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US4877547A Expired / Lapsed US ⏱️ 0.0 years remaining

Liquid crystal display element

Assignee: Merck Patent GmbH
•
Filing: 1987-02-14
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Granted: 1989-10-31
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Expires: 2007-02-14
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Abstract

Abstract The invention relates to a new liquid crystal display element with static or multiplex control with a low multiplex ratio and an operating voltage below 3.3 volts, containing a liquid crystal dielectric, wherein the operating temperature range extends from -30° C. to +80° C. and the viscosity of the dielectric at 20° C. is less than 40 mPa.s.

Inventors

  • 👤 Georg Weber
  • 👤 Bernhard Scheuble
  • 👤 Joachim Krause

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 03:21
CPC Classifications
C; C09; C09K; C09K11/00; C09K19/00; C09K19/02; C09K19/04; C09K19/42

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 170 words
A liquid crystal display element with static or multiplex control with a low multiplex ratio and an operating voltage below 3.3 volts, containing a liquid crystal dielectric, wherein the operating temperature range extends from -30° C. to +80° C. and the viscosity of the dielectric at 20 ° C. is less than 40 mPa.s, wherein the dielectric contains at least one component of the formula I ##STR5## wherein R 1 is alkyl with 1 to 12 C atoms, wherein one or two non-adjacent CH 2 groups can also be replaced by O atoms, --CO--, --O--CO--, --CO--O-- and/or --CH═CH-- groups, A o and A 1 each independently of one another are Cy, Dio or Phe, Z is --CH 2 --O--, --O--CH 2 or a single bond, X 1 is F, Cl, --CN or --NCS, X 2 is F, Cl and, in the case where X 1 =NCS, also H, m is 0 or 1, Cy is trans-1,4-cyclohexylene, Dio is trans-1,3-dioxane-2,5-diyl and Phe is 1,4-phenylene which is unsubstituted or substituted by fluorine.
Claim 2
Dependent Claim 170 words
A liquid crystal display element with static or multiplex control with a low multiplex ratio and an operating voltage below 3.3 volts, containing a liquid crystal dielectric, wherein the operating temperature range extends from -30° C. to +80° C. and the viscosity of the dielectric at 20 ° C. is less than 40 mPa.s, wherein the dielectric contains at least one component of the formula I ##STR5## wherein R 1 is alkyl with 1 to 12 C atoms, wherein one or two non-adjacent CH 2 groups can also be replaced by O atoms, --CO--, --O--CO--, --CO--O-- and/or --CH═CH-- groups, A o and A 1 each independently of one another are Cy, Dio or Phe, Z is --CH 2 --O--, --O--CH 2 or a single bond, X 1 is F, Cl, --CN or --NCS, X 2 is F, Cl and, in the case where X 1 =NCS, also H, m is 0 or 1, Cy is trans-1,4-cyclohexylene, Dio is trans-1,3-dioxane-2,5-diyl and Phe is 1,4-phenylene which is unsubstituted or substituted by fluorine.
Claim 3
Dependent Claim 147 words
Liquid crystal display element according to claim 1, wherein the dielectric contains at least one component of the formula II ##STR6## wherein R 1 is alkyl with 1 to 12 C atoms, wherein one or two non-adjacent CH 2 groups can also be replaced by --O--, --CO--, --O--CO--, --CO--O-- and/or --CH═CH--, Q 1 is trans-1,4-cyclohexylene, wherein one or two non-adjacent CH 2 groups can also be replaced by O and or S, Q 2 is trans-1,4-cyclohexylene, wherein one or two non-adjacent CH 2 groups can also be replaced by O and/or S, or 1,4-phenylene which is unsubstituted or substitited by flourine and wherein one or more CH groups can be replaced by N, Z o is --CO--O--, CH 2 O-- or --CH 2 CH 2 --, X 1 is F, Cl, --CN or --NCS and X 2 is F, Cl or, if X 1 =NCS, also H.
Claim 4
Dependent Claim 128 words
