoplastic materials, at a temperature in the range 220° to 280° C.; and (III) forming the resulting admixture into a shaped body.

Claim 18

A method according to claim 15 wherein step (I) is performed by melting an already formed granulate of a blend of said components (i) and (ii).