Claims Analysis
Total Claims: 13
Claim 1
Independent Claim
365 words
A process for the catalytic cracking of a heavy, metals laden hydrocarbonaceous feed by contacting a hot regenerated catalyst stream with the feed in a base of riser reactor, cracking the feed in the riser reactor at catalytic cracking conditions to form cracked products and coked catalyst containing metals, separating the coked catalyst from cracked products, stripping the coked catalyst with steam and regenerating the steam stripped catalyst regenerator with an oxygen-containing gas to form hot regenerated catalyst, characterized by: (a) using a mixture of fluidizable catalytic cracking catalyst and a demetallizing additive, which mixture is resolvable by elutriation; (b) demetallizing the feed by contacting the feed in the base of the riser reactor with the demetallizing additive and removing a majority of the metals and some coke from the feed to produce a coked additive containing a majority of the metals content of the feed and a demetallized feed; (c) cracking the demetallized feed in the riser reactor with the hot regenerated cracking catalyst and discharging from the riser reactor cracked products and a mixture of coked cracking catalyst and coked additive; (d) regenerating the mixture in a first stage regenerator having a base, at least one inlet for coked catalyst and additive, an upper outlet and a lower outlet by adding the mixture to the first stage regenerator, contacting the mixture with an oxygen-containing gas at coke combustion conditions, segregating by elutriation a dense phase fluidized bed with an increased concentration of demetallizing additive, relative to the mixture discharged from the riser, to form a dense phase fluidized bed of regenerated demetallizing additive with a reduced coke content and partially regenerated catalytic cracking catalyst; (e) removing from the lower outlet of the first stage regenerator a regenerated demetallizing additive and recycling it to the base of the riser reactor; (f) removing from the upper outlet of the first stage regenerator the partially regenerated catalytic cracking catalyst and discharging it into a second stage regenerator; (g) regenerating the partially regenerated catalytic cracking catalyst with an oxygen containing gas in the second stage regenerator to produce regenerated catalytic cracking catalyst; (h) recycling regenerated catalytic cracking catalyst from the second stage regenerator to the riser reactor.
Claim 2
Dependent Claim
365 words
A process for the catalytic cracking of a heavy, metals laden hydrocarbonaceous feed by contacting a hot regenerated catalyst stream with the feed in a base of riser reactor, cracking the feed in the riser reactor at catalytic cracking conditions to form cracked products and coked catalyst containing metals, separating the coked catalyst from cracked products, stripping the coked catalyst with steam and regenerating the steam stripped catalyst regenerator with an oxygen-containing gas to form hot regenerated catalyst, characterized by: (a) using a mixture of fluidizable catalytic cracking catalyst and a demetallizing additive, which mixture is resolvable by elutriation; (b) demetallizing the feed by contacting the feed in the base of the riser reactor with the demetallizing additive and removing a majority of the metals and some coke from the feed to produce a coked additive containing a majority of the metals content of the feed and a demetallized feed; (c) cracking the demetallized feed in the riser reactor with the hot regenerated cracking catalyst and discharging from the riser reactor cracked products and a mixture of coked cracking catalyst and coked additive; (d) regenerating the mixture in a first stage regenerator having a base, at least one inlet for coked catalyst and additive, an upper outlet and a lower outlet by adding the mixture to the first stage regenerator, contacting the mixture with an oxygen-containing gas at coke combustion conditions, segregating by elutriation a dense phase fluidized bed with an increased concentration of demetallizing additive, relative to the mixture discharged from the riser, to form a dense phase fluidized bed of regenerated demetallizing additive with a reduced coke content and partially regenerated catalytic cracking catalyst; (e) removing from the lower outlet of the first stage regenerator a regenerated demetallizing additive and recycling it to the base of the riser reactor; (f) removing from the upper outlet of the first stage regenerator the partially regenerated catalytic cracking catalyst and discharging it into a second stage regenerator; (g) regenerating the partially regenerated catalytic cracking catalyst with an oxygen containing gas in the second stage regenerator to produce regenerated catalytic cracking catalyst; (h) recycling regenerated catalytic cracking catalyst from the second stage regenerator to the riser reactor.
Claim 3
Dependent Claim
41 words
The process of claim 1 further characterized in that the mixture of coked cracking catalyst and coked additive discharged from the riser is steam stripped at an elevated temperature and then subjected to an additional stripping step at a higher temperature.
Claim 4
Dependent Claim
22 words
The process of claim 2 further characterized in that the additional stripping step comprises contact with carbon dioxide at about 1050-1250° F.
Claim 5
Dependent Claim
35 words
The process of claim 1 further characterized in that an external additive cooler which is intermediate the lower outlet of the first stage regenerator and the base of the riser reactor cools regenerated demetallizing additive.
Claim 6
Dependent Claim
28 words
The process of claim 1 further characterized in that an external additive cooler which is intermediate the second stage regenerator and the riser reactor cools regenerated cracking catalyst.
Claim 7
Dependent Claim
20 words
The process of claim 1 further characterized in that a heat removal means removes heat from the second stage regenerator.
Claim 8
Dependent Claim
29 words
The process of claim 1 further characterized in that the mixture of coked additive, coked catalyst and cracked products is discharged from the riser reactor into a cyclone separator.
Claim 9
Dependent Claim
48 words
The process of claim 1 further characterized in that the coked catalyst and coked additive are stripped with steam and the steam stripped mixture is mixed with an oxygen containing gas in a riser mixer upstream of the first stage regenerator and discharged into the first stage regenerator.
Claim 10
Dependent Claim
27 words
The process of claim 1 further characterized in that the demetallizing additive is selected from the group of alumina, low activity clay, coke particles, and magnesium oxide.
Claim 11
Dependent Claim
45 words
The process of claim 1 further characterized in that the demetallizing additive has an average settling velocity in the catalytic cracking process of 0.4 to 5 feet per second and the cracking catalyst has an average settling velocity of less than 0.3 feet per second.
Claim 12
Dependent Claim
24 words
The process of claim 1 further characterized in that the flue gas from the first stage regenerator contains 2 to 10 mole % CO.
Claim 13
Dependent Claim
46 words
The process of claim 1 further characterized in that the oxygen containing gas is added to the first stage regenerator at multiple levels in the dense phase fluidized bed of additive through spargers which minimize turbulence and agitation of the dense phase fluidized bed of additive.