US4451436A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Nitrogen fixation by plasma and catalyst
Assignee: Individual
•
Filing: 1983-02-01
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Granted: 1984-05-29
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Expires: 2003-02-01
Abstract
Abstract A system and a method of nitrogen fixation is disclosed in which nitrogen and other gases such as oxygen are electrically activated and reacted on a catalyst-like material to provide a fixed nitrogen product in such a way that the reactant gases are first placed into an excited state by a single electrode electric discharge acting on a gas stream and then by means of the stream the reactants are contacted on the catalyst-like material on which they are then combined and the product compounds which are thereby formed are shielded by the same catalytic material from ultra violet radiation generated by the electric excitation, said shielding being to prevent subsequent disassociation of the product compounds, and the gas stream emerging on the downstream side of the catalyst carries the products to an absorption bed on which they are absorbed and concentrated and then reacted with a periodic flow of hydrogen to provide ammonia. In an alternate embodiment the products absorbed on the bed are first desorbed and then reacted with hydrogen.
Inventors
- 👤 Louis R. O'Hare
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 04:43
CPC Classifications
C; C01; C01B; C01B21/00; C01B21/20; C01B21/24; C01B21/30; C01B21/32; B; B01; B01J; B01J12/00; B01J12/002; B01J19/00; B01J19/08; B01J19/087; B01J19/088; C01C; C01C1/00; C01C1/02; C01C1/04; C01C1/0405; C01C1/0494; B01J2219/00; B01J2219/08; B01J2219/0894; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52; Y10; Y10S; Y10S422/00; Y10S422/904
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
239 words
A gas phase chemical reaction system comprising: (1) gas particle excitation means capable of placing into chemically excited states gas molecules and atoms with an electric discharge in the form of a plasma from a single electrode discharge with the electrode receiving very high radio frequency current at very high impedance and having a radio frequency shield to prevent electromagnetic radiation energy loss, and (2) catalyst contacting and ultraviolet radiation shielding means in the form of a mass of opaque catalytic substance capable of being contacted in such a way by a gas stream containing excited gas species from said excitation means that the excited gas particles are shielded by the catalytic material when they move from the area of the electric excitation and ultraviolet radiation into and through small openings in the catalytic material, said openings being in such a direction as to interpose the catalytic material between the ultraviolet radiation and the gas stream flowing through the catalytic bed, and (3) first reaction product concentration means in the form of a bed of absorbtive material capable of absorbing product gases from a gas stream flowing from said catalyst contacting means, (4) reactant and product gas circulation means in the form of a pump capable of cycling gas through a chamber containing the single electrode excitation means and through the catalyst contacting means as well as through the first product absorbtion means and back to the excitation means.
Claim 2
Dependent Claim
239 words
A gas phase chemical reaction system comprising: (1) gas particle excitation means capable of placing into chemically excited states gas molecules and atoms with an electric discharge in the form of a plasma from a single electrode discharge with the electrode receiving very high radio frequency current at very high impedance and having a radio frequency shield to prevent electromagnetic radiation energy loss, and (2) catalyst contacting and ultraviolet radiation shielding means in the form of a mass of opaque catalytic substance capable of being contacted in such a way by a gas stream containing excited gas species from said excitation means that the excited gas particles are shielded by the catalytic material when they move from the area of the electric excitation and ultraviolet radiation into and through small openings in the catalytic material, said openings being in such a direction as to interpose the catalytic material between the ultraviolet radiation and the gas stream flowing through the catalytic bed, and (3) first reaction product concentration means in the form of a bed of absorbtive material capable of absorbing product gases from a gas stream flowing from said catalyst contacting means, (4) reactant and product gas circulation means in the form of a pump capable of cycling gas through a chamber containing the single electrode excitation means and through the catalyst contacting means as well as through the first product absorbtion means and back to the excitation means.
Claim 3
Dependent Claim
39 words
A gas phase chemical reactor as in claim 1 having additionally a gas pressure control means in the form of a vacuum control valve capable of regulating lowered gas pressure in a chamber containing the gas particle excitation means.
Claim 4
Dependent Claim
91 words
A gas phase chemical reactor as in claim 1 in which the gas molecules and atoms are molecules and atoms of nitrogen and oxygen and in which the catalytic contacting and ultraviolet shielding means is multiple layers of anodized tungsten wire screen having a very fine mesh, and in which the product gas capable of being absorbed on the bed of the absorbtive material of the first product concentration means is nitric oxide and the bed of absorbtive material of the first product concentration means is activated carbon in aqueous slurry.
Claim 5
Dependent Claim
97 words
A gas phase chemical reactor as in claim 1 in which the gas molecules and atoms are molecules and atoms of nitrogen and oxygen and in which the catalytic contacting and ultraviolet shielding means is comprised of both a very fine mesh metallic screen of molybdenum wire coated with molybdenum oxide and also molybdenum oxide granules which are supported by the screen and in which the product gas capable of being absorbed on the absorbtive material of the first product concentration means is nitric oxide and the absorbtive material is carbon derived by pyrolysis of vegetable matter.
Claim 6
Dependent Claim
79 words
A gas phase chemical reactor as in claim 1 in which the gas molecules and atoms are molecules and atoms of nitrogen and oxygen and in which the catalyst contacting and ultraviolet shielding means is a matrix formed by multiple layers of anodized molybdenum wire screen and in which the product gas capable of being absorbed on the absorbtive material of the first product concentration is nitric oxide and the absorbtive material is an aqueous solution of ferrous sulfate.
