Patent US2543876A successfully refreshed from Google Patents.
Patent US4880873A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4880873A Expired / Lapsed US ⏱️ 0.0 years remaining

Adhesive for chlorine-containing polymers and aromatic group-containing polymers

Assignee: Mitsui Chemicals Inc
•
Filing: 1988-03-17
•
Granted: 1989-11-14
•
Expires: 2008-03-17
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract Disclosed is a thermoplastic adhesive comprising a modified polyolefin resin having a branch chain having at least one carbonyl group and at least one benzene nucleus in one side chain. This adhesive shows a strong bonding force to a chlorine-containing polymer or an aromatic group-containing polymer such as a polyester and is especially valuable for the production of a laminate of such a resin and a polyolefin. A blend or block copolymer comprising an olefin resin component that can contain a carboxyl group and a carbon-to-carbon chain resin component having a benzoic acid ester or cinnamic acid ester group in the side chain is especially excellent in the bonding characteristics, particularly the heat-resistance adhesion.

Inventors

  • 👤 Toshihiro Sagane

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 19:10
CPC Classifications
C; C08; C08J; C08J5/00; C08J5/12; C08J5/124; C09; C09J; C09J123/00; C09J123/26

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 240 words
An adhesive for joining together two polymers to form a laminated structure comprising (A) a first layer of polymer selected from the group consisting of a chlorine-containing polymer and an aromatic polymer, (B) a second layer selected from the group consisting of a chlorine-containing polymer, an aromatic polymer and a polyolefin with (C) an adhesive layer therebetween, said adhesive comprising a modified olefin polymer composed of (a) a recurring monomer unit selected from the group consisting of ethylene and propylene, and (b) a recurring monomer unit represented by following formula: ##STR63## wherein R 1 and R 2 stand for a hydrogen atom or an alkyl group having up to 4 carbon atoms, each of k, l, m and n is 0 or 1, Z 1 , Z 2 , Z 3 and Z 4 stand for an oxygen atom or a divalent group comprising at least two elements selected from carbon, hydrogen, nitrogen and oxygen, X 1 stands for a monovalent group comprising at least two elements selected from carbon, hydrogen, nitrogen and oxygen or a blend of said modified olefin polymer with a polyolefin, wherein ##STR64## in said recurring monomer unit (b) is selected from the group consisting of ##STR65## and is present at a concentration of 59 to 267 millimoles per 100 g of the polymer, and said polymer having an intrinsic viscosity (η) measured at 135° C. in decalin as a solvent of 0.7 to 4 dl/g.
Claim 2
Dependent Claim 240 words
An adhesive for joining together two polymers to form a laminated structure comprising (A) a first layer of polymer selected from the group consisting of a chlorine-containing polymer and an aromatic polymer, (B) a second layer selected from the group consisting of a chlorine-containing polymer, an aromatic polymer and a polyolefin with (C) an adhesive layer therebetween, said adhesive comprising a modified olefin polymer composed of (a) a recurring monomer unit selected from the group consisting of ethylene and propylene, and (b) a recurring monomer unit represented by following formula: ##STR63## wherein R 1 and R 2 stand for a hydrogen atom or an alkyl group having up to 4 carbon atoms, each of k, l, m and n is 0 or 1, Z 1 , Z 2 , Z 3 and Z 4 stand for an oxygen atom or a divalent group comprising at least two elements selected from carbon, hydrogen, nitrogen and oxygen, X 1 stands for a monovalent group comprising at least two elements selected from carbon, hydrogen, nitrogen and oxygen or a blend of said modified olefin polymer with a polyolefin, wherein ##STR64## in said recurring monomer unit (b) is selected from the group consisting of ##STR65## and is present at a concentration of 59 to 267 millimoles per 100 g of the polymer, and said polymer having an intrinsic viscosity (η) measured at 135° C. in decalin as a solvent of 0.7 to 4 dl/g.
Claim 3
Dependent Claim 66 words
An adhesive which comprises a benzoic acid-esterified ethylene/vinyl alcohol copolymer which is obtained by reacting an ethylene/vinyl alcohol copolymer with a benzoyl chloride, said benzoic acid-esterified copolymer having a benzoic ester group at a concentration of 59 to 267 millimoles per 100 g of the polymer and having an intrinsic viscosity (η) measured at 135° C. in decalin as a solvent of 0.7 to 4 dl/g.
Claim 4
Dependent Claim 66 words
An adhesive which comprises a benzoic acid-esterified ethylene/vinyl alcohol copolymer which is obtained by reacting an ethylene/vinyl alcohol copolymer with a benzoyl chloride, said benzoic acid-esterified copolymer having a benzoic ester group at a concentration of 59 to 267 millimoles per 100 g of the polymer and having an intrinsic viscosity (η) measured at 135° C. in decalin as a solvent of 0.7 to 4 dl/g.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-11-13 1993-05-15 1993-11-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-11-13 1997-05-15 1997-11-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-11-13 2001-05-15 2001-11-14 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag