Nitrogen fixation by electric arc and catalyst

Claim 2

A nitrogen fixation system comprising: (1) a low frequency, high voltage electric arc production means in the form of two electrodes with electrically insulating, coaxial sleeves, said electrodes being electrically connected to a low frequency, high voltage alternating current transformer, and said electric arc are being capable of raising nitrogen and oxygen to plasma state temperatures and of placing the gases into chemically excited states, and (2) an electric arc chamber for contacting a catalyst with arc plasma gases, said chamber being in the form of a cavity which is produced by pressurized streams of reactant gases heated to the plasma state and expanding from within a catalyst bed in a chamber, the inner surface of said cavity being composed of catalyst particles being contacted and impacted by said outward moving plasma state reactant gases, and (3) a product gas shielding means for shielding the gas product such as nitric oxide from the destructive effects of ultraviolet light emitted by the arc, said effects being capable of disassociating nitric oxide into nitrogen and oxygen, said shielding means being in the form of catalyst particles compacted by the weight of a vertical column of the catalyst bed above the arc cavity in the catalyst chamber and pressing downward about the cavity to provide a cavity wall of compacted catalyst particles opaque to light but permeable to the flow of gas species, and (4) reactant gas transport means in the form of said electrode sleeves, said sleeves being capable of conducting nitrogen and oxygen from inlet ducts to the arc zone through cylindrical channels within said sleeves between the electrode and the inner wall of each sleeve, and (5) heat transfer means in the form of gas driven particle turbulence whereby catalyst particles are moved by the reactant gas stream and plasma heat to and from the arc and the chamber walls, and (6) reactant gas circulation means capable of producing gas pressure for impelling reactant and product gases through said arc zone and catalyst chamber and of producing such particle displacement as to form said arc cavity and sufficient particle agitation for rapid heat transfer.

Claim 3

A nitrogen fixation system as to claim 1 in which the cavity produced by pressurized streams of reactant gases is produced by a vortex generated by said gas streams within the catalytic bed as the streams impinge against one another olibquely.

Claim 4

A nitrogen fixation system as in claim 1 in which the cavity produced by pressurized streams of reactant gases is in the form of a bubble-like cavity in which the gas streams impinge directly against one another forcing aside catalytic particles and generating eddy currents of the catalytic particles in the catalyst bed.

Claim 5

A nitrogen fixation system as in claim 1 in which the catalyst contacted by the arc plasma gases is tungsten trioxide powder.

Claim 6

A nitrogen fixation system as in claim 1 in which the catalyst contacted by the plasma state gases is chromic oxide powder, Cr 2 O 3 .

Claim 7

A nitrogen fixation system as in claim 1 in which the catalyst contacted by the plasma state gases is copper chromite.

Claim 8

A nitrogen fixation system as in claim 1 in which the catalyst contacted by the plasma state gases is barium promoted copper chromite.

Claim 9

A nitrogen fixation system as in claim 1 in which the catalyst contacted by the plasma state gases is tantalum oxide.

Claim 10

A nitrogen fixation system as in claim 1 in which the catalyst contacted by the plasma state gases is magnesium oxide.

