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US4879051A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of boosting foam in low sudsing detergents with zwitterionic polysiloxane

Assignee: Dow Silicones Corp
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Filing: 1988-08-08
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Granted: 1989-11-07
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Expires: 2008-08-08
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Abstract

Abstract A method of boosting foam in a low sudsing detergent system containing high levels of cationic or nonionic fabric softening surfactants in a textile wash liquor wherein there is added to the wash liquor in addition to the detergent a foam boosting effective amount of a short chain non-toxic organosulfobetaine zwitterionic siloxane based silicone surfactant compound, and causing the detergent and the silicone compound to be homogeneously intermixed in the wash liquor along with the textiles.

Inventors

  • 👤 Sunny J. Lo
  • 👤 Steven A. Snow

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 05:32
CPC Classifications
C; C11; C11D; C11D1/00; C11D1/88; C11D1/92; C11D3/00; C11D3/16; C11D3/37; C11D3/3703; C11D3/373; C11D3/3742; C11D1/94; C11D3/0005; C11D3/0026; C11D3/0094; Y; Y10; Y10S; Y10S516/00; Y10S516/01; Y10S516/03; Y10S516/05

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 145 words
A method of boosting foam in a low sudsing detergent system which contains cationic or nonionic fabric softening surfactants in a textile wash liquor comprising adding to the wash liquor in addition to the detergent an organosulfobetaine zwitterionic siloxane based compound having the general formula selected from the group consisting of: Me.sub.3 SiO(SiMeR.sup.1 O).sub.y SiMe.sub.3 and Me.sub.3 SiO(SiMe.sub.2 O).sub.x (SiMeR.sup.1 O).sub.y SiMe.sub.3 wherein: Me=methyl; R 1 =--CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z SO 3 - , or --CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z COO - ; R 2 =an alkyl group having from one to six carbon atoms or (CH 2 ) m OH; m=1-6; x=1-10; y=1-3; and z=1-4, and mixing the detergent and the siloxane compound in the wash liquor along with the textiles.
Claim 2
Independent Claim 145 words
A method of boosting foam in a low sudsing detergent system which contains cationic or nonionic fabric softening surfactants in a textile wash liquor comprising adding to the wash liquor in addition to the detergent an organosulfobetaine zwitterionic siloxane based compound having the general formula selected from the group consisting of: Me.sub.3 SiO(SiMeR.sup.1 O).sub.y SiMe.sub.3 and Me.sub.3 SiO(SiMe.sub.2 O).sub.x (SiMeR.sup.1 O).sub.y SiMe.sub.3 wherein: Me=methyl; R 1 =--CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z SO 3 - , or --CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z COO - ; R 2 =an alkyl group having from one to six carbon atoms or (CH 2 ) m OH; m=1-6; x=1-10; y=1-3; and z=1-4, and mixing the detergent and the siloxane compound in the wash liquor along with the textiles.
Claim 3
Dependent Claim 39 words
The method of claim 1 wherein the siloxane compound is present in the wash liquor in an amount of from about one tenth of one percent to about one percent by weight based on the weight of wash liquor.
Claim 4
Dependent Claim 18 words
The method of claim 2 wherein the degree of polymerization of the siloxane is less than about twenty.
Claim 5
Dependent Claim 139 words
A detergent comprising a low sudsing detergent formulation which includes cationic or nonionic fabric softening surfactants for a textile wash liquor and an organosulfobetaine zwitterionic siloxane based compound, the detergent and the siloxane compound being mixed together for use in the wash liquor along with the textiles, the siloxane being a compound having the general formula selected from the group consisting of: Me.sub.3 SiO(SiMeR.sup.1 O).sub.y SiMe.sub.3 and Me.sub.3 SiO(SiMe.sub.2 O).sub.x (SiMeR.sup.1 O).sub.y SiMe.sub.3 wherein: Me=methyl; R 1 =--CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z SO 3 - , or --CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z COO - ; R 2 =alkyl group having from one to six carbon atoms or (CH 2 ) m OH; m=1-6; x=1-10; y=1-3; and z=1-4.
Claim 6
Dependent Claim 139 words
A detergent comprising a low sudsing detergent formulation which includes cationic or nonionic fabric softening surfactants for a textile wash liquor and an organosulfobetaine zwitterionic siloxane based compound, the detergent and the siloxane compound being mixed together for use in the wash liquor along with the textiles, the siloxane being a compound having the general formula selected from the group consisting of: Me.sub.3 SiO(SiMeR.sup.1 O).sub.y SiMe.sub.3 and Me.sub.3 SiO(SiMe.sub.2 O).sub.x (SiMeR.sup.1 O).sub.y SiMe.sub.3 wherein: Me=methyl; R 1 =--CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z SO 3 - , or --CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z COO - ; R 2 =alkyl group having from one to six carbon atoms or (CH 2 ) m OH; m=1-6; x=1-10; y=1-3; and z=1-4.