Liquid crystal display element according to claim 1, wherein the dielectric contains at least one component of the formula III R.sup.1 --Q.sup.1 --(Q.sup.2).sub.n --X.sup.3 III wherein R 1 is alkyl with 1 to 12 C atoms, wherein one or two non-adjacent CH 2 groups can also be replaced by --O--, --CO--, --O--CO--, --CO--O-- and/or --CH═CH--, Q 1 is trans-1,4-cyclohexylene, wherein one or two non-adjacent CH 2 groups can also be replaced by O and/or S, Q 2 is trans-1,4-cyclohexylene, wherein one or two non-adjacent CH 2 groups can also be replaced by O and/or S, of 1,4-phenylene which is unsubstituted or substituted by fluorine and wherein one or more CH groups can be replaced by N, n is 1 or 2 and X 3 is --CN or --NCS.
Claim 5
Dependent Claim 179 words
Liquid crystal display element according to claim 1, wherein the dielectric contains at least one component of the formula IV R.sup.1 --(Q.sup.1 --Z.sup.1).sub.m --Q.sup.2 --Q.sup.2 --(Z.sup.1 --Q.sup.1).sub.P --R.sup.2 IV wherein R 1 and R 2 each independently of one another are alkyl with 1 to 12 C atoms, wherein one or two non-adjacent CH 2 groups can also be replaced by --O--, --CO--, --O--CH--, --CO--O-- and/or --CH═CH--, the symbols Q 1 each independently of one another are trans-1,4-cyclohexylene, wherein one or two non-adjacent CH 2 groups can also be replaced by O and/or S, the symbols Q 2 each independently of one another are trans-1,4-cyclohexylene, wherein one or two non-adjacent CH 2 groups can also be replaced by O and/or S, or 1,4-phenylene which is unsubstituted or substituted by fluorine and wherein one or more CH groups can also be replaced by N, the symbols Z 1 each independently of one another are --CO--O--, --O--CO--, --CH 2 O--, --OCH 2 , --CH 2 CH 2 -- or a single bond and m and P are each 0 or 1.
Claim 6
Dependent Claim 82 words
Liquid crystal display element according to claim 1. wherein the dielectric contains at least one component of the formula V R.sup.1 --Cy--Q.sup.o --R.sup.2 V wherein R 1 and R 2 each independently of one another are alkyl with 1 to 12 C atoms, wherein one or two non-adjacent CH 2 groups can also be replaced by --O--, --CO--, --O--CO-- --CO--O-- and/or --CH═CH--, Q o is Cy or Phe, Phe is 1,4-phenylene which is unsubstituted or substituted by fluorine and Cy is trans-1,4-cyclohexylene.
Claim 7
Dependent Claim 59 words
Liquid crystal display element according to claim 1, wherein the dielectric contains at least one component of the formula VI R.sup.1 --Phe--Phe--CN VI wherein R 1 is alkyl with 1 to 12 C atoms, wherein one or two non-adjacent CH 2 groups can also be replaced by O atoms, --CO--, --O--CO--, --CO--O-- and/or --CH═CH-- groups and Phe is 1,4-phenylene.
Claim 8
Dependent Claim 119 words
Liquid crystal display element according to claim 1, wherein the dielectric contains at least one component of the formula VII R.sup.1 --(Q).sub.n --COO--Phe-R.sup.2 VII wherein R 1 and R 2 each endependently of one another are alkyl with 1 to 12 C atoms, wherein one or two non-adjacent CH 2 groups can also be replaced by --O--, --CO--, --O--CO--, --CO--O--, and/or --CH═CH--, R 2 is also CN, Q is trans-1,4-cyclohexylene, wherein one or two non-adjacent CH 2 groups can also be replaced by O and/or S, or Phe, Phe is 1,4-phenylene which is unsubstituted or substituted by fluorine and n is 1 or 2, and if n=2, the two groups Q can be identical or different from one another.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-10-30 1993-05-01 1993-10-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-10-30 1997-05-01 1997-10-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-10-30 2001-05-01 2001-10-31 $7700.00 Window Closed / Lapsed

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