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US4877679A Expired / Lapsed US ⏱️ 0.0 years remaining

Multilayer article of microporous and porous materials

Assignee: PPG Industries Ohio Inc
•
Filing: 1988-12-19
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Granted: 1989-10-31
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Expires: 2008-12-19
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Abstract

Abstract A multilayer article comprises at least one layer of substantially porous material bonded to at least one layer of microporous material comprising a matrix consisting essentially of linear ultrahigh molecular weight polyolefin, a large proportion of finely divided, water-insoluble siliceous filler, and interconnecting pores. The microporous material has regions of stretch-induced molecularly oriented polymer in the matrix.

Inventors

  • 👤 Dennis D. Leatherman
  • 👤 Thomas Rechlicz
  • 👤 Richard A. Schwarz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 10:21
CPC Classifications
B; B32; B32B; B32B5/00; B32B5/22; B32B5/32; B32B5/02; B32B29/00; B32B29/002; B32B5/18; C; C08; C08J; C08J5/00; C08J5/12; C08J5/121; B32B2266/00; B32B2266/08; B32B2305/00; B32B2305/02; B32B2305/022; B32B2305/026; B32B2317/00; B32B2317/12; Y; Y10; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249953; Y10T428/249978; Y10T428/249979; Y10T428/249981; Y10T428/249986; Y10T442/00; Y10T442/10; Y10T442/184; Y10T442/198; Y10T442/20; Y10T442/2139; Y10T442/2148

