US4676924A
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Liquid crystalline isothiocyanates with dioxane ring and liquid crystalline admixtures containing same
Assignee: Military University of Technology in Warsaw
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Filing: 1985-06-28
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Granted: 1987-06-30
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Expires: 2005-06-28
Abstract
Abstract New compounds of the general formula: <IMAGE> I wherein the symbols X stand for carbon atom bonded with two hydrogen atoms /-CH2- group/ and the symbols Z stand for oxygen atom or the symbols X stand for oxygen atom and the symbols Z stand for carbon atom bonded with two hydrogen atoms /-CH2- group/, m is an integer of 1 to 2, R represents an alkyl /H2n+1Cn/ or an 4-alkylphenyl /H2n+1Cn-C6H4/ or an alkylbiphenyl /H2n+1Cn-C6H4-C6H4/ or an alkylcyclohexylphenyl group /H2n+1Cn-C6H10-C6H4/, the term alkyl group signifies an alkyl chain containing 1 to 15 carbon atoms or it also signifies a branched-chain alkyl group C2H5-CH/CH3/-/CH2/k where k in an integer of 1 to 3, have utility as liquid crystals. A process for manufacture of compounds of the general formula I. Liquid crystalline admixtures containing those compounds and a way of selection of their compositions to obtain the admixtures which exhibit smectic, smectic and nematic or only smectic properties as well as their use in electrooptical devices is described.
Inventors
- 👤 Roman Dabrowski
- 👤 Jerzy Dziaduszek
- 👤 Jaroslaw Szulc
- 👤 Zygfryd Witkiewicz
- 👤 Zofia Stolarz
- 👤 Krystyna Kenig
- 👤 Gabriela Adamska
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 09:54
CPC Classifications
C; C09; C09K; C09K19/00; C09K19/04; C09K19/42; C07; C07D; C07D319/00; C07D319/04; C07D319/06; C09K19/06; C09K19/34; C09K19/3402; C09K2019/3422; C09K2019/3425
Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
109 words
Compounds of the general formula: ##STR9## wherein the symbols X stand for a carbon atom bonded with two hydrogen atoms /--CH 2 -- group/ and the symbols Z stand for oxygen atom or the symbols X stand for oxygen atom or the symbols Z stand for a carbon atom bonded with two hydrogen atoms /--CH 2 -- group/, m is an integer of 1 to 2, R represents an alkyl /H 2n+1 C n --/ or an 4-alkylphenyl /H 2n+1 C n C 6 H 4 --/ group, the term alkyl group signifies an alkyl chain containing 1 to 15 carbon atoms and the chain is straight or branched.
Claim 2
Dependent Claim
109 words
Compounds of the general formula: ##STR9## wherein the symbols X stand for a carbon atom bonded with two hydrogen atoms /--CH 2 -- group/ and the symbols Z stand for oxygen atom or the symbols X stand for oxygen atom or the symbols Z stand for a carbon atom bonded with two hydrogen atoms /--CH 2 -- group/, m is an integer of 1 to 2, R represents an alkyl /H 2n+1 C n --/ or an 4-alkylphenyl /H 2n+1 C n C 6 H 4 --/ group, the term alkyl group signifies an alkyl chain containing 1 to 15 carbon atoms and the chain is straight or branched.
Claim 3
Dependent Claim
46 words
Compounds as claimed in claim 1 where the symbols X stand for carbon atom bonded with two hydrogen atoms /--CH 2 -- group/ and the symbols Z stand for oxygen atom, m is the integer of 1 and R represents an alkyl or an alkylphenyl group.
Claim 4
Dependent Claim
12 words
Compounds as claimed in claim 2 where R represents normal alkyl group.
Claim 5
Dependent Claim
32 words
Compounds as claimed in claim 2 where R represents a branched alkyl group, C 2 H 5 --CH/CH 3 /--/CH 2 / k , k is an interger of 1 to 3.
Claim 6
Dependent Claim
28 words
A liquid crystalline admixture containing at least two liquid crystalline components, wherein at least one component is a compound of the formula I as claimed in claim 1.
Claim 7
Dependent Claim
66 words
The liquid crystalline admixture as claimed in claim 5, which contains one or more liquid crystalline compounds of formula I defined in claim 1 and one or more compounds of the formulae: ##STR10## wherein symbols p and r are the integer of 1 to 2, Y represents NO 2 or CN group, R 1 represents an alkyl, an alkoxy, an alkylcarbonate, an alkoxycarboxy, an alkylphenyl group.
Claim 8
Dependent Claim
60 words
The liquid crystalline admixture as claimed in claim 6, which contains 50 to 90 percent by weight of at least one of the compounds of the formulae II to XI defined in claim 6, wherein R 1 represents an alkyl or an alkoxy group having at least 5 carbon atom in the alkyl chain, p is the integer of 1.
Claim 9
Dependent Claim
23 words
A liquid crystalline admixture as claimed in claim 5, which additionally contains an optically active dopant compound and/or a pleochroic or dichroic dye.
Claim 10
Dependent Claim
23 words
A liquid crystalline admixture containing as liquid crystalline components at least two of the compounds of formula I as claimed in claim 2.
Claim 11
Dependent Claim
74 words
A liquid crystalline admixture as claimed in claim 9 containing at least two compounds of the formula I, wherein R represents an alkyl group in which at least one of said compounds from the group having alkyl groups containing from 2 to 6 carbon atoms and at least one of said compounds is selected from the groups containing from 8 to 12 carbon atoms both of said groups being present simultaneously in said admixture.
Claim 12
Dependent Claim
77 words
A method for the preparation of nematic liquid crystalline mixtures from smectic compounds which comprises the steps of adding to at least one compound selected from the compounds according to claim 1 or mixtures thereof, at least one compound selected from the group of compounds having the formulae II through XI ##STR11## wherein p and r are the integer 1 or 2; Y is NO 2 or CN; R 1 is alkyl, alkoxy, alkanoyloxy, alkylcarbonato or alkylphenyl.
Claim 13
Dependent Claim
63 words
The method for the preparation of nematic phase mixtures according to claim 11 wherein 50 to 90 wt.% of a compound selected from the group having the formulae II to XI, wherein R 1 is alkyl or alkoxy with at least 5 carbon atoms in said alkyl portion, and p is 1; is admixed to at least one compound having the formula I.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1990-06-29 | 1990-12-29 | 1991-06-30 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1994-06-29 | 1994-12-29 | 1995-06-30 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1998-06-29 | 1998-12-29 | 1999-06-30 | $7700.00 | Window Closed / Lapsed |