Claim 7
Dependent Claim
110 words
A gas phase chemical reactor as in claim 1 in which the gas molecules and atoms are molecules and atoms of nitrogen and oxygen and in which the catalytic contacting and ultraviolet shielding means is comprised of both a very fine mesh metallic screen of tungsten wire coated with a tungsten oxide and tungstic oxide pellets which are supported by the screen, and in which the product gas capable of being absorbed on the absorbtive material of the first product concentration means is nitric oxide and the absorbtive material is charcoal type carbon derived from pyrolyzed wood and cellulosic vegetable matter in the form of field and forest waste materials.
Claim 8
Dependent Claim
81 words
A gas phase chemical reaction system as in claim 1 in which the gas molecules and atoms are of nitrogen and hydrogen and in which the catalyst contacting and ultraviolet shielding means is a bed of y type zeolite of a metal selected from the group consisting of sodium, nickel, cobalt and manganese, and in which the product gas capable of being absorbed on the absorbtive material of the first product concentration means is ammonia and the absorbtive material is water.
Claim 9
Dependent Claim
67 words
A chemical reaction system as in claim 1 in which the gas molecules and atoms are of hydrogen and nitrogen and in which the catalyst contacting and ultraviolet shielding means is a catalytic bed of manganese x type zeolites, and in which the product gas capable of being absorbed on the absorbtive material of the first product concentration means is ammonia and the absorbtive material is water.
Claim 10
Dependent Claim
67 words
A chemical reaction system as in claim 1 in which the gas molecules and atoms are of hydrogen and nitrogen and in which the catalyst contacting and ultraviolet shielding means is granulated, activated alumina and atomic aluminum type graphimet, and in which the product gas capable of being absorbed on the absorbtive material of the first product concentration means is ammonia and the absorbtive material is water.
Claim 11
Dependent Claim
49 words
A chemical reaction system as in claim 1 in which the gas molecules and atoms are of nitrogen and hydrogen and in which the catalyst contacting and ultraviolet shielding means is wire screening made from wire of a metal selected from the group consisting of tungsten, tantalum and molybdenum.
Claim 12
Dependent Claim
72 words
A chemical reactor as in claim 1 in which the gas molecules and atoms are molecules and atoms of nitrogen and water vapor and in which the catalytic contacting and ultraviolet shielding means is a catalytic bed of granulated activated alumina and aluminum graphimet, and in which the product gas capable of being absorbed on the absorbtive material of the first product concentration means is ammonia and the absorbtive material is water.
Claim 13
Dependent Claim
88 words
A gas phase chemical reaction system as in claim 1 in which the catalyst contacting means and the ultraviolet shielding means is a bed of catalytic material in the form of pellets and granules of tungsten oxide and molybdenum oxide located at the base of a reaction chamber, said being supported by a porous material and said bed being located beneath the plasma of the gas particle excitation means and said bed being capable of permeation by a gas stream moving from the plasma and through the bed.
Claim 14
Dependent Claim
73 words
A gas phase chemical reaction system as in claim 1 and having additionally a desorbtion-reaction means by which compounds absorbed on the absorbtive material of the first product absorbtion means are heated and desorbed and reacted with a reactant in a second time period, and having additionally a second product reaction means in the form of a container of absorbtive material capable of absorbing a product of the reaction of the second period.
Claim 15
Dependent Claim
119 words
A gas phase chemical reaction system as in claim 13 in which the gas molecules and atoms of the gas excitation means are molecules and atoms of oxygen and nitrogen, and in which one of the product gases of the first product concentration means is nitrogen oxide and in which the absorbtive material capable of absorbing product gas of the first reaction product concentration means is an absorbtive material selected from the group consisting of chromium trioxide supported on activated alumina and on silica gel, cupric oxide on alumina, manganese oxide, magnesium oxide, nickel oxide, molybdenum trioxide, platinum supported on alumina and on silica, rhenium and rhodium supported on alumina and on silica and CoNiNa y type crystaline zeolite.
Claim 16
Dependent Claim
39 words
A reaction system as in claim 13 in which the reactant of the desorbtion-reaction means is hydrogen gas, and the product of the second reaction period is ammonia and the absorbent of the second product reaction period is water.
Claim 17
Dependent Claim
71 words
A reaction system as in claim 13 in which the desorbtion-reaction means by which compounds absorbed on the absorbtive material of the first product absorbtion means are heated and desorbed is an electric resistance heater heating a duct which carries the reactant gas of the second time period and heats the absorbed compounds by means of contact with the heated gas when the heated gas flows during the second time period.
Claim 18
Dependent Claim
66 words
A reaction system as in claim 13 in which the desorbtion-reaction means by which compounds absorbed on the absorbtive material of the first product absorbtion means are heated and desorbed is an electric resistance heater embedded in the same absorbtive material of the first product absorbtion means, said heater being energized by current only during the second period which is the period of the desorbtion reaction.
Claim 19
Dependent Claim
62 words
A chemical reaction system as in claim 1 in which the catalyst contacting means and the ultraviolet shielding means is chromium trioxide and manganese oxide and in which the product gas capable of being absorbed on the bed of absorbative material of the first product concentration means is nitric oxide and the reactant gas molecules and atoms are of nitrogen and oxygen.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1987-05-29 | 1987-11-28 | 1988-05-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1991-05-29 | 1991-11-28 | 1992-05-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1995-05-29 | 1995-11-28 | 1996-05-29 | $7700.00 | Window Closed / Lapsed |