Claims Analysis

Total Claims: 36
Claim 1
Independent Claim 153 words
A multilayer article comprising at least one layer of porous material bonded to at least one layer of microporous material comprising (a) a matrix consisting essentially of essentially linear ultrahigh molecular weight polyolefin which is essentially linear ultrahigh molecular weight polyethylene having an intrinsic viscosity of at least about 18 deciliters/gram, essentially linear ultrahigh molecular weight polypropylene having an intrinsic viscosity of at least about 6 deciliters/gram, or a mixture thereof; said matrix comprising regions of stretch-induced molecularly oriented ultrahigh molecular weight polyolefin distributed throughout said matrix, (b) finely divided particulate substantially water-insoluble filler, of which at least about 50 percent by weight is siliceous, distributed throughout said matrix, said filler constituting from about 50 percent to about 90 percent by weight of said microporous material, and (c) a network of interconnecting pores communicating throughout said microporous material, said pores before bonding constituting more than 80 percent by volume of said microporous material.
Claim 2
Dependent Claim 153 words
A multilayer article comprising at least one layer of porous material bonded to at least one layer of microporous material comprising (a) a matrix consisting essentially of essentially linear ultrahigh molecular weight polyolefin which is essentially linear ultrahigh molecular weight polyethylene having an intrinsic viscosity of at least about 18 deciliters/gram, essentially linear ultrahigh molecular weight polypropylene having an intrinsic viscosity of at least about 6 deciliters/gram, or a mixture thereof; said matrix comprising regions of stretch-induced molecularly oriented ultrahigh molecular weight polyolefin distributed throughout said matrix, (b) finely divided particulate substantially water-insoluble filler, of which at least about 50 percent by weight is siliceous, distributed throughout said matrix, said filler constituting from about 50 percent to about 90 percent by weight of said microporous material, and (c) a network of interconnecting pores communicating throughout said microporous material, said pores before bonding constituting more than 80 percent by volume of said microporous material.
Claim 3
Dependent Claim 24 words
The multilayer article of claim 1 wherein said microporous material has a thickness in the range of from about 0.03 to about 0.4 millimeter.
Claim 4
Dependent Claim 19 words
The multilayer article of claim 1 wherein said layer of porous material is another layer of said microporous material.
Claim 5
Dependent Claim 22 words
The multilayer article of claim 1 wherein said layer of porous material is a layer of porous thermoplastic polymeric sheet or film.
Claim 6
Dependent Claim 19 words
The multilayer article of claim 1 wherein said layer of porous material is a layer of open celled foam.
Claim 7
Dependent Claim 17 words
The multilayer article of claim 1 wherein said layer of porous material is a layer of fabric.
Claim 8
Dependent Claim 12 words
The multilayer article of claim 6 wherein said fabric is woven fabric.
Claim 9
Dependent Claim 12 words
The multilayer article of claim 6 wherein said fabric is knitted fabric.
Claim 10
Dependent Claim 12 words
The multilayer article of claim 6 wherein said fabric is nonwoven fabric.
Claim 11
Dependent Claim 17 words
The multilayer article of claim 9 wherein said microporous material is powder bonded to said nonwoven fabric.
Claim 12
Dependent Claim 12 words
The multilayer article of claim 6 wherein said fabric is a scrim.
Claim 13
Dependent Claim 18 words
The multilayer article of claim 1 wherein said layer of porous material is a layer of fiber mat.
Claim 14
Dependent Claim 17 words
The multilayer article of claim 1 wherein said layer of porous material is a layer of paper.
Claim 15
Dependent Claim 18 words
The multilayer article of claim 1 wherein said layer of porous material is a layer of synthetic paper.
Claim 16
Dependent Claim 17 words
The multilayer article of claim 1 wherein said layer of porous material is a layer of felt.
Claim 17
Dependent Claim 31 words
The multilayer article of claim 1 wherein said essentially linear ultrahigh molecular weight polyolefin is essentially linear ultrahigh molecular weight polyethylene having an intrinsic viscoity of at least about 18 deciliters/gram.
Claim 18
Dependent Claim 27 words
The multilayer article of claim 16 wherein said ultrahigh molecular weight polyethylene has an intrinsic viscosity in the range of from about 18 to about 39 deciliters/gram.
Claim 19
Dependent Claim 19 words
The multilayer article of claim 16 wherein at least about 65 percent by weight of said filler is siliceous.
Claim 20
Dependent Claim 19 words
The multilayer article of claim 16 wherein at least about 85 percent by weight of said filler is siliceous.
Claim 21
Dependent Claim 13 words
The multilayer article of claim 16 wherein all of said filler is siliceous.
Claim 22
Dependent Claim 12 words
The multilayer article of claim 16 wherein said siliceous filler is silica.
Claim 23
Dependent Claim 13 words
The multilayer article of claim 16 wherein said siliceous filler is precipitated silica.
Claim 24
Dependent Claim 22 words
The multilayer article of claim 22 wherein said precipitated silica has an average ultimate particle size of less than about 0.1 micrometer.
Claim 25
Dependent Claim 31 words
The multilayer article of claim 16 wherein the volume average diameter of said pores as determined by mercury porosimetry is in the range of from about 0.6 to about 50 micrometers.
Claim 26
Dependent Claim 25 words
The multilayer article of claim 16 wherein said pores constitute from more than 80 percent to about 95 percent by volume of said microporous material.
Claim 27
Dependent Claim 28 words
The multilayer article of claim 1 wherein said layer of microporous material is indirectly bonded to said layer of porous material by one or more intermediate bonding layers.
Claim 28
Dependent Claim 26 words
The multilayer article of claim 1 wherein said layer of microporous material is indirectly bonded to said layer of porous material by a layer of adhesive.
Claim 29
Dependent Claim 21 words
The multilayer article of claim 1 wherein said layer of microporous material is heat sealed to said layer of porous material.
Claim 30
Dependent Claim 21 words
The multilayer article of claim 1 wherein said layer of microporous material is discontinuously bonded to said layer of porous material.
Claim 31
Dependent Claim 22 words
The multilayer article of claim 1 wherein said layer of microporous material is essentially continuously bonded to said layer of porous material.
Claim 32
Dependent Claim 36 words
The multilayer article of claim 1 wherein other thermoplastic organic polymer is present in said matrix and wherein at least about 50 percent by weight of said matrix is said essentially linear ultrahigh molecular weight polyolefin.
Claim 33
Dependent Claim 14 words
The multilayer article of claim 31 wherein said other thermoplastic organic polymer is polypropylene.
Claim 34
Dependent Claim 16 words
The multilayer article of claim 31 wherein said other thermoplastic organic polymer is high density polyethylene.
Claim 35
Dependent Claim 36 words
The multilayer article of claim 1 wherein other thermoplastic organic polymer is present in said matrix and wherein at least about 70 percent by weight of said matrix is said essentially linear ultrahigh molecular weight polyolefin.
Claim 36
Dependent Claim 17 words
The multilayer article of claim 1 wherein other thermoplastic organic polymer is substantially absent from said matrix.

References Cited (Backward Citations)

US4377616A Cited
US4539256A Cited
US4707404A Cited
US4578297A Cited
US4702954A Cited
US4632869A Cited
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US4704323A Cited
JPH0689333A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-10-30 1993-05-01 1993-10-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-10-30 1997-05-01 1997-10-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-10-30 2001-05-01 2001-10-31 $7700.00 Window Closed / Lapsed

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