Claim 7
Dependent Claim 36 words
The detergent of claim 4 wherein the siloxane compound is present in an amount of from about one tenth of one percent to about one percent by weight based on the weight of the wash liquor.
Claim 8
Dependent Claim 18 words
The detergent of claim 5 wherein the degree of polymerization of the siloxane is less than about twenty.
Claim 9
Independent Claim 147 words
A method of reducing the surface tension of a low sudsing detergent system which contains cationic or nonionic fabric softening surfactants in a textile wash liquor comprising adding to the wash liquor in addition to the detergent, an organosulfobetaine zwitterionic siloxane based compound having the general formula selected from the group consisting of: Me.sub.3 SiO(SiMeR.sup.1 O).sub.y SiMe.sub.3 and Me.sub.3 SiO(SiMe.sub.2 O).sub.x (SiMeR.sup.1 O).sub.y SiMe.sub.3 wherein: Me=methyl; R 1 =--CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z SO 3 - , or --CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z COO - ; R 2 =an alkyl group having from one to six carbon atoms or (CH 2 ) m OH; m=1-6; x=1-10; y=1-3; and z=1-4, and mixing the detergent and the siloxane compound in the wash liquor along with the textiles.
Claim 10
Independent Claim 147 words
A method of reducing the surface tension of a low sudsing detergent system which contains cationic or nonionic fabric softening surfactants in a textile wash liquor comprising adding to the wash liquor in addition to the detergent, an organosulfobetaine zwitterionic siloxane based compound having the general formula selected from the group consisting of: Me.sub.3 SiO(SiMeR.sup.1 O).sub.y SiMe.sub.3 and Me.sub.3 SiO(SiMe.sub.2 O).sub.x (SiMeR.sup.1 O).sub.y SiMe.sub.3 wherein: Me=methyl; R 1 =--CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z SO 3 - , or --CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z COO - ; R 2 =an alkyl group having from one to six carbon atoms or (CH 2 ) m OH; m=1-6; x=1-10; y=1-3; and z=1-4, and mixing the detergent and the siloxane compound in the wash liquor along with the textiles.
Claim 11
Dependent Claim 39 words
The method of claim 7 wherein the siloxane compound is present in the wash liquor in an amount of from about one tenth of one percent to about one percent by weight based on the weight of wash liquor.
Claim 12
Dependent Claim 18 words
The method of claim 8 wherein the degree of polymerization of the siloxane is less than about twenty.
Claim 13
Independent Claim 151 words
A method of boosting foam and simultaneously reducing the surface tension in a low sudsing detergent system which contains cationic or nonionic fabric softening surfactants in a textile wash liquor comprising adding to the wash liquor in addition to the detergent an organosulfobetaine zwitterionic siloxane based compound having the general formula selected from the group consisting of: Me.sub.3 SiO(SiMeR.sup.1 O).sub.y SiMe.sub.3 and Me.sub.3 SiO(SiMe.sub.2 O).sub.x (SiMeR.sup.1 O).sub.y SiMe.sub.3 wherein: Me=methyl; R 1 =--CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z SO 3 - , or --CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z COO - ; R 2 =an alkyl group having from one to six carbon atoms or (CH 2 ) m OH; m=1-6; x=1-10; y=1-3; and z=1-4, and mixing the detergent and the siloxane compound in the wash liquor along with the textiles.
Claim 14
Independent Claim 151 words
A method of boosting foam and simultaneously reducing the surface tension in a low sudsing detergent system which contains cationic or nonionic fabric softening surfactants in a textile wash liquor comprising adding to the wash liquor in addition to the detergent an organosulfobetaine zwitterionic siloxane based compound having the general formula selected from the group consisting of: Me.sub.3 SiO(SiMeR.sup.1 O).sub.y SiMe.sub.3 and Me.sub.3 SiO(SiMe.sub.2 O).sub.x (SiMeR.sup.1 O).sub.y SiMe.sub.3 wherein: Me=methyl; R 1 =--CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z SO 3 - , or --CH 2 CH 2 CH 2 N + (R 2 ) 2 (CH 2 ) z COO - ; R 2 =an alkyl group having from one to six carbon atoms or (CH 2 ) m OH; m=1-6; x=1-10; y=1-3; and z=1-4, and mixing the detergent and the siloxane compound in the wash liquor along with the textiles.
Claim 15
Dependent Claim 39 words
The method of claim 10 wherein the siloxane compound is present in the wash liquor in an amount of from about one tenth of one percent to about one percent by weight based on the weight of wash liquor.
Claim 16
Dependent Claim 18 words
The method of claim 11 wherein the degree of polymerization of the siloxane is less than about twenty.

References Cited (Backward Citations)

EP0276114A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-11-06 1993-05-08 1993-11-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-11-06 1997-05-08 1997-11-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-11-06 2001-05-08 2001-11-07 $7700.00 Window Closed / Lapsed

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