Claim 11

A nitrogen fixation system comprising: (1) low frequency, high voltage electric arc production means in the form of four electrodes with electrically insulating, coaxial sleeves, said electrodes being in sets of two, each set being electrically connected to a low frequency, high voltage alternating current transformer, and being capable of supporting an electric arc across its two electrodes in such a manner that the arc from one electrode set is approximately perpendicular to the path of the other arc, both arcs being in an approximately horizontal plane with alternating current to one arc being at a ninety degree phase difference with the current to the other, both arcs being capable of raising nitrogen and oxygen to plasma state temperatures and of placing the gases into chemically excited states, and (2) an electric arc chamber for contacting a catalyst with arc plasma gases, said chamber being formed by catalyst particles driven by reactant gas and plasma pressure as said pressure causes the particles to whirl in a vortex and move outward from a cavity at the center of a catalyst bed, and (3) product gas shielding means to shield the gas product in the form of nitric oxi oxide from the destructive effects of ultraviolet light emissions from the electric arcs, said emissions being otherwise capable of photodisassociating nitric oxide into nitrogen and oxygen, said shielding means being in the form of said catalyst particles partially compacted by the weight of a vertical column of the catalyst bed above the arc chamber as said weight presses down on particles about said chamber to more densely aggregate the particles and to thereby impede the passage of ultraviolet light from the arcs to the product gas diffusing outward through the particles, and (4) reactant gas transport means in the form of cylindrical channels within said electrode sleeves, said channels being coaxial between the electrode and the inner wall of each sleeve, and (5) heat transfer means in the form of gas-driven particle turbulence whereby catalyst particles are moved by the streams of reactant gases and plasma heat to and from the arc zone and the chamber walls, said particles being heated by contact with the arc zone and being cooled by proximity to the catalyst chamber walls, and (6) reactant gas circulation means capable of producing gas pressure for impelling reactant and product gases through said arc zone and through said catalyst chamber and capable of producing such particle displacement as to form said arc chamber and to circulate catalyst particles to and from the arc zone and the catalyst chamber walls.

Claim 12

A nitrogen fixation system comprising: (1) low frequency, high voltage electric arc production means in the form of four electrodes with electrically insulating, coaxial sleeves, said electrodes being in sets of two, each set being electrically connected to a low frequency, high voltage alternating current transformer, and being capable of supporting an electric arc across its two electrodes in such a manner that the arc from one electrode set is approximately perpendicular to the path of the other arc, both arcs being in an approximately horizontal plane with alternating current to one arc being at a ninety degree phase difference with the current to the other, both arcs being capable of raising nitrogen and oxygen to plasma state temperatures and of placing the gases into chemically excited states, and (2) an electric arc chamber for contacting a catalyst with arc plasma gases, said chamber being formed by catalyst particles driven by reactant gas and plasma pressure as said pressure causes the particles to whirl in a vortex and move outward from a cavity at the center of a catalyst bed, and (3) product gas shielding means to shield the gas product in the form of nitric oxi oxide from the destructive effects of ultraviolet light emissions from the electric arcs, said emissions being otherwise capable of photodisassociating nitric oxide into nitrogen and oxygen, said shielding means being in the form of said catalyst particles partially compacted by the weight of a vertical column of the catalyst bed above the arc chamber as said weight presses down on particles about said chamber to more densely aggregate the particles and to thereby impede the passage of ultraviolet light from the arcs to the product gas diffusing outward through the particles, and (4) reactant gas transport means in the form of cylindrical channels within said electrode sleeves, said channels being coaxial between the electrode and the inner wall of each sleeve, and (5) heat transfer means in the form of gas-driven particle turbulence whereby catalyst particles are moved by the streams of reactant gases and plasma heat to and from the arc zone and the chamber walls, said particles being heated by contact with the arc zone and being cooled by proximity to the catalyst chamber walls, and (6) reactant gas circulation means capable of producing gas pressure for impelling reactant and product gases through said arc zone and through said catalyst chamber and capable of producing such particle displacement as to form said arc chamber and to circulate catalyst particles to and from the arc zone and the catalyst chamber walls.

Claim 13

A nitrogen fixation system as in claims 1 and 10 in which the catalyst contacted by the plasma state gases from the electric arc discharge is tungstic oxide supported on porous alumina.

Claim 14

A nitrogen fixation system as in claims 1 and 10 in which the catalyst contacted by plasma state nitrogen and oxygen is barium promoted copper chromite supported on porous alumina.

Claim 15

A nitrogen fixation system as in claims 1 and 10 in which the catalyst is molybdenum oxide supported on porous alumina.

Claim 16

A nitrogen fixation system as in claims 11 and 10 in which the catalyst is tantalum oxide supported on porous alumina.